Ecohydrologic considerations for modeling of stable water isotopes in a small intermittent watershed

Naturally occurring stable water isotope tracers provide useful information for hydrologic model development and calibration. Existing models include varied approaches concerning unsaturated zone percolation mixing (preferential versus matrix flow) and evapotranspiration (ET) partitioning. We assess the impact of unsaturated zone simplifying assumptions when simulating the Shale Hills Watershed, a small (7.9 ha), temperate, forested watershed near Petersburg, Pennsylvania, USA, with a relatively simple model. We found that different model structures/assumptions and parameterizations of unsaturated zone percolation had substantial impacts on the agreement between simulated and observed unsaturated‐zone water isotopic signatures. We show that unsaturated zone percolation mixing primarily affects the unsaturated zone δ¹⁸O and δ²H during winter and spring and that percolation was best represented as a combination of both preferential and matrix flow. We evaluate the importance and implications related to the partitioning of ET into evaporation and transpiration and demonstrated that incorporation of a plant growth model for ET partitioning substantially improved reproduction of observed hydrologic isotopic patterns of the unsaturated zone during the spring season. We show that unsaturated zone percolation mixing and ET partitioning approaches do not substantially influence stream δ¹⁸O and δ²H and conclude that observed streamflow isotopic data is not always a strong predictor of model performance with respect to intrawatershed processes.     

Simulation and statistical modelling approaches to investigate hydrologic regime transformations following Eastern hemlock decline

Ecohydrological processes occurring at or near the Earth's surface are strongly influenced by Eastern hemlock [EH; Tsuga canadensis (L.) Carrière], a foundation tree species of eastern North American forests. EH populations are currently threatened by the invasive hemlock woolly adelgid (HWA; Adelges tsugae Annand). HWA HWA populations have been expanding rapidly throughout the EH's range. Catchment-scale research examining the hydrological consequences of HWA infestation is lacking, and plot-scale studies remain conflicted in their findings. Given the complex relationships between canopy interception, unsaturated and saturated groundwater storage, and root water uptake, it is not immediately clear how EH loss will affect the hydrologic cycle. We investigated the impact of EH mortality on stream discharge characteristics across a regional sample of catchments utilizing both simulation and statistical modelling approaches. We first examined the relationship between various catchment characteristics, including EH health, and three hydrological variables through regression analysis. We then employed a non-parametric statistical test to evaluate differences in hydrologic regime trends between non-infested and infested catchments. Finally, we calibrated a physically based hydrologic model and considered differences in optimal model parameter values and simulated overland runoff between non-infested and infested catchments. HWA presence modified several ecohydrological characteristics and precipitation partitioning between groundwater flows and surface runoff, potentially driving higher stream flashiness and overland flow, lower baseflow contributions and catchment storage, shorter flow-path lengths, and variable source area dilation at infested sites. Our results suggest that EH decline will augment flooding potential associated with the increasing frequency and intensity of Atlantic Basin tropical cyclone events. Further, our physically based simulation provides more determinate results than regression analysis, indicating that a purely statistical methodology, commonly utilized in studying the relationship between landcover characteristics and hydrologic regime, neglects dynamic physical ecohydrologic relationships.     

The M/V Cosco Busan spill: source identification and short-term fate

Understanding the fate of heavy fuel oils (HFOs) in the environment is critical for sound decisions regarding its usage and spill cleanup. To study weathering of HFOs, we examined the M/V CoscoBusan spill (November 2007; San Francisco Bay, CA, USA). In this baseline report, we identified which ruptured tank (port tank 3 or 4) was the source of the spilled oil and characterized changes in the oil composition across location and time. Samples from three impacted shorelines, collected within 80 days of the spill, were analyzed using one- and two-dimensional gas chromatography (GC and GC × GC, respectively). Weathering varied across sites, but compounds with GC retention times less than n-C₁₆ were generally lost by evaporation and dissolution. Changes in n-C₁₈/phytane and benz[a]anthracene/chrysene ratios indicated some biodegradation and photodegradation, respectively.     

Electrical Resistivity Imaging of a Permanganate Injection During In Situ Treatment of RDX‐Contaminated Groundwater

Groundwater beneath the former Nebraska Ordnance Plant (NOP) is contaminated with the explosive hexahydro‐1,3,5‐trinitro‐1,3,5‐triazine (RDX) and trichloroethene (TCE). Previous treatability experiments confirmed that permanganate could mineralize RDX in NOP aquifer material. The objective of this study was to determine the efficacy of permanganate to transform RDX in the field by monitoring a pilot‐scale in situ chemical oxidation (ISCO) demonstration. In this demonstration, electrical resistivity imaging (ERI) was used to create two‐dimensional (2‐D) images of the test site prior to, during, and after injecting sodium permanganate. The ISCO was performed by using an extraction‐injection well configuration to create a curtain of permanganate. Monitoring wells were positioned downgradient of the injection zone with the intent of capturing the permanganate‐RDX plume. Differencing between ERI taken preinjection and postinjection determined the initial distribution of the injected permanganate. ERI also quantitatively corroborated the hydraulic conductivity distribution across the site. Groundwater samples from 12 downgradient wells and 8 direct‐push profiles did not provide enough data to quantify the distribution and flow of the injected permanganate. ERI, however, showed that the permanganate injection flowed against the regional groundwater gradient and migrated below monitoring well screens. ERI combined with monitoring well samples helped explain the permanganate dynamics in downgradient wells and support the use of ERI as a means of monitoring ISCO injections.     

Quaternary features beneath Lake Simcoe,Ontario, Canada: drumlins,tunnel channels,and records of proglacial to postglacial closed and overflowing lakes

Lake Simcoe is a large lake 45 km across and in places over 30 m deep, located between Lake Huron and Lake Ontario, in the glaciated terrain of southern Ontario, Canada. Seismostratigraphic analysis of high-resolution seismic reflection profiles, together with lakebed sediment sampling and pollen study, revealed distinctive sequences in the sediments beneath Lake Simcoe, Ontario. A surface unit (Blue Sequence) of soft Holocene mud (low-amplitude surface reflection, discontinuous parallel internal reflections) lies in the deeper basins of the lake. The underlying unit (Green Sequence) is characterized by high-amplitude parallel internal reflections; basal sediments of this sequence consist of clay rhythmites with dropstones. The Green Sequence was deposited by lacustrine sedimentation in proglacial Lake Algonquin; sedimentation persisted until the basin was isolated from other glacial lakes at about 10 ¹⁴C ka at the Penetang post-Algonquin phase. Subsequent erosion of the uppermost portion of the Green Sequence is attributed to wave action in a low-level early Holocene lake, possibly closed hydrologically and coeval with closed lowstands in the Huron and Georgian Bay basins. Two sequences with high-amplitude surface reflections and chaotic internal reflections (Purple and Red Sequences) lie below the Green Sequence. Northeast-southwest trending ridges, tens of metres in height, on the Red Sequence (the lowermost of these two units) are interpreted to be drumlins. An erosion surface descends into narrow valleys 50–80 m deep beneath the lake in bays to the west and south of the main lake basin. These depressions are interpreted as subglacial tunnel channels cut by rapid flows of meltwater. The sediments of Purple Sequence are interpreted as channel-fill sediments rapidly deposited during waning stages of the meltwater drainage. The Red Sequence is correlated with the Newmarket Till of the last glacial maximum identified beneath the Oak Ridges Moraine to the south.     

Temperature as a Tool to Evaluate Aerobic Biodegradation in Hydrocarbon Contaminated Soil

This study evaluates the theory, and some practical aspects of using temperature measurements to assess aerobic biodegradation in hydrocarbon contaminated soil. The method provides an easily applicable alternative for quantifying the rate of biodegradation and/or evaluating the performance of in situ remediation systems. The method involves two nonintrusive procedures for measuring vertical temperature profiles down existing monitoring wells; one using a thermistor on a cable for one‐time measurements and the other using compact temperature data loggers deployed for 3‐month to 1‐year period. These vertical temperature profile measurements are used to identify the depth and lateral extent of biodegradation as well as to monitor seasonal temperature changes throughout the year. The basic theory for using temperature measurements to estimate the minimum rate of biodegradation will be developed, and used to evaluate field measurements from sites in California where biodegradation of spilled petroleum hydrocarbons is due to natural processes. Following, temperature data will be used to evaluate the relative rates of biodegradation due to natural processes and soil vapor extraction (SVE) at a former refinery site in the North‐Central United States. The results from this study show that the temperature method can be a simple, cost effective tool for assessing biodegradation in the soil, and optimizing remediation systems at a wide variety of hydrocarbon spill sites.     

Courage under fire: Seagrass persistence adjacent to a highly urbanised city–state

Due to increasing development Southeast Asia’s coastlines are undergoing massive changes, but the associated impacts on marine habitats are poorly known. Singapore, a densely populated island city–state, is a quintessential example of coastal modification that has resulted in the (hitherto undocumented) loss of seagrass. We reconstructed the historic extent and diversity of local seagrass meadows through herbarium records and backwards extrapolation from contemporary seagrass locations. We also determined the current status of seagrass meadows using long-term monitoring data and identified the main threats to their presence in Singapore. Results show that, even though ∼45% of seagrass has been lost during the last five decades, species diversity remains stable. The main cause of seagrass loss was, and continues to be, land reclamation. We conclude that strict controls on terrestrial runoff and pollution have made it possible for seagrass to persist adjacent to this highly urbanised city–state.     

Evidence of biogeomorphic patterning in a low‐relief karst landscape

Patterned landscapes are often evidence of biotic control on geomorphic processes, emerging in response to coupled ecosystem processes acting at different spatial scales. Self‐reinforcing processes at local scales expand patches, while self‐inhibiting processes, operating at a distance, impose limits to expansion. In Big Cypress National Preserve (BICY) in southwest Florida, isolated forested wetland depressions (cypress domes) appear to be evenly distributed within a mosaic of short‐hydroperiod marshes and pine uplands. To test the hypothesis that the apparent patterning is regular, we characterized frequency distributions and spatial patterns of vegetation communities, surface and bedrock elevation, and soil properties (thickness and phosphorus content). Nearest neighbor distances indicate strongly significant wetland spatial overdispersion, and bedrock elevations exhibited periodic spatial autocorrelation; both observations are consistent with regular patterning. Bedrock elevations and soil P were clearly bimodal, suggesting strong positive feedbacks on wetland patch development. Soil‐surface elevations exhibited weaker bimodality, indicating smoothing of surface morphology by some combination of sediment transport, mineral reprecipitation, and organic matter production. Significant negative autocorrelation of bedrock elevations at scales similar to wetland spacing suggest the presence of distal negative feedbacks on patch expansion. These findings support the inference of regular patterning, and are consistent with the presence of local positive feedbacks among hydroperiod, vegetation productivity and bedrock dissolution. These processes are ultimately constrained by distal negative feedbacks, potentially induced by landscape scale limitations on the water volume required to enable this biogeomorphic mechanism. Copyright © 2014 John Wiley & Sons, Ltd.     

RAT J1953+1859: a dwarf nova discovered through high amplitude QPOs in quiescence

We report the discovery of an accreting binary, RAT J1953+1859, made during the RApid Temporal Survey (RATS) on the Isaac Newton Telescope. It showed high amplitude (0.3 mag) quasi-periodic oscillations on a time-scale of ∼20 min. Further observations made using the Nordic Optical Telescope showed it to be ∼4 mag brighter than in the discovery images. These photometric observations, together with radial velocity data taken using the William Herschel Telescope, point to an orbital period of ∼90 min. These data suggest that RAT J1953+1859 is a dwarf novae of the SU UMa type. What makes RAT J1953+1859 unusual is that it is the first such system to be discovered as a result of high amplitude QPOs during quiescence. This suggests that high-cadence wide-field surveys could be another means to discover cataclysmic variables as a result of their short period variability.