Possible production by lightning of aerosols and trace gases in Titan's atmosphere

Although lightning has not yet been observed in Titan's atmosphere, the presence of condensable vapors and the deposition of a significant amount of solar energy at the surface suggest the possibility of lightning activity. Based on an understanding of the relationship of lightning activity to the amount of convective energy available on Titan, a lightning energy dissipation rate of 4 × 10^?6, W/m² can be expected. This value is much lower than that for Earth or Jupiter, and is a result of both the reduced solar flux at Titan and the absorption of sunlight by the aerosols that lie above the convective layer. For this dissipation rate, the amount of HCN and C₂N₂ produced by lightning should be greater than that by solar UV, but could be less than that produced by electron precipitation and galactic cosmic rays. Equilibrium calculations indicate that large mole fractions of elemental solid phase carbon will also be produced. Using a simplified model of aerosol formation, coagulation, and settling, it is estimated that a lightning-produced aerosol could have a typical optical depth of 10^?2, with values as high as 0.1. The accumulation of soot over geological time might reach a meter or more in depth.     

Surface features on glass spherules from the Luna 16 sample

Two ellipsoidal spherules approximately 0.5 mm in diameter were studied in detail using a scanning electron microscope. A variety of surface features were observed: vesicles, mounds, dimples, streaks, ridges, grooves, accretion phenomena, and high-speed impact craters. The diameters of 27 glass-lined pits formed by impact on one spherule range from less than 1m to approximately 50m. Intermediate-sized glass-lined pits surrounded by concentric fractures demonstrate the transition between larger craters that have both a pit and a spall zone and generally smaller craters that have only a pit. Assuming all craters showing evidence of impact-related melting or flow are the result of primary impacts, the differential mass spectrum of impacting meteoroids in the range 10^–11 to 10^–10 g is in good agreement with a spectrum based on satellite-borne particle-detecting experiments.     

HST spectral imaging of Titan's haze and methane profile between 0.6 and 1 μm during the 2000 opposition

We report on the analysis of high spatial resolution visible to near-infrared spectral images of Titan at Ls=240° in November 2000, obtained with the Space Telescope Imaging Spectrograph instrument on board the Hubble Space Telescope as part of program GO-8580. We employ a radiative transfer fractal particle aerosol model with a Bayesian parameter estimation routine that computes Titan's absolute reflectivity per pixel for 122 wavelengths by modeling the vertical distribution of the lower atmosphere haze and tropospheric methane. Analysis of these data suggests that Titan's haze concentration in the lower atmosphere varies in strength with latitude. We find Titan's tropospheric methane profile to be fairly consistent with latitude and longitude, and we find evidence for local areas of a CH₄-N₂ binary saturation in Titan's troposphere. Our results suggest that a methane and haze profile at one location on Titan would not be representative of global conditions.     

Stability of mid-latitude snowpacks on Mars

Christensen [2003. Nature 422, 45-48] suggested that runoff from melting snowpacks on martian slopes might be responsible for carving gullies. He also suggested that snowpacks currently exist on Mars, for example on the walls of Dao Valles (approximately 33° S). Such snowpacks were presumably formed during the last obliquity cycle, which occurred about 70,000 years ago. In this paper we investigate a specific scenario under conditions we believe are favorable for snowpack melting. We model the rate at which a snowpack located at 33° S on a poleward-facing slope sublimates and melts on Mars, as well as the temperature profile within the snowpack. Our model includes the energy and mass balance of a snowpack experiencing diurnal variations in insolation. Our results indicate that a dirty snowpack would quickly sublimate and melt under current martian climate conditions. For example a 1 m thick dusty snowpack of moderate density (550 kg/m³) and albedo (0.39) would sublimate in less than two seasons, producing a small amount of meltwater runoff. Similarly, a cleaner snowpack (albedo 0.53) would disappear in less than 9 seasons. These results suggest that the putative snowpack almost certainly could not have survived for 70,000 years. For most of the parameter settings snowpack interior temperatures at this latitude and slope do reach the melting point. Under most conditions melting occurs when the snowpack is less than 10 cm thick. The modeled snowpack will not melt if it is covered by a 1 cm dust lag. In general, these findings raise interesting possibilities regarding gully formation, but perhaps mostly during a past climate regime when snowfall was expected to have occurred. If there currently are exposed snowpacks on martian mid-latitude slopes, then these ice sheets cannot last long. Hence they might be time variable features on Mars and should be searched for.     

Temperature lapse rate and methane in Titan's troposphere

We have reanalyzed the Voyager radio occultation data for Titan, examining two alternative approaches to methane condensation. In one approach, methane condensation is facilitated by the presence of nitrogen because nitrogen lowers the condensation level of a methane/nitrogen mixture. The resulting enhancement in methane condensation lowers the upper limit on surface relative humidity of methane obtained from the Voyager occultation data from 0.7 to 0.6. We conclude that in this case the surface relative humidity of methane lies between 0.08 and 0.6, with values close to 0.6 indicated. In the other approach, methane is allowed to become supersaturated and reaches 1.4 times saturation in the troposphere. In this case, surface humidities up to 100% are allowed by the Voyager occultation data, and thus the upper limit must be set by other considerations. We conclude that if supersaturation is included, then the surface relative humidity of methane can be any value greater than 0.08--unless a deep ocean is present, in which case the surface relative humidity is limited to less than 0.85. Again, values close to 0.6 are indicated. Overall, the tropospheric lapse rate on Titan appears to be determined by radiative equilibrium. The lapse rate is everywhere stable against dry convection, but is unstable to moist convection. This finding is consistent with a supersaturated atmosphere in which condensation-and hence moist convection-is inhibited.     

Visual characterization technique for gravel‐cobble river bed surface sediments; validation and environmental applications Contribution to the programme of CIRSA (Centre Interuniversitaire de Recherche sur le Saumon Atlantique)

This paper presents an evaluation of the feasibility and the reliability of a visual characterization technique for gravel–cobble river bed surface substrate. Based on principal axis regressions, using phi scale (ϕ), comparisons of visual estimation and grid sampling techniques show that useful predictive relations (R² = 0·78–0·88) exist between visual estimates of the surface d₁₆, d₅₀ and d₈₄ and estimates obtained for the same percentiles with the grid sampling technique. Comparisons of visual estimation and the surface‐bulk sampling technique also indicate a predictive relation (R² = 0·70) between the d₅₀ of the two methods. Trained operators can visually estimate gravel–cobble bed surface d₁₆ to uncertainties of 41 per cent, d₅₀ to 15 per cent and d₈₄ to 11 per cent (for example, there is a 5·5 mm error on a d₈₄ size of 50 mm). Furthermore, evidence shows that if operators are properly trained, a calibration relation for each percentile can be applied independently of operators. This visual characterization allows effective detailed mapping of spatial patterns in substrate size distribution along extensive reaches of gravel‐bed rivers. The technique can be very useful in creating terrain models for various geomorphological, hydrological and biological applications such as the determination of entrainment thresholds, hydraulic roughness and substrate suitability for benthic insects or salmonid habitat. Copyright © 2001 John Wiley & Sons, Ltd.     

Deep-sea Fe-Mn Crusts from the Northeast Atlantic Ocean: Composition and Resource Considerations

Eighteen deep-sea ferromanganese crusts (Fe-Mn crusts) from 10 seamounts in the northeast Atlantic were studied. Samples were recovered from water depths of ～1,200 to ～4,600 m from seamounts near Madeira, the Canary and Azores islands, and one sample from the western Mediterranean Sea.

The mineralogical and chemical compositions of the samples indicate that the crusts are typical continental margin, hydrogenetic Fe-Mn crusts. The Fe-Mn crusts exhibit a Co + Cu + Ni maximum of 0.96 wt%. Platinum-group element contents analyzed for five samples showed Pt contents from 153 to 512 ppb.

The resource potential of Fe-Mn crusts within and adjacent to the Portuguese Exclusive Economic Zone (EEZ) is evaluated to be comparable to that of crusts in the central Pacific, indicating that these Atlantic deposits may be an important future resource.     

Seamount Characteristics and Mine-Site Model Applied to Exploration- and Mining-Lease-Block Selection for Cobalt-Rich Ferromanganese Crusts

Regulations are being developed through the International Seabed Authority (ISBA) for the exploration and mining of cobalt-rich ferromanganese crusts. This paper lays out geologic and geomorphologic criteria that can be used to determine the size and number of exploration and mine-site blocks that will be the focus of much discussion within the ISBA Council deliberations. The surface areas of 155 volcanic edifices in the central equatorial Pacific were measured and used to develop a mine-site model. The mine-site model considers areas above 2,500 m water depth as permissive, and narrows the general area available for exploration and mining to 20% of that permissive area. It is calculated that about eighteen 100 km² exploration blocks, each composed of five 20 km² contiguous sub-blocks, would be adequate to identify a 260 km² 20-year-mine site; the mine site would be composed of thirteen of the 20 km² sub-blocks. In this hypothetical example, the 260 km² mine site would be spread over four volcanic edifices and comprise 3.7% of the permissive area of the four edifices and 0.01% of the total area of those four edifices. The eighteen 100 km² exploration blocks would be selected from a limited geographic area. That confinement area is defined as having a long dimension of not more than 1,000 km and an area of not more than 300,000 km².