Updated Expressions for Determining Temperatures and Emission Measures from Goes Soft X-Ray Measurements

{We investigate the conversion of the 0.5–4 and 1–8 Å soft X-ray flux measurements made by detectors on the Geostationary Operational Environmental Satellites (GOES) into temperature and emission measures of coronal plasma using modern spectral models and modern understanding of coronal abundances. In particular, the original analysis by Thomas, Starr and Crannell (1985) is updated to take into account the realization that coronal abundances may be quite different from photospheric abundances. An important result of this analysis is that the derived temperatures and emission measures depend strongly on the assumed abundances even at high temperatures where continuum rather than spectral lines dominates the Sun’s X-ray spectrum. This occurs because the higher coronal abundances mean that most of the continuum is due to free–bound emission processes, not free–free emission, and thus is abundance-dependent. We find significant differences between modern calculations of the temperature response of the flux measurements and the versions currently in use: for a typical flare, emission measures may be up to a factor of 4 smaller than the current software suggests. Derived temperatures are similar for both photospheric and coronal abundances for cool flares (e.g., 15 MK), but for hot flares (e.g., 35 MK) coronal abundances can lead to significantly (~25%) lower temperatures being derived.     

The effect of screening factors and thermonuclear reaction rates in the pre-main sequence evolution of low mass stars

In understanding the nucleosynthesis of the elements in stars, one of the most important quantities is the reaction rate and it must be evaluated in terms of the stellar temperature T, and its determination involves the knowledge of the excitation function σ(E) of the specific nuclear reaction leading to the final nucleus. In this paper, the effect of thermonuclear reaction rates to the pre-main sequence evolution of low mass stars having masses 0.7, 0.8, 0.9 and 1M_⊙ are studied by using our modified Stellar Evolutionary Program.     

Discussion: “Xenoliths in ultrapotassic volcanic rocks in the Lhasa block: direct evidence for crust–mantle mixing and metamorphism in the deep crust” by Wang et al. 2016 (Contributions to Mineralogy and Petrology) 171:62

Wang et al. (Contrib Mineral Petrol 171:62, 2016a) present data on composition of xenolith from Southern Tibet and conclude that ulrapotassic melts from the region formed by melting mantle, and complex interaction with a crustal component. In this discussion we demonstrate that numerous observations presented by Wang et al. (2016a) can be explained by partial melting of crust followed by interaction between that melt and the mantle. We show that this model can explain the variability of magmas in such suits without evoking occurrence of coincidental, unrelated events. Moreover we demonstrate that our model of a crustal origin of the proto-shoshonite melts is now supported by independent lines of evidence such as geochemistry of restites after high- and ultrahigh- pressure melting and melt inclusion studies.     

Stability of phlogopite in ultrapotassic kimberlite-like systems at 5.5–7.5 GPa

Hydrous K-rich kimberlite-like systems are studied experimentally at 5.5–7.5 GPa and 1200–1450?°C in terms of phase relations and conditions for formation and stability of phlogopite. The starting samples are phlogopite–carbonatite–phlogopite sandwiches and harzburgite–carbonatite mixtures consisting of Ol?+?Grt?+?Cpx?+?L (±Opx), according to the previous experimental results obtained at the same P–T parameters but in water-free systems. Carbonatite is represented by a K- and Ca-rich composition that may form at the top of a slab. In the presence of carbonatitic melt, phlogopite can partly melt in a peritectic reaction at 5.5 GPa and 1200–1350?°C, as well as at 6.3–7.0 GPa and 1200?°C: 2Phl?+?CaCO₃ (L)?Cpx?+?Ol?+?Grt?+?K₂CO₃ (L)?+?2H₂O (L). Synthesis of phlogopite at 5.5 GPa and 1200–1350?°C, with an initial mixture of H₂O-bearing harzburgite and carbonatite, demonstrates experimentally that equilibrium in this reaction can be shifted from right to left. Therefore, phlogopite can equilibrate with ultrapotassic carbonate–silicate melts in a?≥?150?°C region between 1200 and 1350?°C at 5.5 GPa. On the other hand, it can exist but cannot nucleate spontaneously and crystallize in the presence of such melts in quite a large pressure range in experiments at 6.3–7.0 GPa and 1200?°C. Thus, phlogopite can result from metasomatism of peridotite at the base of continental lithospheric mantle (CLM) by ultrapotassic carbonatite agents at depths shallower than 180–195 km, which creates a mechanism of water retaining in CLM. Kimberlite formation can begin at 5.5 GPa and 1350?°C in a phlogopite-bearing peridotite source generating a hydrous carbonate–silicate melt with 10–15 wt% SiO₂, Ca# from 45 to 60, and high K enrichment. Upon further heating to 1450?°C due to the effect of a mantle plume at the CLM base, phlogopite disappears and a kimberlite-like melt forms with SiO₂ to 20 wt% and Ca#?=?35–40.     

Crystallization conditions of peraluminous charnockites: constraints from mineral thermometry and thermodynamic modelling

Most igneous charnockites are interpreted to have crystallized at hot and dry conditions, i.e. at >800?°C and <3 wt.% H₂O and with an important CO₂ component in the system. These charnockites are metaluminous to weakly peraluminous and their formation involves a significant mantle-derived component. This study, in contrast, investigates the crystallization conditions of strongly peraluminous, metasediment-sourced charnockites from the Qinzhou Bay Granitic Complex, South China. To constrain the temperature-melt H₂O crystallization paths for the studied peraluminous charnockites, petrographic characterization was combined with fluid inclusion compositional data, mineral thermometry, and thermodynamic modelling. The uncertainties of the thermodynamic modelling in reconstructing the crystallization conditions of the granitic magmas have been evaluated by comparison between modelled and experimental phase relations for a moderately evolved, peraluminous granite (~70 wt.% SiO₂). The comparison suggests that the modelling reproduces the experimentally derived phase saturation boundaries with uncertainties of 20–60?°C and 0.5–1 wt.% H₂O for systems with ≤1–2 wt.% initial melt H₂O at ~0.2 GPa. For the investigated natural systems, the thermometric estimates and modelling indicate that orthopyroxene crystallized at relatively low temperature (750–790?±?30?°C) and moderately high to high melt H₂O content (3.5–5.6?±?0.5 wt.%). The charnockites finally solidified at relatively “cold” and “wet” conditions. This suggests that thermodynamic modelling affords a possible approach to constrain charnockite crystallization as tested here for peraluminous, moderately low pressure (≤0.3 GPa), and overall H₂O-poor systems (≤1–2 wt.% H₂O total), but yields results with increasing uncertainty for high-pressure or H₂O-rich granitic systems.     

A geochemical approach to constraining the formation of glassy fallout debris from nuclear tests

Glassy nuclear fallout debris from near-surface nuclear tests is fundamentally reprocessed earth material. A geochemical approach to analysis of glassy fallout is uniquely suited to determine the means of reprocessing and shed light on the mechanisms of fallout formation. An improved understanding of fallout formation is of interest both for its potential to guide post-detonation nuclear forensic investigations and in the context of possible affinities between glassy debris and other glasses generated by high-energy natural events, such as meteorite impacts and lightning strikes. This study presents a large major-element compositional dataset for glasses within aerodynamic fallout from the Trinity nuclear test (“trinitite”) and a geochemically based analysis of the glass compositional trends. Silica-rich and alkali-rich trinitite glasses show compositions and textures consistent with formation through melting of individual mineral grains—quartz and alkali feldspar, respectively—from the test-site sediment. The volumetrically dominant glass phase—called the CaMgFe glass—shows extreme major-element compositional variability. Compositional trends in the CaMgFe glass are most consistent with formation through volatility-controlled condensation from compositionally heterogeneous plasma. Radioactivity occurs only in CaMgFe glass, indicating that co-condensation of evaporated bulk ground material and trace device material was the main mechanism of radioisotope incorporation into trinitite. CaMgFe trinitite glasses overlap compositionally with basalts, rhyolites, fulgurites, tektites, and microtektites but display greater compositional diversity than all of these naturally formed glasses. Indeed, the most refractory CaMgFe glasses compositionally resemble early solar system condensates—specifically, CAIs.     

A subsidiary fast-diffusing substitution mechanism of Al in forsterite investigated using diffusion experiments under controlled thermodynamic conditions

Diffusion of Al in synthetic forsterite was studied at atmospheric pressure from 1100 to 1500 °C in air along [100] with activities of SiO₂, MgO and Al₂O₃ (a_SiO2, a_MgO and a_Al2O3) buffered. At low a_SiO2, the buffer was forsterite + spinel + periclase (fo + sp + per) at all temperatures, while at high a_SiO2 and subsolidus conditions a variety of three-phase assemblages containing forsterite and two other phases from spinel, cordierite, protoenstatite or sapphirine were used at 1100–1350 °C. Experiments at high a_SiO2 and 1400 °C used forsterite + protoenstatite + melt (fo + en + melt), and at 1500 °C, fo + melt. The resulting diffusion profiles were analysed by LA–ICP–MS in scanning mode. Diffusion profiles in the high a_SiO2 experiments were generally several hundred microns in length, but diffusion at low a_SiO2 was three orders of magnitude slower than in high a_SiO2 experiments carried out at the same temperature, producing short profiles only a few microns in length and close to the spatial resolution of the analytical method. Interface concentrations of Al in the forsterite, obtained by extrapolating the diffusion profiles to the crystal/buffer interface, were only a fraction of those expected at equilibrium, and varied among the differing buffer assemblages according to (a_Al2O3)^1/2 and (a_SiO2)^3/4, pointing to the substitution of Al in forsterite by an octahedral-site, vacancy-coupled (OSVC) component with the stoichiometry Al _4/3 ³⁺ vac_2/3SiO₄, whereas the main substitution expected from previous equilibrium studies would be the coupled substitution of 2 Al for Mg + Si, giving the stoichiometry MgAl₂O₄. It is proposed that this latter substitution is not seen on the length scales of the present experiments because it requires replacement of Si by Al on tetrahedral sites, and is accordingly rate-limited by the slow diffusivity of Si. Instead, diffusion of Al by the OSVC mechanism is relatively fast, and at high a_SiO2, even faster than Fe–Mg interdiffusion.     

金兴定三年(公元1219年)固原地震重新考证

金宣宗兴定三年(公元1219年),在今宁夏回族自治区南部发生强烈地震,现有文献给出的地震次数、地震时间、震中位置差异很大.本文根据我国地震史料和近年固原发现的碑文和地方志记载,考证该强震时间在六月十八日巳时(公历格列历8月6日10时前后);震中在固原南(35.6°N,106.2°E);震级为61/2级;震中烈度为Ⅷ至Ⅸ度.