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131.
Shovan Lal Chattoraj Santanu Banerjee P. K. Saraswati 《Journal of the Geological Society of India》2009,73(4):567-574
Glauconitic minerals are considered as one of the valuable input parameters in sequence stratigraphic analysis of a basin.
In the present study glauconitic minerals are reported from subtidal green shale facies in the lower part of the Late Paleocene-Early
Eocene Naredi Formation of western Kutch. On the basis of the foraminiferal assemblage the glauconite bearing beds are interpreted
to have formed in a mid shelf depositional settings of an unstable marine conditions. XRD studies confirm the glauconite mineralogy
of the green pellets and provide an estimation of glauconite maturity. Textural attributes of the glauconites confirm their
derivation by different degrees of alteration of precursor feldspar grains. Because of the authigenic origin and autochthonous
nature, these glauconites hold promise for understanding sequence stratigraphy of the Palaeogene succession of the western
Kutch. 相似文献
132.
W. A. El-Said D. M. Fouad M. H. Ali M. A. El-Gahami 《International Journal of Environmental Science and Technology》2018,15(8):1731-1744
Green synthesis of nanomaterials has received increasing attention as an eco-friendly technology in materials science. Here, we have used two types of extractions from green tea leaf (i.e., total extraction and tannin extraction) as reducing agents for a rapid, simple and one-step synthesis method of mesoporous silica nanoparticles/iron oxide nanocomposite based on deposition of iron oxide onto mesoporous silica nanoparticles. Mesoporous silica nanoparticles/iron oxide nanocomposite were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, energy-dispersive X-ray, vibrating sample magnetometer, N2 adsorption and high-resolution transmission electron microscopy. Mesoporous silica nanoparticles/iron oxide nanocomposite was used as a solid adsorbent for removal of lindane pesticide from aqueous solutions. The developed system possesses the advantages of silica as core that include large surface area and advantages of iron oxide (shell) that include the capability to interact with chlorinated compounds and ability to release by using external magnetic field. UV-Vis technique was used as a simple and easy method for monitoring the removal of lindane. Effects of pH and temperature on the removal efficiency of the developed mesoporous silica nanoparticles/iron oxide nanocomposite toward lindane pesticide were also investigated. Fourier transform infrared spectroscopy, high-performance liquid chromatography and gas chromatography techniques were used to confirm the high ability of mesoporous silica nanoparticles/iron oxide nanocomposite for sensing and the capture of lindane molecules with high sorption capacity (about 99%) that could develop a new eco-friendly strategy for detection and removal of pesticide and as a promising material for water treatment. 相似文献
133.
Kinetic study of the dehydroxylation of chrysotile asbestos with temperature by in situ XRPD 总被引:6,自引:0,他引:6
The kinetics of the dehydroxylation of chrysotile was followed in situ at high temperature using real-time conventional and
synchrotron powder diffraction (XRPD). This is the first time kinetics parameters have been calculated for the dehydroxylation
of chrysotile. The value of the order of the reaction mechanism calculated using the Avrami model indicates that the rate-limiting
step of the reaction is a one-dimensional diffusion with an instantaneous nucleation or a deceleratory rate of nucleation
of the reaction product. Hence, the rate-limiting step is the one-dimensional diffusion of the water molecules formed in the
interlayer region by direct condensation of two hydrogen atoms and an oxygen atom. The calculated apparent activation energy
of the reaction in the temperature range 620–750 °C is 184 kJ mol−1. The diffusion path is along the axis of the fibrils forming the fibers. The amorphous or short-range ordered dehydroxylate
of chrysotile is extremely unstable because forsterite readily nucleates in the Mg-rich regions. Moreover, it is less stable
than the dehydroxylate of kaolinite, the so-called metakaolinite, which forms mullite at about 950 °C. This difference is
interpreted in terms of the different nature of the two ions Mg2+ and Al3+ and their function as glass modifier and glass-forming ion, respectively.
Received: 10 April 2002 / Accepted: 7 January 2003
Acknowledgements This work is part of a COFIN project (04 Scienze della Terra, NR 17, 2000) supported by MURST. Dr Dapiaggi is kindly acknowledged
for help during the data collection at the Dipartimento di Scienze della Terra, University of Milan. 相似文献
134.
Authigenic carbonate precipitates from the NE Black Sea: a mineralogical,geochemical, and lipid biomarker study 总被引:1,自引:0,他引:1
A. Bahr T. Pape G. Bohrmann A. Mazzini M. Haeckel A. Reitz M. Ivanov 《International Journal of Earth Sciences》2009,98(3):677-695
Carbonate precipitates recovered from 2,000 m water depth at the Dolgovskoy Mound (Shatsky Ridge, north eastern Black Sea)
were studied using mineralogical, geochemical and lipid biomarker analyses. The carbonates differ in shape from simple pavements
to cavernous structures with thick microbial mats attached to their lower side and within cavities. Low δ13C values measured on carbonates (−41 to −32‰ V-PDB) and extracted lipid biomarkers indicate that anaerobic oxidation of methane
(AOM) played a crucial role in precipitating these carbonates. The internal structure of the carbonates is dominated by finely
laminated coccolith ooze and homogeneous clay layers, both cemented by micritic high-magnesium calcite (HMC), and pure, botryoidal,
yellowish low-magnesium calcite (LMC) grown in direct contact to microbial mats. δ18O measurements suggest that the authigenic HMC precipitated in equilibrium with the Black Sea bottom water while the yellowish
LMC rims have been growing in slightly 18O-depleted interstitial water. Although precipitated under significantly different environmental conditions, especially with
respect to methane availability, all analysed carbonate samples show lipid patterns that are typical for ANME-1 dominated
AOM consortia, in the case of the HMC samples with significant contributions of allochthonous components of marine and terrestrial
origin, reflecting the hemipelagic nature of the primary sediment. 相似文献
135.
María Charco José Fernández Francisco Luzón Kristy F. Tiampo John B. Rundle 《Pure and Applied Geophysics》2007,164(4):865-878
Surface displacements and gravity changes due to volcanic sources are influenced by medium properties. We investigate topographic,
elastic and self-gravitation interaction in order to outline the major factors that are significant in data modelling. While
elastic-gravitational models can provide a suitable approximation to problems of volcanic loading in areas where topographic
relief is negligible, for prominent volcanoes the rough topography could affect deformation and gravity changes to a greater
extent than self-gravitation. This fact requires the selection, depending on local relief, of a suitable model for use in
the interpretation of surface precursors of volcanic activity. We use the three-dimensional Indirect Boundary Element Method
to examine the effects of topography on deformation and gravity changes in models of magma chamber inflation/deflation. Topography
has a significant effect on predicted surface deformation and gravity changes. Both the magnitude and pattern of the geodetic
signals are significantly different compared to half-space solutions. Thus, failure to account for topographic effects in
areas of prominent relief can bias the estimate of volcanic source parameters, since the magnitude and pattern of deformation
and gravity changes depend on such effects. 相似文献
136.
The climate–population relationship has long been conceived. Although the topic has been repeatedly investigated, most of
the related works are Eurocentric or qualitative. Consequently, the relationship between climate and population remains ambiguous.
In this study, fine-grained temperature reconstructions and historical population data sets have been employed to statistically
test a hypothesized relationship between temperature change and population growth (i.e., cooling associated with below average
population growth) in China over the past millennium. The important results were: (1) Long-term temperature change significantly
determined the population growth dynamics of China. However, spatial variation existed, whilst population growth in Central
China was shown to be responsive to both long- and short-term temperature changes; in marginal areas, population growth was
only sensitive to short-term temperature fluctuations. (2) Temporally, the temperature–population relationship was obscured
in some periods, which was attributable to the factors of drought and social buffers. In summary, a temperature–population
relationship was mediated by geographic factors, the aridity threshold, and social factors. Given the upcoming threat posed
by climate change to human societies, this study seeks to improve our knowledge and understanding of the climate–society relationship. 相似文献
137.
Actual surface fields of meteorological variables 1–3 hours before the heavy showers are analyzed in detail for the purpose
of their specification with WRF-ARW model. The complex of hygrothermodynamic characteristics needed for this purpose is discovered.
The detailed satellite, radar, and synoptic data are also considered. 相似文献
138.
139.
José Luís Argaín Miguel A. C. Teixeira Pedro M. A. Miranda 《Boundary-Layer Meteorology》2017,165(1):145-160
A method is proposed for estimating the surface-layer depth \((z_s)\) and the friction velocity \((u_*)\) as a function of stability (here quantified by the Obukhov length, L) over the complete range of unstable flow regimes. This method extends that developed previously for stable conditions by Argaín et al. (Boundary-Layer Meteorol 130:15–28, 2009), but uses a qualitatively different approach. The method is specifically used to calculate the fractional speed-up \((\varDelta S)\) in flow over a ridge, although it is suitable for more general boundary-layer applications. The behaviour of \(z_s \left( L\right) \) and \(u_*\left( L\right) \) as a function of L is indirectly assessed via calculation of \(\varDelta S\left( L\right) \) using the linear model of Hunt et al. (Q J R Meteorol Soc 29:16–26, 1988) and its comparison with the field measurements reported in Coppin et al. (Boundary-Layer Meteorol 69:173–199, 1994) and with numerical simulations carried out using a non-linear numerical model, FLEX. The behaviour of \(\varDelta S\) estimated from the linear model is clearly improved when \(u_*\) is calculated using the method proposed here, confirming the importance of accounting for the dependences of \(z_s\left( L \right) \) and \(u_*\left( L \right) \) on L to better represent processes in the unstable boundary layer. 相似文献
140.
Summary The summer monsoon circulation shows various spatial and temporal oscillations and often a combination of systems produces
an integrated effect. In this study phases of the southwest (SW) monsoon have been identified in an objective manner with
the help of T-mode principal component analysis (PCA) of weekly rainfall anomalies. Mean composite charts have been prepared
utilising all available upper air data (1977–1986) for each category of the SW monsoon epochs identified by the PCA. These
sets of charts have been constructed for both the strong and weak phases associated with the first four significant principal
components (PCs).
A well defined east-west oriented trough system, extending from about 28° N Latitude/65° E Longitude to 20° N Latitude/90° E
Longitude, in the lower levels, has been the main feature associated with the strong phase of the monsoon corresponding to
PC I. The trough in the lower levels is more marked in the eastern half compared to the western half in both the sets of charts
associated with strong phases of the monsoon related to the PC II and PC III. With PC II, the position of the troughs in the
lower levels is further north of its location in PC III. The east-west trough system associated with the strong phase of PC
IV has a large southward tilt with height. The charts corresponding to the weak phases of these PCs have synoptic features,
such as the position of the trough close to the foothills of the Himalayas, and the shifting of middle and upper tropospheric
anticyclones to the south.
The study suggests an objective method of interpretation of principal components by utilising synoptic data. In addition,
synoptic models and data sets corresponding to different phases of the monsoon can also be prepared in an objective manner
by such PCA.
Received July 18, 1997 Revised April 30, 1999 相似文献