Dissolved inorganic carbon (DIC) and its carbon isotopic composition in sediment pore waters from the Shenhu area,northern South China Sea

The Shenhu area is one of the most favorable places for the occurrence of gas hydrates in the northern continental slope of the South China Sea. Pore water samples were collected in two piston cores (SH-A and SH-B) from this area, and the concentrations of sulfate and dissolved inorganic carbon (DIC) and its carbon isotopic composition were measured. The data revealed large DIC variations and very negative δ ¹³C-DIC values. Two reaction zones, 0–3 mbsf and below 3 mbsf, are identified in the sediment system. At site SH-A, the upper zone (0–3 mbsf) shows relatively constant sulfate and DIC concentrations and δ ¹³C-DIC values, possibly due to bioturbation and fluid advection. The lower zone (below 3 mbsf) displays good linear gradients for sulfate and DIC concentrations, and δ ¹³C-DIC values. At site SH-B, both zones show linear gradients, but the decreasing gradients for δ ¹³C-DIC and SO₄ ²⁻ in the lower zone below 3 mbsf are greater than those from the upper zone, 0–3 mbsf. The calculated sulfate-methane interface (SMI) depths of the two cores are 10.0 m and 11.1 m, respectively. The depth profiles of both DIC and δ ¹³C-DIC showed similar characteristics as those in other gas hydrate locations in the world oceans, such as the Blake Ridge. Overall, our results indicate an anaerobic methane oxidation (AMO) process in the sediments with large methane flux from depth in the studied area, which might be linked to the formation of gas hydrates in this area.     

Nonlinear influences on ocean waves observed by X-band radar

The purpose of this study is to discuss the influence of signal nonlinearity upon X-band radar observations. A method for estimating the degree of nonlinearity by bispectral analysis was applied and discussed. We found that bispectral analyses from spatial radar backscatter series are similar to results obtained from water level time series. In addition, the average nonlinear degree from radar backscatter is related to wind speed. The accuracy of wave observations derived by consideration of the nonlinear effect from radar backscatter was also investigated. The estimated error in wave height from the radar data is also related to the degree of nonlinearity. In order to improve accuracy, the modulation transfer function method was applied in order to eliminate the influence of nonlinearity.     

Numerical simulation of Pacific water intrusions into Otsuchi Bay,northeast of Japan,with a nested-grid OGCM

A numerical simulation of Otsuchi Bay located on the northeast coast of the Honshu, the largest island of Japan, is conducted, using an ocean general circulation model (OGCM) with a nested-grid system in order to illustrate seasonal variability of the circulation in the bay. Through a year, an anticlockwise circulation is dominant in the bay, as observational studies have implied, although it is modified in the bay-mouth-half of the bay in winter. In addition, there is an intense outflow at the surface layer during spring to autumn, influenced by river water discharge. Intrusion of the Pacific water into the bay is influened by mean circulations, but it is also influenced by baroclinic tides from spring to autumn. Pacific water intrusions affected by baroclinic tides may have an impact on the environment in Otsuchi Bay.     

Underwater observations of the giant spoon worm <Emphasis Type="Italic">Ikeda taenioides</Emphasis> (Annelida: Echiura: Ikedidae) in a subtidal soft-bottom environment in northeastern Japan,which survived tsunamis of the 2011 off the Pacific Coast of Tohoku Earthquake

Tsunamis associated with the 2011 off the Pacific Coast of Tohoku Earthquake seriously disrupted the shallow marine ecosystem along a 2000 km stretch of the Pacific coast of Japan. The effects of the 2011 tsunamis on the soft-bottom benthic community have been relatively well studied in the intertidal zone, whereas tsunami effects on the subtidal benthos remain poorly understood. Here, we investigated populations of the world’s largest spoon worm Ikeda taenioides (Annelida: Echiura: Ikedidae) in subtidal zone of Funakoshi Bay, Tohoku District, northeastern Japan. Subtidal scuba-diving surveys at two sites in the bay showed extremely long proboscises frequently extending from small holes in the sandy seafloor shortly before and soon after the tsunami disturbances. Based on morphological and molecular identification, the proboscises were revealed to be parts of I. taenioides. On 30 November 2011, 265 days after the tsunami event, many large-sized individuals with >1 m long proboscises were observed; these individuals were probably not derived from post-tsunami larval recruitment but more likely survived the tsunami disturbances. This is surprising because other sympatric megabenthos (e.g. spatangoid echinoids and venerid bivalves) and seagrass beds were almost completely destroyed (although they later recovered) by the tsunamis in this bay. The burrows of I. taenioides are known to be very deep (70–90 cm), which may have sheltered them from the impacts of the tsunamis. Our observations suggest that the effects of the 2011 tsunamis on benthos in soft sediments may differ depending on their burrowing depth.     

Optimization of dissolved urea measurements in coastal waters with the combination of a single reagent and high temperature

Urea is an unstable and intermediate organic nitrogenous compound present in coastal environments and is derived from the excretion of some aquatic organisms and wastewater discharges. Urea plays an important role in the nitrogen cycle, where it is utilized by algae, including diatoms. However, there are very limited relevant data on the production, consumption, and degradation of urea because of the lack of appropriate measurement techniques. The conventional method is based on the formation of a colored product when urea reacts with diacetyl monoxime in a sulfuric acid solution. We examined the optimal conditions for the formation of the colored product; specifically, we evaluated different temperatures (22–80 °C), reaction times, mixing ratios of color reagents, and sample storage times. Application of the single mixed color-developing reagent (COLDER) at 70 °C resulted in the optimal formation of the colored product within a short reaction time of 60 min. This method was then used to measure dissolved urea in different coastal environments. The concentrations detected were as follows: 0.65–0.72, 0.49–0.58, and 1.09–2.28 µM urea-N at coral reef, seagrass, and mangrove sites, respectively. Our results showed high precision (SD = 0.02, CV = 1.2%), a low detection limit (0.03 µM urea-N), and a high recovery rate (94–99%). In summary, this high-temperature procedure for urea measurements should be valuable for obtaining high-precision data that can further the understanding of urea dynamics and its role in coastal ecosystems.     

A note on ocean surface drift with application to surface velocities measured with HF Radar

The ocean drift current consists of a (local) pure drift current generated by the interaction of wind and waves at the sea surface, to which the surface geostrophic current is added vectorially. We present (a) a similarity solution for the wave boundary layer (which has been validated through the prediction of the 10-m drag law), from which the component of pure drift current along the direction of the wind (and hence the speed factor) can be evaluated from the 10-m wind speed and the peak wave period, and (b) a similarity solution for the Ekman layers of the two fluids, which shows that under steady-state neutral conditions the pure drift current lies along the direction of the geostrophic wind, and has a magnitude 0.034 that of the geostrophic wind speed. The co-existence of these two similarity solutions indicates that the frictional properties of the coupled air-sea system are easily evaluated functions of the 10-m wind speed and the peak wave period, and also leads to a simple expression for the angle of deflection of the pure drift current to the 10 m wind. The analysis provides a dynamical model for global ocean drift on monthly and annual time scales for which the steady-state neutral model is a good approximation. In particular, the theoretical results appear to be able to successfully predict the mean surface drift measured by HF Radar, which at present is the best technique for studying the near surface velocity profile.     

Spatio-temporal variability in sea surface temperatures for the Yellow Sea based on MODIS dataset

The spatio-temporal variabilities in sea surface temperature (SST) were analyzed using a time series of MODIS datasets for four separate regions in the Yellow Sea (YS) that were located along a north-south axis. The space variant temporal anomaly was further decomposed using an empirical orthogonal function (EOF) for estimating spatially distributed SST. The monthly SSTs showed similar temporal patterns in each region, which ranged from 2.4°C to 28.4°C in the study years 2011 to 2013, with seasonal cycles being stronger at the higher latitudes and weaker at the lower latitudes. Spatially, although there were no significant differences among the four regions (p < 0.05) in any year, the geographical distribution of SST was characterized by an obvious gradient whereby SST decreased along the north-south axis. The monthly thermal difference among regions was largest in winter since the SST in the southeast was mainly affected by the Yellow Sea Warm Currents. The EOF1 mode accounted for 56% of the total spatial variance and exhibited a warming signal during the study period. The EOF2 mode accounted for 8% of the total variance and indicated the warm current features in the YS. The EOF3 mode accounted for 6% of the total variance and indicated the topographical features. The methodology used in this study demonstrated the spatio-temporal variabilities in the YS.     

<Emphasis Type="Italic">Zostera marina</Emphasis> seed burial can be enhanced by Manila clam <Emphasis Type="Italic">Ruditapes philippinarum</Emphasis>: A microcosm study

Seagrass seed bank plays a key role in the regeneration of new vegetation when seagrasses are removed by the natural or man-made disaster. Various factors may affect the development of sediment seed bank. We conducted a microcosm experiment to test the effects of burrowing and feeding activities of Manila clam, Ruditapes philippinarum on the burial of Zostera marina seeds in sediments. The effects of lasting time (3-hour, 1-day, 3-day, 7-day, 14-day and 28-day), clam density (0, 2, 4 and 8 clams with shell length of 3 cm in each microcosm) and clam size (shell length of 2, 3 and 4 cm at 4-clam density) on seed burial were examined in plastic microcosm cores (30 cm high × 10 in inner diameter) in a 28-day period. Results showed that the seed burial depth significantly increased with time, the density and the size of clams. No seeds were buried in the sediment in the cores without clams during the whole experiment period. For the 3-cm clams, about 91.61% of the seeds were buried in the sediment at the end of the experiment in the high-density treatment (8 clams at each core); while in the medium and low-density treatments (4 and 2 clams in each core, respectively), about 76.93% and 60.61% of the seeds were buried in the sediment, respectively. For the size treatments, large (4 cm) clams buried 89.56% of the seeds at the end of the experiment, much more than those of medium (3 cm, 76.93%) and small (2 cm, 61.50%) size clams. During the whole experiment period, nearly all of the buried seeds were at a depth of from 0 cm to 5 cm. These results suggested that Manila clam Ruditapes philippinarum may play an important positive role in seagrass seed bank dynamics in the field.     

Numerical simulation of groundwater flowing to horizontal seepage wells under a river

A horizontal seepage well, consisting of an interconnected vertical well, galleries, chambers and small-diameter radiating bores, is used to acquire relatively clean water that has been filtered through natural alluvial deposits in a riverbed. It has wide application, especially in arid and semi-arid areas. The lack of calculation formulae or models for horizontal seepage wells, up until now, has resulted in several false applications. Based on the analysis of groundwater flow characteristics, it has been concluded that several flow regimes coexist and hydraulic head loss exists in the horizontal seepage well. To avoid the difficulty of confirming the flux or head distribution in such a complex system, the model boundary of the whole horizontal seepage well has been moved to that of just the vertical well, and the well-aquifer system was treated as a heterogeneous medium, where the horizontal seepage well itself is a highly permeability medium. A mathematical model has been developed, based on the coupled seepage-pipe flow, by the introduction of equivalent hydraulic conductivity according to different flow regimes. Then a three-dimensional finite difference numerical model, based on the mathematical model, was developed and applied to a horizontal seepage well in China. The numerical model verified the groundwater flow characteristics of the horizontal seepage well. An erratum to this article can be found at     

Paleoproterozoic quartz-pebble conglomerate type uranium mineralisation in Mankarhachua area,Angul district,Orissa

Ground Radiometric survey of Paleoproterozoic pyritiferous quartz-pebble conglomerate (QPC) occurring to the north of Pallahara area led to the discovery of a QPC type uranium mineralisation near Mankarhachua village. Significant radioactivity is recorded in three sub-parallel uraniferous QPC horizons with metamorphosed pebbly to medium grained recrystallised massive sandstones. Detrital grains of uranothorite, thorite, radioactive allanite, monazite, zircon, minute uraninite grains in carbonaceous matter and thucolite contributes to the radioactive phases present in QPC matrix. Adsorbed U on limonite and goethite, secondary uranyl minerals in matrix, along bedding planes and fractures are commonly observed. This discovery has opened up a new horizon for future exploration for QPC type uranium mineralization in the area. The paper presents observations on geology, radioactivity, petrological and geochemical nature of the uraniferous QPC horizons.