Morphosedimentary features and recent depositional architectural model of the Cantabrian continental margin

Multibeam bathymetry, high (sleeve airguns) and very high resolution (parametric system-TOPAS-) seismic records were used to define the morphosedimentary features and investigate the depositional architecture of the Cantabrian continental margin. The outer shelf (down to 180–245 m water depth) displays an intensively eroded seafloor surface that truncates consolidated ancient folded and fractured deposits. Recent deposits are only locally present as lowstand shelf-margin deposits and a transparent drape with bedforms. The continental slope is affected by sedimentary processes that have combined to create the morphosedimentary features seen today. The upper (down to 2000 m water depth) and lower (down to 3700–4600 m water depth) slopes are mostly subject to different types of slope failures, such as slides, mass-transport deposits (a mix of slumping and mass-flows), and turbidity currents. The upper slope is also subject to the action of bottom currents (the Mediterranean Water — MW) that interact with the Le Danois Bank favouring the reworking of the sediment and the sculpting of a contourite system. The continental rise is a bypass region of debris flows and turbidity currents where a complex channel-lobe transition zone (CLTZ) of the Cap Ferret Fan develops.The recent architecture depositional model is complex and results from the remaining structural template and the great variability of interconnected sedimentary systems and processes. This margin can be considered as starved due to the great sediment evacuation over a relatively steep entire depositional profile. Sediment is eroded mostly from the Cantabrian and also the Pyrenees mountains (source) and transported by small stream/river mountains to the sea. It bypasses the continental shelf and when sediment arrives at the slope it is transported through a major submarine drainage system (large submarine valleys and mass-movement processes) down to the continental rise and adjacent Biscay Abyssal Plain (sink). Factors controlling this architecture are tectonism and sediment source/dispersal, which are closely interrelated, whereas sea-level changes and oceanography have played a minor role (on a long-term scale).     

Miocene extensional detachments in the outcropping basement of the northern Alboran Basin (Betics) and their tectonic implications

Whether or not there are extensional detachment faults in the Alboran basement can be tested directly because a part of the Alboran Basin is now emerged. These detachments, related to crustal thinning beneath the Alboran Basin, occurred from the Aquitanian to Tortonian. The resulting extensional geometries can be described in general terms. During the Serravalian a considerable southwest extension of the basin took place, accompanied by south-southeast extension in the northern Gibraltar Arc. Other detachments affected by Serravalian extension can be found. The spreading of the Alboran was nearly coeval with roughly westward migration of the Gibraltar mountain front.     

The behaviour of a Cu(II) ion selective electrode in seawater; copper consumption capacity and copper determinations

Determinations of copper consumption capacity (CuCs.C) and labile copper concentrations in surface coastal seawater, using a copper ion selective electrode (Cu-ISE) potentiometric method under predominantly diffusive conditions, are reported. For evaluation of the copper concentrations, the points of the endpoint contiguity zone of the CuCs.C titration curve were treated by an ISE multiple standard addition technique. The results were compared with those obtained by means of a Chelex-100 (calcic form) ‘batch’ procedure-potentiometric stripping analysis.The labile copper of the sample was determined at concentrations down to 10.70 nM with an average RSD of 12%, independent of the Cu-ISE employed. For adjacent subsamples, the mean CuCs.C values obtained for El Way seawater were equivalent to 81.05 and 48.00 nM copper, with an RSD of 4 and 7%, and for Isla Santa Maria seawater the value was equivalent to 70.27 nM copper, with an RSD of 7%. The theoretical approach of the electrode diffusive mechanism proposed, which would depend, fundamentally, on the adsorptive, complexing and reducing properties of the dissolved organic matter in the seawater sample, allows simultaneous analytical determination of CuCs.C and labile copper concentration in seawater.     

Phylogenetic position and systematics of the wood‐associate limpet genus Caymanabyssia and implications for ecological radiation into deep‐sea organic substrates by lepetelloid gastropods

The gastropod superfamily Lepetelloidea represents an extremely diverse lineage in terms of their utilization of different deep‐sea organic substrates that include sunken wood, leaves, whale and fish bones, egg cases of sharks and rays, annelid tubes and detrital cephalopod beaks among others. They also inhabit cold seeps and hydrothermal vents, thus presenting an interesting case for the evaluation of such organic substrates as ‘stepping stones’ into these chemosynthetically nourished environments. Here we show the first molecular phylogeny of the Pseudococculinidae, a primarily wood‐dwelling family and the most speciose in Lepetelloidea. Special emphasis is placed on the genus Caymanabyssia, for which the only subfamily Caymanabyssiinae has been established, and a new species Caymanabyssia solis is described herein and compared with previously known taxa in order to reconsider the morphological characteristics of lepetelloids on wood. Bayesian and likelihood trees reconstructed using four‐gene sequences reveal that Pseudococculinidae sensu auctt. is a polyphyletic taxon that is grouped by shared plesiomorphic conditions of characters including the radula, a digestive organ, the morphology of which is often governed strongly by diet and feeding ecology. The newly reinterpreted families Pseudococculinidae and Caymanabyssiidae represent reciprocal sister clades as a basal radiation in Lepetelloidea. Sunken wood might thus have served as an ancestral habitat from which species on other substrates and vent and seep taxa were derived.     

Stratigraphic framework of gas accumulations in the Ría de Pontevedra (NW Spain)

Knowledge of marine geological environments in which shallow gas is accumulating is becoming increasingly important in global studies of climate change because a measurable proportion of the total methane source comes from continental margins. Previous studies have revealed that coastal environments represent important geological environments where microbial methane is being generated, is accumulating, and is being released. In the Ría de Pontevedra, at least 4.5 km² of seafloor in the innermost part of the ría is underlain by sediments containing natural gas. Seismic interpretation contributes new findings for the definition of periods and geological environments in which the gas could have been generated, and is accumulating and released in the Ría de Pontevedra. Groundtruthing the seismic data (facies, environments) makes it possible to identify favourable geological environments for gas generation in the sedimentary infill of the Ría de Pontevedra. Sequence stratigraphy based on high-resolution seismic profiles and post-Last Glacial Maximum sea-level records makes it possible to establish the stratigraphic architecture of the ría and to define the periods in which gas could have been generated. The results of this study show that the sedimentary infill is composed of a fifth-order sequence developed since the Last Glacial Maximum. Within this sequence, gas appears to have accumulated in the Holocene deposits associated with the latest transgressive and highstand system tracts. Seismic analysis shows that gas could have been generated in different geological environments in the Ría de Pontevedra. If coastal environments at times of lower sea level were similar to those of the present, organic-rich mud deposits (deposited mainly in lakes, estuaries and floodplains) could have survived transgression and remained buried as potential gas sources in the inner part of the ría.     

Dynamics of arrays of floating point-absorber wave energy converters with inter-body and bottom slack-mooring connections

If point absorbers are employed in the extensive exploitation of the offshore wave energy resource, they should be deployed in arrays, the distance between the elements in the array being possibly tens of meters. In such cases, it may be more convenient that the array is spread moored to the sea bottom through only some of its elements, located in the periphery, while the other array elements are prevented from drifting and colliding with each other by connections to adjacent elements. An array of identical floating point absorbers located at the grid points of an equilateral triangular grid is considered in the paper. A spread set of slack-mooring lines connect the peripheric floaters to the bottom. A weight is located at the centre of each triangle whose function is to pull the three floaters towards each other and keep the inter-body mooring lines under tension. The power take-off system (PTO) is a linear damper activated by the buoy heaving motion. The whole system–buoys, moorings and power take-off systems–is assumed linear, so that a frequency domain analysis may be employed. Hydrodynamic interference between the oscillating buoys in array is accounted for. Equations are presented for a set of three identical point absorbers. This is then extended to more complex equilateral triangular grid arrays. Results from numerical simulations, with regular and irregular waves, are presented for the motions and power absorption of hemispherical converters in arrays of three and seven elements and for different mooring parameters and wave incidence angles. Comparisons are given with the unmoored and independently-moored buoy situations.     

Historical record of heavy metals in a highly contaminated Mediterranean deposit: The Besòs prodelta

The Besòs prodelta, located around a highly populated area, receives the discharge of the Besòs River, one of the most contaminated rivers discharging into the Mediterranean sea. The record of heavy metals accumulated in this prodelta is studied to assess the sedimentary behaviour and the history of the anthropogenic heavy metals in the area.

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dated sediments have allowed the identification of the sedimentation patterns and the elaboration of dated heavy metals and cenospheres profiles, which reflected the evolution of the anthropogenic impact in this marine environment. Sediments accumulated during the 18th and 19th centuries were already affected by a moderate heavy metal contamination. This contamination increased drastically in the sediments accumulated during the last decades. This data is well correlated with the increase in industrialisation, population and energy consumption in the Besòs drainage basin during the last century.     

Microscopy and rock magnetism of fine grain-size titanomagnetite from the Jacupiranga Alkaline Complex,Brazil: unearthing Ti-magnesioferrite nanoparticles

Very fine samples from the mineralized zones of the Jacupiranga complex at the Cajati mine were selected for crystallographic identification of Ti-magnesioferrite (TMf) nanostructures embedded in titanomagnetite (TM) using high-resolution transmission electron microscopy (TEM). A magnetic concentrate obtained of pyroxenite samples (sites 4 to 7) was reduced and divided into fractions of distinct range sizes: 26±2 μm, 19±1 μm, 13±1 μm, 9±1 μm, 6±1 μm and 6-0.1 μm. The mineralized samples of carbonatite and pyroxenite were characterized by X-ray diffraction, transmitted and reflected light microscope, and scanning electron microscope with multielemental analysis. The finest magnetic concentrate sample (MC₆) was analyzed under high-resolution transmitted electron microscopy (TEM) and high angle annular dark field and Raman spectroscopy. Magnetic properties were measured for the distinct granulometric fractions, showing drastic changes when grain sizes go beyond the frontier from micro to nanometer sizes. Frequency-dependent magnetic susceptibility percentage (÷_fd%) report higher values (10.2%) for the finer fractions (6±1 μm and 6-0.1 μm) attributed to dominant fractions of superparamagnetic particles. Nanometer and < 6 μm grain size TMf in TM particles require a magnetic field up to 249 mT to reach saturation during the isothermal remanent magnetization experiment. Coercivity and remanent magnetization of these samples increase when the particle size decreases, probably due to parallel coupling effects. Magnetic susceptibility versus temperature experiments were conducted two times on the same (< 35 nm) sample, showing that the repetition during the second heating is probably due to the formation of new TMf nanoparticles and growth of those already present during the first heating process.     

Probabilistic calibration of a distributed hydrological model for flood forecasting

Abstract

The complexity of distributed hydrological models has led to improvements in calibration methodologies in recent years. There are various manual, automatic and hybrid methods of calibration. Most use a single objective function to calculate estimation errors. The use of multi-objective calibration improves results, since different aspects of the hydrograph may be considered simultaneously. However, the uncertainty of estimates from a hydrological model can only be taken into account by using a probabilistic approach. This paper presents a calibration method of probabilistic nature, based on the determination of probability functions that best characterize different parameters of the model. The method was applied to the Real-time Interactive Basin Simulator (RIBS) distributed hydrological model using the Manzanares River basin in Spain as a case study. The proposed method allows us to consider the uncertainty in the model estimates by obtaining the probability distributions of flows in the flood hydrograph.

Citation Mediero, L., Garrote, L. & Martín-Carrasco, F. J. (2011) Probabilistic calibration of a distributed hydrological model for flood forecasting. Hydrol. Sci. J. 56(7), 1129–1149.     

Chemical and isotopic assessment of surface water–shallow groundwater interaction in the arid Grande river basin,North-Central Chile

ABSTRACT

This paper analyses the composition of surface water and shallow groundwater in the Grande River basin, North-Central Chile, using this information to characterize water interactions. Chemical and isotopic data for surface water and groundwater (7 and 6 sampling locations, respectively) were obtained from three sampling campaigns performed in March–April (autumn), August–September (late winter) and December (early summer) 2012. Precipitation samples were also collected. Data was processed using spatial distribution charts, Piper and Stiff diagrams, and multivariate analysis. In general, the results for each method converge on a high degree of connectivity between surface water and shallow groundwater in the study area. Furthermore, approximately a 10% of groundwater contribution to the surface flow discharge was estimated for a particular reach. This multi-method approach was useful for the characterization of surface water–groundwater interactions in the Grande River basin, and may become a suitable and replicable scheme for studies in arid and semi-arid basins facing similar water management challenges.

Editor D. Koutsoyiannis; Associate editor B. Dewals