Influence of agricultural development and climate changes on the drainage valley density of the southern half of the Russian Plain

The southern half of the Russian Plain is characterized by a relatively short history of intensively ploughed lands.The duration varies from approximately three centuries in the southern part of the forest zone to less than one century in some parts of the steppe zone.It was found that after cultivation,on more than 40％ of lands in river basins the drainage valley density (Ddv) decreased by 15-58％ in all landscape zones.In the first stage,the Ddv decrease was mostly associated with increasing surface runoff coefficient after cultivation of virgin lands with proportional decreases in groundwater runoff.In the second stage,usually after reaching areas of arable lands in river basins ＞ 60％,the volume of eroded sediments entering small fiver channels exceeded the transport capacities of the permanent water-courses.As a result,the river channels completely silted.In later stages,the sediment redistribution cascade within the small river basins of the Russian Plain stabilized because of the increasing proportion of sediment eroded from the basin areas and re-deposited before entering the river channels because of the increasing area of sediment sinks due to the increase in dry valley lengths and total areas.The morphological parameters of small valleys and groundwater discharges are the key parameters that affect the intensity of small river aggradation on the regional scale.     

The end of the Great Khersonian Drying of Eurasia: Magnetostratigraphic dating of the Maeotian transgression in the Eastern Paratethys

Central Eurasia underwent significant palaeoclimatic and palaeogeographic transformations during the middle to late Miocene. The open marine ecosystems of the Langhian and Serravallian seas progressively collapsed and were replaced in the Tortonian by large endorheic lakes. These lakes experienced major fluctuations in water level, directly reflecting the palaeoclimatic conditions of the region. An extreme lowstand of the Eastern Paratethys lake (?300 m) during the regional Khersonian stage reveals a period of intensely dry conditions in Central Eurasia causing a fragmentation of the Paratethys region. This period of “Great Drying” ended by a climate change towards more humid conditions at the base of the Maeotian stage, resulting in a large transgressive event that reconnected most of the Paratethyan basins. The absence of a robust time frame for the Khersonian–Maeotian interval hampers a direct correlation with the global records and complicates a thorough understanding of the underlying mechanisms. Here we present a new chronostratigraphic framework for the Khersonian and Maeotian deposits of the Dacian Basin of Romania, based on integrated magneto‐biostratigraphic studies on long and continuous sedimentary successions. We show the dry climate conditions in the Khersonian start at 8.6–8.4 Ma. The Khersonian/Maeotian transition is dated at 7.65–7.5 Ma, several million years younger than previous estimates. The Maeotian transgression occurs later (7.5–7.4 Ma) in more marginal and shallower basins, in agreement with the time transgressive character of the flooding. In addition, we date a sudden water level drop of the Eastern Paratethys lake, the Intra‐Maeotian Event (IME), at 6.9 Ma, and hypothesize that this corresponds to a reconnection phase with the Aegean basin of the Mediterranean. Finally, we discuss the potential mechanisms explaining the particularities of the Maeotian transgression and conclude that the low salinity and the seemingly “marine influxes” most likely correspond to episodes of intrabasinal mixing in a gradual and pulsating transgressive setting.     

EPR and magnetism of the nanostructured natural carbonaceous material shungite

The X-band EPR and magnetic susceptibility in the temperature range 4.2–300 K study of the shungite-I, natural nanostructured material from the deposit of Shunga are reported. Obtained results allow us to assign the EPR signal to conduction electrons, estimate their number, N _P, and evaluate the Pauli paramagnetism contribution to shungite susceptibility. A small occupation (~5%) of the localized nonbonding π states in the zigzag edges of the open-ended graphene-like layers and/or on σ (sp ^2+x ) orbitals in the curved parts of the shungite globules has been also revealed. The observed temperature dependence of the EPR linewidth can be explained by the earlier considered interaction of conduction π electrons with local phonon modes associated with the vibration of peripheral carbon atoms of the open zigzag-type edges and with peripheral carbon atoms cross-linking different nanostructures. The relaxation time T ₂ and diffusion time T _D are found to have comparable values (2.84 × 10⁻⁸ and 1.73 × 10⁻⁸ s at 5.2 K, respectively), and similar dependence on temperature. The magnetic measurements have revealed the suppression of orbital diamagnetism due to small amount of large enough fragments of the graphene layers.     

Normal Modes of the Global Oceans—A Review

This paper deals with the normal modes of the global oceans. More specifically, it reviews some of the work done in association with the modeling, detection, and application of the barotropic, basin-wide normal modes. The paper presents some results obtained by means of the Proudman-Rao method. The fields of tidal synthesis from a set of normal modes, and paleotides, in the context of normal modes and the evolution of the Earth-Moon system, are surveyed as well. Works associated with the detection of normal modes are discussed also. The paper closes with an analysis of possible future developments.     

Sources of δ18O Concentration Variability in Greenland Ice Cores: Temperature, North Atlantic Oscillation and Solar Activity

This work concerns possible connection between variations of δ¹⁸O in Greenland ice, temperature, precipitation amount, NAO indices and relative sunspot numbers. The relationships between 10-year averaged values of this data were derived making use of regression analysis methods. It was discovered that February temperature yields the main contribution in variability of δ¹⁸O. The multiple correlation coefficient between weighted night temperature of the most important months and δ¹⁸O equals 0.95±0.01. Besides the local source of δ¹⁸O changes, defined by the amount of precipitation and temperature, an additional source correlated with the level of solar activity has been revealed. The relative contribution of this source in the δ¹⁸O variance is about 0.1. It has been shown that the multiple correlation coefficient between δ¹⁸O and NAO indices is equal to 0.85. Therefore the NAO yields more than 2/3 of the variances of climatic change in Greenland. An independent contribution of solar activity in climatic changes is about 1/3.     

Use of terrestrial photosieving and airborne topographic LiDAR to assess bed grain size in large rivers: a study on the Rhine River

Most grain size monitoring is still being conducted by manual sampling in the field, which is time consuming and has low spatial representation. Due to new remote sensing methods, some limitations have been partly overcome, but methodological progress is still needed for large rivers as well as in underwater conditions. In this article, we tested the reliability of two methods along the Old Rhine River (France/Germany) to estimate the grain size distribution (GSD) in above-water conditions: (i) a low-cost terrestrial photosieving method based on an automatic procedure using Digital Grain Size (DGS) software and (ii) an airborne LiDAR topo-bathymetric survey. We also tested the ability of terrestrial photosieving to estimate the GSD in underwater conditions. Field pebble counts were performed to compare and calibrate both methods. The results showed that the automatic procedure of terrestrial photosieving is a reliable method to estimate the GSD of sediment patches in both above-water and underwater conditions with clean substrates. Sensitivity analyses showed that environmental conditions, including solar lighting conditions and petrographic variability, significantly influence the GSD from the automatic procedure in above-water conditions. The presence of biofilm in underwater conditions significantly altered the GSD estimation using the automatic procedure, but the proposed manual procedure overcame this problem. The airborne LiDAR topographic survey is an accurate method to estimate the GSD of above-water bedforms and is able to generate grain size maps. The combination of terrestrial photosieving and airborne topographic LiDAR methods is adapted to assess the GSD over several kilometers long reaches of large rivers. © 2020 John Wiley & Sons, Ltd.     

Engineering geological mapping developed in the Fortaleza Metropolitan Region, State of Ceara, Brazil

Engineering geological mapping was carried out, at a scale of 1:100,000, in the Fortaleza Metropolitan Region, located in northeastern Brazil, to provide engineering geological information as an aid in planning land use and occupation. In this study, eight basic maps were produced drawing: urban areas, lithology, unconsolidated materials in addition to geomorphological map showing slopes, water resources, engineering geological zoning and distribution of geological–geotechnical environmental problems based on information collected through field and laboratory investigations. The region was divided into nine engineering geological zones analyzed in terms of geohazard susceptibility and foundation, excavation and waste disposal conditions.     

Hydrochemical characteristics of groundwater and surface water for domestic and irrigation purposes in Vea catchment,Northern Ghana

The Vea catchment, mainly underlain by crystalline basement rocks, is located in Northern Ghana. Hydrogeochemical studies were carried out in this area with the objective of identifying the geochemical processes influencing water quality and suitability of surface and groundwater for agricultural and domestic uses. Sixty-one groundwater and four surface water samples were collected from boreholes, dams and rivers and analysed for Ca²⁺, Mg²⁺, Na⁺, K⁺, HCO₃ ^?, Cl^?, and SO₄ ^2?, Fe_tot, PO₄ ^3?, Mn_tot, NH₄ ⁺, NO₃ ^?, NO₂ ^?. In addition, pH, total dissolved solids, electrical conductivity, total hardness, turbidity, colour, salinity and dissolved oxygen were analysed. Chloro-alkaline indices 1 and 2, and characterization of weathering processes suggest that the chemistry of groundwater is dominated by the interaction between water and rocks. Cation exchange and silicate weathering are the dominant processes controlling the chemical composition of the groundwater in the area studied. Mineral saturation indices indicate the presence of at least three groups of groundwater in the Vea catchment with respect to residence time. The meteoric genesis index suggests that 86% of the water samples belong to the shallow meteoric water percolation type. The findings further suggest that the groundwater and surface water in the basin studied are mainly Ca–Mg–HCO₃ water type, regardless of the geology. Compared to the water quality guidelines of WHO, the study results on sodium absorption ratio, sodium percentage, magnesium hazard, permeability index and residual sodium carbonate indicate that groundwater and surface water in the Vea catchment are generally suitable for drinking and irrigation purposes.     

Use of geoprocessing in the study of land degradation in urban environments: the case of the city of São Carlos,state of São Paulo,Brazil

This paper presents a methodology for the geological engineering survey of land degradation in urban environments using both remote sensing and geoprocessing tools. The area under study was the city of São Carlos, state of São Paulo, Brazil (urban and expansion area). The data presented here were obtained from earlier studies, photointerpretation and geological engineering mapping. The Envi 4.1 software package was used to prepare the digital orthophotos that served as a reference base for the information. Orthorectification of the Ikonos image (PSM, 1 m) was done and compared with other orthophotos from studies of environmental degradation in urban areas. The evolution of land degradation processes was analyzed based on the photointerpretation of aerial photographs taken on different dates and using Ikonos image. This study allowed to conclude that most of the degradation occurring in the city has been caused by unplanned land occupation, in disregard of environmental conditions, resulting in environmental degradation and thus impacting the quality of life of the urban population.     

Observations on New Approaches for the Determination of Platinum-Group Elements, Gold and Silver in Different Geochemical Samples from Siberia and the Far East

Some recent experiments on the determination of Au and the platinum-group elements (PGE) in geochemical samples are reviewed. Emphasis is given to the determination of ultra-low levels of PGE concentrations in resistant matrices, including chromites, molybdenites and ultrabasic ores. The problems and features of PGE determination in samples of various chemical composition are considered. For each sample type studied, a series of sample preparation techniques are proposed. These techniques included acid digestion, fusion with sodium peroxide, cold sintering with an oxidizing mixture of Na₂O₂+ Na₂CO₃ and also oxidizing fluorination with bromine trifluoride. A new approach for preparing geochemical material prior to digestion, based on mechano-chemical activation with simultaneous hyperfine grinding, is proposed and studied. The instrumental determination of PGE contents was carried out directly by AAS from extracted organic phases. It was found that a combination of digestion processes was required to achieve geochemical background levels of Au and PGE concentrations with the following detection limits: Pd, Rh - 1 ng g⁻¹, Pt, Ru - 10 ng g⁻¹, Au - 0.2 ng g⁻¹, Ag - 0.1 ng g^−1. The uncertainty in PGE and Au determination in geochemical samples is dependent on metal concentration, and also on their distribution in samples. The total analytical uncertainty of the proposed method is between 15-30%.