A statistically selected Chandra sample of 20 galaxy clusters – I. Temperature and cooling time profiles

We present an analysis of 20 galaxy clusters observed with the Chandra X-ray satellite, focusing on the temperature structure of the intracluster medium and the cooling time of the gas. Our sample is drawn from a flux-limited catalogue but excludes the Fornax, Coma and Centaurus clusters, owing to their large angular size compared to the Chandra field of view. We describe a quantitative measure of the impact of central cooling, and find that the sample comprises nine clusters possessing cool cores (CCs) and 11 without. The properties of these two types differ markedly, but there is a high degree of uniformity amongst the CC clusters, which obey a nearly universal radial scaling in temperature of the form   T ∝ r ^∼0.4  , within the core. This uniformity persists in the gas cooling time, which varies more strongly with radius in CC clusters  ( t _cool∝ r ^∼1.3)  , reaching   t _cool < 1 Gyr  in all cases, although surprisingly low central cooling times (<5 Gyr) are found in many of the non-CC systems. The scatter between the cooling time profiles of all the clusters is found to be remarkably small, implying a universal form for the cooling time of gas at a given physical radius in virialized systems, in agreement with recent previous work. Our results favour cluster merging as the primary factor in preventing the formation of CCs.     

Evolution and Morphodynamics of a Prograded Beach‐Ridge Foreland,Northern Baffin Island,Canadian Arctic Archipelago

Landward retreat (marine transgression) is a common response of coastal systems to rising relative sea level. However, given sufficient sediment supply, the coast may advance seaward. The latter response of gravel barriers has been recorded in parts of southeastern and northwestern Canada, where seaward‐rising sets of beach ridges are observed in areas of Holocene RSL rise. Cape Charles Yorke, northern Baffin Island, is a 5 km long gravel foreland characterized by seaward‐rising beach‐ridge crest elevations. The prograded morphology of the Cape Charles Yorke foreland is a prime example of coastal response to a combination of rising RSL and abundant sediment supply, an unusual and little‐documented pattern in the Canadian Arctic. The main gravel supply to Cape Charles Yorke is likely from eroding bedrock and raised marine deposits southwest of the foreland. Although not the dominant sediment source, the Cape Charles Yorke delta contributed to the formation of the foreland by sheltering it from easterly storm waves and providing an anchor point for the prograding ridges. The truncation of relict ridges by the modern shoreline suggests a recent regime shift from continuous deposition to predominant erosion. The cause and timing of this shift are unknown but could result from a recent dwindling in sediment supply, increased accommodation space, increased wave energy, and/or an accelerated rise of relative sea level.     

Coasts, water levels, and climate change: A Great Lakes perspective

The North American Laurentian Great Lakes hold nearly 20 % of the earth’s unfrozen fresh surface water and have a length of coastline, and a coastal population, comparable to frequently-studied marine coasts. The surface water elevations of the Great Lakes, in particular, are an ideal metric for understanding impacts of climate change on large hydrologic systems, and for assessing adaption measures for absorbing those impacts. In light of the importance of the Great Lakes to the North American and global economies, the Great Lakes and the surrounding region also serve as an important benchmark for hydroclimate research, and offer an example of successful adaptive management under changing climate conditions. Here, we communicate some of the important lessons to be learned from the Great Lakes by examining how the coastline, water level, and water budget dynamics of the Great Lakes relate to other large coastal systems, along with implications for water resource management strategies and climate scenario-derived projections of future conditions. This improved understanding fills a critical gap in freshwater and marine global coastal research.     

Chemical studies of copper-organic complexes isolated from estuarine waters using C18 reverse-phase liquid chromatography

Dissolved organic matter (DOM) and dissolved copper-organic complexes were isolated from the estuarine waters of Narragansett Bay, RI, using reverse-phase liquid chromatography employing C₁₈ Sep-Pak cartridges (Waters Associates). The cartridges were found to have a constant retention efficiency for processing ? 1-l volumes of seawater. Fractionation of the isolated material, by sequential elution of the Sep-Pak with water: methanol mixtures of increasing organic solvent concentration, yielded a fraction of the organic matter with a specific copper activity six times greater than the overall activity for the isolated DOM. Analysis of this fraction by high performance liquid chromatography suggested that the organic components are of intermediate polarity and have appreciable aromatic character.An investigation of the protonation characteristics of the isolated complexes indicated that most of the copper is associated with a broad range of acidic sites on the DOM. Analysis by electron paramagnetic resonance spectroscopy confirmed the organic association of the isolated copper and also suggested the presence of several types of binding sites which probably involve oxygen donor ligands.Studies of the exchange of ⁶⁴Cu with these binding sites on the isolated DOM indicated that 70% of the sites undergo rapid exchange with copper in seawater while 20% of these sites did not exchange in a 24-h time period.     

Isolation of dissolved organic matter and copper-organic complexes from estuarine waters using reverse-phase liquid chromatography

Reverse-phase liquid chromatography was used for the isolation of dissolved organic matter and dissolved copper-organic complexes from the estuarine waters of Narragansett Bay, Rhode Island. The procedure isolates 10–30% of the organic matter and up to 50% of the total dissolved copper from various bay samples. Chromatograms obtained by high-performance liquid chromatography of the isolated organic matter showed qualitative differences between sampling stations progressing from the Providence River in the upper bay to the lower bay.     

Effects of metals and sediment particle size on the species composition of the epifauna of Pinna bicolor near a lead smelter,Spencer Gulf,South Australia

Pinna bicolor (Mollusca: Pelecypoda) were transplanted between four sites near a lead smelter. The species composition of their epifauna (sessile and mobile) was examined in relation to characteristics of both sediments and seston at the sites. Seventy-two taxa were distinguished in the epifaunal community. Substantial differences were found in the short-term sensitivity of some of the species to concentrations of Cd, Pb and Zn in sediments and to sediment particle size. The short-term sensitivity of many species to metals or sediment particle size explained their long-term distribution pattern. Twenty-three taxa were identified as significantly characterizing the faunal differences. Of these, eleven (four molluscs, four bryozoans, two barnacles and one ascidian) were affected by both sediment metal concentration and particle size, and eight (four molluscs, one bryozoan, one polychaete, one hydroid and one barnacle) were affected by metal contamination but not particle size. Of all fauna examined, the Bryozoa were the most metal-sensitive. Four species, Smittina raigii (Bryozoa), Galeolaria sp. 1 (Polychaeta), Epopella simplex (Cirripedia) and Monia ione (Pelecypoda) were identified by their short- and long-term sensitivity to metal contamination, and absence of sensitivity to sediment particle size, as suitable species for monitoring the effects of metal contamination on the epifauna. The implications of the results for toxicity-testing are discussed.     

Chemical comparison of dissolved organic matter isolated from different oceanic environments

Dissolved organic matter was isolated from coastal and open-ocean surface waters having a wide range of biological productivities, and from seawater of intermediate depths. Approximately 50% of the organic matter was recovered by the use of activated-charcoal chromatography. The organic matter isolated from different types of water masses exhibited varying spectroscopic characteristics, and stable carbon-isotope compositions. The ability of the isolated organic matter to interact with copper ions also varied, but over a relatively narrow range which was not exceeded by more than a factor of two by similarly isolated terrigenous organic matter.     

Ice in the Southern Coalsack

To better understand the conditions under which ice mantles form on grains in molecular clouds, three globules in the Southern Coalsack have been searched for the presence of H₂O ice. Given the total lack of star formation in the Coalsack, it is an ideal site for studying unprocessed icy molecular mantles. In our sample of eight field stars lying behind the Coalsack we detect strong H₂O ice absorption in the lines of sight to two stars and possible weak absorption in four others. We estimate H₂O ice column densities or upper limits for these lines of sight. Compared to dark clouds such as Taurus, the Coalsack H₂O ice column densities are lower than expected given the quiescent nature of the Coalsack region. It is possible that the chemical evolution of the Coalsack may simply be at too early a stage for significant ice mantles to appear on the grains, except perhaps in the densest parts of some of the globules. Alternatively, the presence or absence of ice absorption may be related to the distribution of dust along each line of sight, specifically, the relative contributions of dense globules and a more extended diffuse component. For example, our observations are consistent with an ice threshold extinction similar to that observed in the Taurus dark cloud if extinction amounting to   A _V∼5  towards Globules 2 and 3 arises in the extended component. Globule 1 appears to have no extended component.