The M/V Cosco Busan spill: source identification and short-term fate

Understanding the fate of heavy fuel oils (HFOs) in the environment is critical for sound decisions regarding its usage and spill cleanup. To study weathering of HFOs, we examined the M/V CoscoBusan spill (November 2007; San Francisco Bay, CA, USA). In this baseline report, we identified which ruptured tank (port tank 3 or 4) was the source of the spilled oil and characterized changes in the oil composition across location and time. Samples from three impacted shorelines, collected within 80 days of the spill, were analyzed using one- and two-dimensional gas chromatography (GC and GC × GC, respectively). Weathering varied across sites, but compounds with GC retention times less than n-C₁₆ were generally lost by evaporation and dissolution. Changes in n-C₁₈/phytane and benz[a]anthracene/chrysene ratios indicated some biodegradation and photodegradation, respectively.     

Ecohydrologic considerations for modeling of stable water isotopes in a small intermittent watershed

Naturally occurring stable water isotope tracers provide useful information for hydrologic model development and calibration. Existing models include varied approaches concerning unsaturated zone percolation mixing (preferential versus matrix flow) and evapotranspiration (ET) partitioning. We assess the impact of unsaturated zone simplifying assumptions when simulating the Shale Hills Watershed, a small (7.9 ha), temperate, forested watershed near Petersburg, Pennsylvania, USA, with a relatively simple model. We found that different model structures/assumptions and parameterizations of unsaturated zone percolation had substantial impacts on the agreement between simulated and observed unsaturated‐zone water isotopic signatures. We show that unsaturated zone percolation mixing primarily affects the unsaturated zone δ¹⁸O and δ²H during winter and spring and that percolation was best represented as a combination of both preferential and matrix flow. We evaluate the importance and implications related to the partitioning of ET into evaporation and transpiration and demonstrated that incorporation of a plant growth model for ET partitioning substantially improved reproduction of observed hydrologic isotopic patterns of the unsaturated zone during the spring season. We show that unsaturated zone percolation mixing and ET partitioning approaches do not substantially influence stream δ¹⁸O and δ²H and conclude that observed streamflow isotopic data is not always a strong predictor of model performance with respect to intrawatershed processes.     

A Modified Radial Diagram Approach for Evaluating Natural Attenuation Trends for Chlorinated Solvents and Inorganic Redox Indicators

Selection of monitored natural attenuation as a ground water remedy requires that sound scientific documentation clearly illustrating the effectiveness of this remedial alternative be presented to regulatory agencies and concerned citizens. An innovative radial diagram approach is applied to illustrate natural attenuation trends for total benzene, toluene, ethylbenzene, and xylenes (BTEX) and chlorinated ethenes at a former fire training area at Pittsburgh Air Force Base, New York. A BTEX-CAH (chlorinated aliphatic hydrocarbons) radial diagram map shows that concentrations of site contaminants are generally decreasing along the primary flowpath downgradient from the source area. This radial diagram map also suggests that there is a spatial correlation between decreasing CAH parent compound concentrations and increasing or stable daughter product concentrations. This provides secondary evidence of intrinsic biodegradation of TCE downgradient from the source area. A SEQUENCE-Redox™ map suggests that there is a spatial correlation between trends in electron acceptor and metabolic byproduct concentrations, and the decline in total BTEX concentrations downgradient from the source area. This correlation provides secondary evidence for the intrinsic biodegradation of total BTEX in the aquifer. This study demonstrates that radial diagram visual aids can provide a clear and efficient approach for documenting natural attenuation lines of evidence, as an alternative or a complement to using multiple contour maps, tabulated data, or log-linear plots.     

Limitations of single-basket trading: lessons from the Montreal Protocol for climate policy

Numerous policy options exist to reduce future greenhouse gas emissions. A single-basket approach, which controls aggregate emissions, was adopted by the Kyoto Protocol. Such an approach allows emissions reductions of one gas to be traded with those of other gases in the “basket”, with the trade “price” determined by some weighting metric like the Global Warming Potential. To reduce stratospheric ozone depletion, the Montreal Protocol also dealt with controlling many compounds, but did so employing an alternative, multi-basket scheme. Trading was allowed within each basket, but not among baskets. While the Montreal Protocol has been highly successful using this approach, we show that if a single-basket approach had been adopted the short-term success could have been at risk due to the non-unique relationship between controls and environmental impacts when using a single basket. Using climate policy as an example, and without considering technological and economic constraints, we further show that the magnitude of the ambiguities in impacts associated with a single-basket approach depends on the rapidity of the emission phaseout. Fast phaseouts lead to less ambiguity than do slow ones. These results suggest that for each set of greenhouse gas control policies considered, the benefit of additional flexibility associated with a single-basket approach should be weighed against the associated increased uncertainties in the impacts to ascertain whether a single- or a multi-basket approach has the greater chance of successfully mitigating climate change.     

A case of offshore convective initiation by interacting land breezes near Darwin, Australia

A case of offshore convective initiation by interacting land breezes near Darwin, Australia is investigated using convection-permitting model simulations, radar-derived precipitation observations, thermodynamic profiles from radiosonde soundings and surface measurements. These analyses elucidate the convergence of two land breezes in the Van Diemen Gulf, one originating from the Tiwi Islands and the other from mainland Australia; the convergence is sufficient to initiate a line of convection that forms parallel to the mainland coast in the early morning. While differing in small-scale features, the modeled system shows reasonably good agreement with the observed precipitation accumulations. However, using simulations with different initialization times and examining a second case, it is shown that the representation of the land-breeze system and subsequent convective initiation is very sensitive to the upstream wind and thermodynamic conditions, making correct simulation of these processes challenging.     

Observations of planview flux patterns within convective structures of the marine atmospheric surface layer

Air/sea flux variability on horizontal scales from 50 m to several km results, in part, from the presence of coherent convective structures within the atmospheric boundary layer. The horizontal distribution of fluxes within these convective updrafts and downdrafts is, therefore, central to studies of air/sea interaction and remote sensing of sea surface wind and wave fields. This study derives these flux patterns from observations of the Marine Atmospheric Surface Layer (MASL).Research aircraft flights through the MASL provide an optimal means for sampling large numbers of the above-mentioned coherent structures. The NCAR Electra flew numerous legs through the MASL at a height of 50 m during the 1987 stratocumulus phase of Project FIRE (First ISSCP (International Satellite Cloud Climatology Program) Regional Experiment).In situ measurements from these legs serve as the dataset for this paper. The data are processed in such a way as to retain only the turbulence fluctuations. Conditional sampling, based on the vertical velocity field, results in the isolation of convective updrafts and downdrafts. Compositing of the data for these two classes of convective drafts results in horizontal planviews of the vertical fluxes of buoyancy, absolute humidity, along-meanwind component of momentum, and vertical velocity. To ensure dynamical similarity, these horizontal planviews are oriented in a coordinate system aligned with the mean wind.     

Utilization of Landsat data to quantify land-use and land-cover changes related to oil and gas activities in West-Central Alberta from 2005 to 2013

Land use and land cover (LULC) change detection associated with oil and gas activities plays an important role in effective sustainable management practices, compliance monitoring, and reclamation assessment. In this study, a mapping methodology is presented for quantifying pre- and post-disturbance LULC types with annual Landsat Best-Available-Pixel multispectral data from 2005 to 2013. Annual LULC and land disturbance maps were produced for one of the major conventional oil and gas production areas in West-Central Alberta with an accuracy of 78% and 87%, respectively. The highest rate of vegetation loss (178 km²/year) was observed in coniferous forest compared to broadleaf forest, mixed forest, and native vegetation. Integration of ancillary oil and gas geospatial data with annual land disturbances indicated that less than 20% of the total land disturbances were attributable to oil and gas activities. In 2013, approximately 44% of oil and gas disturbances from 2005 to 2013 showed evidence of vegetation recovery. In the future, geospatial data related to wildfire, logging activities, insect defoliation, and other natural and anthropogenic factors can be integrated to quantify other causes of land disturbances.     

DME/TACAN interference mitigation for GNSS: algorithms and flight test results

The Galileo E5a/E5b signals and the Global Positioning System (GPS) L5 signal lie within the aeronautical radionavigation services (ARNS) band. They suffer interference from the services in this frequency band, in particular, pulsed signals from distance measuring equipment (DME) and tactical air navigation (TACAN) systems. To maintain system accuracy and integrity, interference mitigation is beneficial and necessary. We first present the real DME/TACAN environment at Stanford, CA as an example to illustrate the need for mitigating DME/TACAN interference. We then propose a time and frequency joint mitigation algorithm—Hybrid Blanking and its simplified version, frequency domain adaptive filtering (FDAF) for hardware implementation. Finally, a flight measurements campaign was performed over a European DME/TACAN hotspot near Frankfurt, Germany, to record a worst-case DME interference environment. Recorded data from the flight tests mixed with injected GNSS signals verify the effectiveness of the proposed mitigation algorithm.     

Changes in timber haul emissions in the context of shifting forest management and infrastructure

The issues surrounding 'Reduced Emissions from Deforestation and Forest Degradation' (REDD) have become a major component of continuing negotiations under the United Nations Framework Convention on Climate Change (UNFCCC). This paper aims to address two key requirements of any potential REDD mechanism: first, the generation of measurable, reportable and verifiable (MRV) REDD credits; and secondly, the sustainable and efficient provision of emission reductions under a robust financing regime. To ensure the supply of MRV credits, we advocate the establishment of an 'International Emission Reference Scenario Coordination Centre' (IERSCC). The IERSCC would act as a global clearing house for harmonized data to be used in implementing reference level methodologies. It would be tasked with the collection, reporting and subsequent processing of earth observation, deforestation- and degradation driver information in a globally consistent manner. The IERSCC would also assist, coordinate and supervise the computation of national reference scenarios according to rules negotiated under the UNFCCC. To overcome the threats of "market flooding" on the one hand and insufficient economic incentives for REDD on the other hand, we suggest an 'International Investment Reserve' (IIR) as REDD financing framework. In order to distribute the resources of the IIR we propose adopting an auctioning mechanism. Auctioning not only reveals the true emission reduction costs, but might also allow for incentivizing the protection of biodiversity and socio-economic values. The introduced concepts will be vital to ensure robustness, environmental integrity and economic efficiency of the future REDD mechanism.     

Biogeochemical transformation of Fe minerals in a petroleum-contaminated aquifer

The Bemidji aquifer in Minnesota, USA is a well-studied site of subsurface petroleum contamination. The site contains an anoxic groundwater plume where soluble petroleum constituents serve as an energy source for a region of methanogenesis near the source and bacterial Fe(III) reduction further down gradient. Methanogenesis apparently begins when bioavailable Fe(III) is exhausted within the sediment. Past studies indicate that Geobacter species and Geothrix fermentens-like organisms are the primary dissimilatory Fe-reducing bacteria at this site. The Fe mineralogy of the pristine aquifer sediments and samples from the methanogenic (source) and Fe(III) reducing zones were characterized in this study to identify microbiologic changes to Fe valence and mineral distribution, and to identify whether new biogenic mineral phases had formed. Methods applied included X-ray diffraction; X-ray fluorescence (XRF); and chemical extraction; optical, transmission, and scanning electron microscopy; and Mössbauer spectroscopy.All of the sediments were low in total Fe content (≈ 1%) and exhibited complex Fe-mineralogy. The bulk pristine sediment and its sand, silt, and clay-sized fractions were studied in detail. The pristine sediments contained Fe(II) and Fe(III) mineral phases. Ferrous iron represented approximately 50% of Fe_TOT. The relative Fe(II) concentration increased in the sand fraction, and its primary mineralogic residence was clinochlore with minor concentrations found as a ferroan calcite grain cement in carbonate lithic fragments. Fe(III) existed in silicates (epidote, clinochlore, muscovite) and Fe(III) oxides of detrital and authigenic origin. The detrital Fe(III) oxides included hematite and goethite in the form of mm-sized nodular concretions and smaller-sized dispersed crystallites, and euhedral magnetite grains. Authigenic Fe(III) oxides increased in concentration with decreasing particle size through the silt and clay fraction. Chemical extraction and Mössbauer analysis indicated that this was a ferrihydrite like-phase. Quantitative mineralogic and Fe(II/III) ratio comparisons between the pristine and contaminated sediments were not possible because of textural differences. However, comparisons between the texturally-similar source (where bioavailable Fe(III) had been exhausted) and Fe(III) reducing zone sediments (where bioavailable Fe(III) remained) indicated that dispersed detrital, crystalline Fe(III) oxides and a portion of the authigenic, poorly crystalline Fe(III) oxide fraction had been depleted from the source zone sediment by microbiologic activity. Little or no effect of microbiologic activity was observed on silicate Fe(III). The presence of residual “ferrihydrite” in the most bioreduced, anoxic plume sediment (source) implied that a portion of the authigenic Fe(III) oxides were biologically inaccessible in weathered, lithic fragment interiors. Little evidence was found for the modern biogenesis of authigenic ferrous-containing mineral phases, perhaps with the exception of thin siderite or ferroan calcite surface precipitates on carbonate lithic fragments within source zone sediments.