Numerical simulation of comet nuclei I. Water-ice comets

A one-dimensional simulation of pure water-ice cometary nuclei is presented, and the effect of the nucleus as a heat reservoir is considered. The phase transition from amorphous to crystalline ice is studied for two cases: (1) where the released latent heat goes entirely into heating adjacent layers and (2) where the released latent heat goes entirely into sublimation. For a Halley-like orbit it was found that for case 1 the phase boundary penetrates about 15 m on the first orbit and does not advance until sublimation brings the surface to some 10 m from the phase boundary. For case 2 the phase boundary penetrates about 1 m below the surface and remains at this depth as the surface sublimates. For an orbit like that of Schwassmann-Wachmann 1 the phase boundary penetrates about 50 m initially for case 1 and about 1 m for case 2. There is no further transformation until the entire comet is heated slowly to near the transition temperature, after which the entire nucleus is converted to crystalline ice. For an Encke-type orbit case 1 gives a nearly continuous transition of the entire nucleus to crystalline ice, while for case 2 the initial penetration is about 8 m and remains at this depth relative to the surface as sublimation decreases the cometary radius. Thus the entire comet is converted to crystalline ice just before it is completely dissipated.     

Numerical simulations of comet nuclei: II. The effect of the dust mantle

The insulating effect of an evolving dust mantle is examined. The role of this mantle in determining the surface temperature of the ice core is studied as a function of the mass fraction of the dust in the ice-dust mixture and the thermal conductivity of the nucleus. Using the so-called “looselattice” model of D.A. Mendis and G.D. Brin (1977, Moon17, 359–372) (which was also extended to include cracks and pores in the mantle), it was found that both high dust to ice ratios and high core conductivities inhibit mantle blowoff. Indeed, it is often possible to build an essentially permanent dust mantle around an ice nucleus, so that the nucleus will take on an asteroidal appearance.     

A new microsplitter for unconsolidated sediments

Unrepresentative subsamples can be obtained from a sedimentary sample through repeated subdivision when using a mechanical microsplitter. Physical biases are often compounded by repetition and can result in wide variations among the estimates computed from the relative proportion of foraminifera of a given species. A new microsplitter, designed on a new principle, has been built to separate small representative subsamples. The device is based on the uniform distribution of unconsolidated sediments suspended in water. A subsample of the desired size is obtained by collecting sediment from an appropriate sedimentation area. Operation of this sampler is rapid and convenient and requires only one step, thus eliminating sampling biases introduced by repeated operations with other splitters. This new device was tested and found to be superior to the Otto Microsplitter according to some statistical goodness-of-fit tests conducted on the series.     

Solidification depth and crystallization age of the Shiaidani Granodiorite: Constraints to the average denudation rate of the Hida Range,central Japan

Solidification pressure and crystallization age of the ~5 Ma Shiaidani Granodiorite (Hida Mountain Range, central Japan) are determined based on Al-in-hornblende geobarometry and U–Pb zircon dating. Al-poor patchy replacements developed in amphiboles are common in this granite and petrographic study revealed that the replacements include chloritized biotite and albitic plagioclase. These are probably the hydrothermally recrystallized domains, and should not be used for solidification pressure estimates. Magmatic rim of amphibole is characterized by Si < 7.3 a.p.f.u. (Al_IV > 0.7 a.p.f.u.), and utilized in solidification pressure estimate that yielded 0.17–0.29 GPa. The solidification age of the granite is estimated as ~5.6–5.2 Ma using U–Pb zircon dating. From these data, the lower limit of an average denudation rate after ~5.6–5.2 Ma for the area where Shiaidani Granodiorite is exposed is estimated as 0.93–2.5 mm/year.     

The mobility of thorium in natural waters at low temperatures

Thermodynamic properties of 32 dissolved thorium species and 9 thorium-bearing solid phases have been collected from the literature, critically evaluated and estimated where necessary for 25°C and 1 atm pressure. Although the data are incomplete, especially for thorium minerals and organic complexes, some tentative conclusions can be drawn. Dissolved thorium is almost invariably complexed in natural waters. For example, based on ligand concentrations typical of ground water (ΣCl = 10 ppm, ΣF = 0.3 ppm, ΣSO₄ = 100 ppm, andΣPO₄ = 0.1 ppm), the predominant thorium species are Th(SO₄)⁰₂, ThF²⁺₂, and Th(HPO₄)₂⁰below pH ≈ 4.5; Th(HPO₄)^2?₃ from about pH 4.5 to 7.5; and Th(OH)⁰₄ above pH 7.5. Based on stability constants for thorium citrate, oxalate and EDTA complexes, it seems likely that organic complexes predominate over inorganic complexes of thorium in organic-rich stream waters, swamp waters, soil horizons, and waterlogged recent sediments. The thorium dissolved in seawater is probably present in organic complexes and as Th(OH)⁰₄. The tendency for thorium to form strong complexes enhances its potential for transport in natural waters by many orders of magnitude below pH 7 in the case of inorganic complexing, and below about pH 8 when organic complexing is important. The existence of complexes in addition to those formed with hydroxyl, is apparent from the fact that measured dissolved thorium in fresh surface waters (pH values generally 5–8) usually ranges from about 0.01 to 1 ppb and in surface seawater (pH = 8.1) is about 0.00064 ppb. This may be contrasted with the computed solubility of thorianite in pure water which is only 0.00001 ppb Th as Th(OH)⁰₄ above pH 5. Although complexing increases the solubility of thorium-bearing heavy minerals below pH 8, maximum thorium concentrations in natural waters are probably limited in general by the paucity and slow solution rate of these minerals and by sorption processes, rather than by mineral-solution equilibria.