Paleolimnological reconstructions of Rouyn-Noranda lakes within the zone of influence of the Horne Smelter,Québec,Canada

Diatoms were identified and enumerated from a surface sediment calibration set of 50 lakes in northwestern Québec. The relationship between species composition and environmental variables was examined using canonical correspondence analysis (CCA). Forward selection and Monte Carlo permutation tests in CCA indicated that diatom species distributions in the data set are most strongly correlated to lakewater pH. A strong (r ² _boot = 0.83) weighted averaging calibration model, that includes bootstrapped error estimates, was developed for inferring past lakewater pH. Using this model, temporal changes in pH were reconstructed for two kettle lakes, Lac de la Pépinière and Lac Perron. Based on limnological data, both the study lakes were expected to have recently acidified due to increased acidic precipitation and increases in anthropogenic metal loading. However, our long-term pH inference data indicate that these lakes were naturally acidic during pre-industrial times. Nonetheless, the rate of acidification, particularly in Lac de la Pépinière, has accelerated in the last ∼75 years. These long-term pH records developed for the dilute lakes in northwestern Québec suggest that the region has received increased atmospheric pollutants from the nearby Horne smelter in Rouyn-Noranda. The pH inference profiles are markedly different from many other paleolimnological studies in acid-sensitive regions of Canada that have become acidic primarily as a result of industrial activities. Electronic supplementary material The online version of this article (doi: ) contains supplementary material, which is available to authorized users.     

Assessment of nutrient sources and paleoproductivity during the past century in Longgan Lake,middle reaches of the Yangtze River,China

Total organic carbon (TOC), total nitrogen (TN) and total phosphorus (TP) were determined in combination with stable isotope ratios of carbon and nitrogen (δ¹³C_Org, δ¹⁵N) in a 63 cm sediment core from Longgan Lake, located in the middle reaches of the Yangtze River, China. These geochemical and isotopic records provide a continuous history of lake productivity and trophic state of Longgan Lake since 1890. Variations of δ¹³C_Org, TOC, TN and TP indicate that primary productivity of Longgan Lake increased continuously during the last century and that the trophic state of the lake shifted from oligotrophic to mestrotrophic conditions accordingly. Anthropogenic sources of organic carbon (OC), nitrogen (N) and phosphorus (P) were distinguished from their natural background in the sediments using mass accumulation rates. Element mass accumulation rates suggested increased human activities in the lake’s catchment since 1950s, were especially the utilization of artificial fertilizers amplified the anthropogenic input of N and P into the lake. In the course of the improved availability of dissolved nutrients also primary productivity of Longgan Lake increased, resulting in an increase of the Suess-effect corrected organic carbon isotope ratios. δ¹⁵N of bulk sediments show a marked shift towards lower values around 1950 that has been attributed to the input of nitrogen from chemical fertilizers characterized by relatively depleted isotopic signatures into the lake.     

中国陆地生态系统净初级生产力时空特征模拟

In this paper,we use CEVSA,a process-based model,which has been validated on regional and global scales,to explore the temporal and spatial patterns of Net Primary Productivity (NPP) and its responses to interannual Climate fluctuations in China‘‘‘‘‘‘‘‘s terrestrial ecosystems over the period 1981-1998,The estimated results suggest that ,in this study period,the averaged annual total NPP is about 3.09 Gt C/yr^-1 and average NPP is about 342 g C/m^2,The results also showed that the precipitaion was the key factor determining the spsatial distribution and temporal trends of NPP. Temporally,the total NPP exhibited a slowly increasing trend.In some ENSO years( e.g.1982,1986,1997)NPP decreased clearly compared to the previous year,but the relationship between ENSO and NPP is decreased clearly compared to the previous year,but the relationship between ENSO and NPP is complex due to the integrated effects of monsoons and regional differentiation. Spatially,the relatively high NPP occurred at the middle high latitudes,the low latitudes and the lower appeared at the middle latitudes,On national scale,precipitaion is the key conntro factor on NPP variations and there exists a weak correlation between NP and temperature ,but regional responses are greatly different.     

中国生态地理区域系统区划

Eco-geographic regionalization has been one of the most important topics in China‘s regionalization researches since the end of the 20th century. It is a major ecosystem in geographic zonality. A hierarchical system, which is formed by division or combination of natural features based on geographic relativity and comparison of major ecosystem factors (including biological and non-biological) and geographic zonality, is called eco-geographic regional system. This paper introduces process of China‘s regionalization development. The first level unit, temperature zone, is delineated with main criteria of temperature. The second level unit, humidity region, is based on criteria of water/moisture states. The third level unit, natural region, is divided according to medium geomorphologic units. Vegetation types and soils are applied as supplementary criteria to indicate temperature and water/moisture states. Mapping process from qualitative to quantitative and China‘s eco-geographic regional system are also explained in this paper.     

Factors that contributed to recent eutrophication of two Slovenian mountain lakes

Increased eutrophication was recently observed in the 5th (5J) and 6th (6J) Triglav Lakes, two remote Slovenian mountain lakes. Sediment phosphorus (P) pools were analysed and potential external P sources affecting the lakes (atmospheric deposition, terrestrial export and nearby hut) evaluated, to assess the effects of internal and external changes on the lakes. A sequential extraction procedure was used to quantify five P fractions from the sediments: adsorbed (NH₄Cl–P), redox-sensitive (BD–P), aluminium- (NaOH–P) and calcium- (HCl–P) bound, and refractory organic (Res–P) P. Total phosphorus (TP) contents in surface sediment of 5J and 6J were 1430 and 641 µg P g^?1 dry weight sediment (dw), respectively. TP varied with depth in 5J sediments, but displayed no discernible pattern, whereas it decreased steadily downcore in 6J. Contents of all P forms were distinctly higher in 5J than 6J, but their rank order and relative abundances were similar in the two lakes. Res–P was the most abundant P fraction, followed by HCl–P. Together, the two P forms accounted for nearly 80 and 90% of TP in 5J and 6J sediments, respectively. BD–P and NaOH–P were less abundant, with each fraction accounting for 3 to 9% of TP, whereas NH₄Cl–P was least abundant. Atmospheric deposition and terrestrial export were substantial sources of P for the lakes. Delivery of the former was estimated to be at least 7.5 mg P m^?2 yr^?1 and the latter around 20 mg P m^?2 yr^?1. We concluded that P was not retained in the catchment effectively, likely because of only slightly acidic soil pH (5.9), relatively low aluminium content and high organic matter content (53%) in soils, resulting in higher vulnerability of the studied lakes to eutrophication. The mountain hut could also be a significant source of P for the lakes. Each year, it could potentially contribute ~12 kg of soluble P to the environment, but the true impact of the hut on lake trophic status remains unclear.     

Soil organic carbon storage and soil CO<Subscript>2</Subscript> flux in the alpine meadow ecosystem

High-resolution sampling, measurements of organic carbon contents and ¹⁴C signatures of selected four soil profiles in the Haibei Station situated on the northeast Tibetan Plateau, and application of ¹⁴C tracing technology were conducted in an attempt to investigate the turnover times of soil organic carbon and the soil-CO₂ flux in the alpine meadow ecosystem. The results show that the organic carbon stored in the soils varies from 22.12×10⁴ kg C hm⁻² to 30.75×10⁴ kg C hm⁻² in the alpine meadow ecosystems, with an average of 26.86×10⁴ kg C hm⁻². Turnover times of organic carbon pools increase with depth from 45 a to 73 a in the surface soil horizon to hundreds of years or millennia or even longer at the deep soil horizons in the alpine meadow ecosystems. The soil-CO₂ flux ranges from 103.24 g C m⁻² a⁻¹ to 254.93 gC m⁻² a⁻¹, with an average of 191.23 g C m⁻² a⁻¹. The CO₂ efflux produced from microbial decomposition of organic matter varies from 73.3 g C m⁻² a⁻¹ to 181 g C m⁻² a⁻¹. More than 30% of total soil organic carbon resides in the active carbon pool and 72.8%281.23% of total CO₂ emitted from organic matter decomposition results from the topsoil horizon (from 0 cm to 10 cm) for the Kobresia meadow. Responding to global warming, the storage, volume of flow and fate of the soil organic carbon in the alpine meadow ecosystem of the Tibetan Plateau will be changed, which needs further research. Supported by the National Natural Science Foundation of China (Grant Nos. 40231015, 40471120 and 40473002) and the Guangdong Provincial Natural Science Foundation of China (Grant No. 06300102)     

Cloud radiative forcing in Asian monsoon region simulated by IPCC AR4 AMIP models

This study examines cloud radiative forcing (CRF) in the Asian monsoon region (0^o--50^oN,60^o--150^oE) simulated by Intergovernmental Panel on Climate Change (IPCC) Fourth Assessment Report (AR4) AMIP models. During boreal winter, no model realistically reproduces the larger long-wave cloud radiative forcing (LWCF) over the Tibet Plateau (TP) and only a couple of models reasonably capture the larger short-wave CRF (SWCF) to the east of the TP. During boreal summer, there are larger biases for central location and intensity of simulated CRF in active convective regions. The CRF biases are closely related to the rainfall biases in the models. Quantitative analysis further indicates that the correlation between simulated CRF and observations are not high, and that the biases and diversity in SWCF are larger than that in LWCF. The annual cycle of simulated CRF over East Asia (0^o--50^oN, 100^o--145^oE) is also examined. Though many models capture the basic annual cycle in tropics, strong LWCF and SWCF to the east of the TP beginning in early spring are underestimated by most models. As a whole, GFDL-CM2.1, MPI-ECHAM5, UKMO-HadGAM1, and MIROC3.2 (medres) perform well for CRF simulation in the Asian monsoon region, and the multi-model ensemble (MME) has improved results over the individual simulations. It is suggested that strengthening the physical parameterizations involved over the TP, and improving cumulus convection processes and model experiment design are crucial to CRF simulation in the Asian monsoon region.     

Annual gametogenesis and reproductive effort of the limpet <Emphasis Type="Italic">Cellana grata</Emphasis> (Gould, 1859) (Gastropoda: Nacellidae) in a rocky intertidal beach at Ulleungdo Island off the east coast of Korea

Widely distributed from the northern coast of Vietnam to the northern Japan, the limpet Cellana grata (Gould, 1859) occurs commonly on the south and east coasts of Korea. Despite their wide distribution range, few studies have investigated the annual gametogenesis and reproductive effort of C. grata. In an attempt to understand the reproductive physiology of the limpet, we investigated the annual gametogenesis and reproductive effort of C. grata from Ulleungdo Island off the east coast of Korea. Histology revealed that the gonial mitosis commenced in January, as the female exhibited small oogonia (10–40 μm) in the follicle. From March to June, the oocyte size increased dramatically, and fully mature eggs (110–170 μm in diameter) appeared in early summer. First spawning males and females were observed in July, as the surface seawater temperature (SST) reached 22.1°C. The spawning male and females could be observed until the end of December. Gonad somatic index (GSI), a ratio of gonad mass to the total tissue weight, of the male ranged from 0.6 (April) to 17.9 (July), while the female GSI varied from 1.0 (February) to 18.3 (July). GSI of male and female declined rapidly from July to August, suggesting that the major purse of the spawning at the study site was between July and August. Our study suggested that the commercial catch of C. grata during July and August must be suspended at Ulleungdo Island, in order to protect the spawning limpets, which enhances C. grata recruitment and the population.     

Environmental Geochemistry and Acid Mine Drainage Evaluation of an Abandoned Coal Waste Pile at the Alborz-Sharghi Coal Washing Plant,NE Iran

In this paper, an abandoned waste coal pile, which is resulted from Alborz-Sharghi coal washing plant, NE of Iran was mineralogically and geochemically characterized to evaluate pyrite oxidation, acid mine drainage (AMD) generation, and trace element mobility. After digging ten trenches and vertical sampling, a quantitative method including the atomic absorption test, and the quality-based methods including optical study were carried out for determination of pyrite fractions in the waste pile. The geochemical results revealed that the fraction of remaining pyrite increased with depth, indicating that pyrite oxidation is limited to the shallower depths of the pile which were confirmed by variations of sulfate, pH, EC, and carbonate with depth of the pile. To evaluate the trend of trace elements and mineralogical constituents of the waste particles, the samples were analyzed by using XRD, ICP-MS, and ICP-OES methods. The results showed the secondary and neutralizing minerals comprising gypsum have been formed below the oxidation zone. Besides, positive values of net neutralization potential indicated that AMD generation has not taken in the waste pile. In addition, variations of trace elements with depth reveal that Pb and Zn exhibited increasing trends from pile surface toward the bottom sampling trenches while another of them such as Cu and Ni had decreasing trends with increasing depth of the waste pile.     

The hydrogeology of the military inundation at the 1914–1918 Yser front (Belgium)

Protection against flooding by the sea, drainage of rainwater and integrated management of groundwater and surface-water resources are key issues in low-lying coastal areas. However, under exceptional circumstances, knowledge to keep coastal areas dry and habitable can be used otherwise. Inundation for military purposes is such an example. The hydrogeology of the inundation at the Yser River, Belgium, during the Great War is studied. The inundation started in October 1914 to stop the German advance and lasted until 1918. A water balance and groundwater model are combined to derive the water balance before and during the inundation and to study the impact on the groundwater system. It is concluded that a number of hydrogeological factors contributed to the effectiveness of the inundation. Most importantly, the low-permeability subsoil facilitated loss of inundation water mainly by evaporation. Further, the normal water management strategy of the area (aimed at evacuating excess water towards the sea) was reversed to keep water between the opposing armies. However, the duration of the inundation meant a reorganization of the drainage of areas not inundated; truly an exercise in integrated water management.