Activity–composition relations for phases in petrological calculations: an asymmetric multicomponent formulation

For petrological calculations, including geothermobarometry and the calculation of phase diagrams (for example, P–T petrogenetic grids and pseudosections), it is necessary to be able to express the activity–composition (a–x) relations of minerals, melt and fluid in multicomponent systems. Although the symmetric formalism—a macroscopic regular model approach to a–x relations—is an easy-to-formulate, general way of doing this, the energetic relationships are a symmetric function of composition. We allow asymmetric energetics to be accommodated via a simple extension to the symmetric formalism which turns it into a macroscopic van Laar formulation. We term this the asymmetric formalism (ASF). In the symmetric formalism, the a–x relations are specified by an interaction energy for each of the constituent binaries amongst the independent set of end members used to represent the phase. In the asymmetric formalism, there is additionally a "size parameter" for each of the end members in the independent set, with size parameter differences between end members accounting for asymmetry. In the case of fluid mixtures, for example, H₂O–CO₂, the volumes of the end members as a function of pressure and temperature serve as the size parameters, providing an excellent fit to the a–x relations. In the case of minerals and silicate liquid, the size parameters are empirical parameters to be determined along with the interaction energies as part of the calibration of the a–x relations. In this way, we determine the a–x relations for feldspars in the systems KAlSi₃O₈–NaAlSi₃O₈ and KAlSi₃O₈–NaAlSi₃O₈–CaAl₂Si₂O₈, for carbonates in the system CaCO₃–MgCO₃, for melt in the melting relationships involving forsterite, protoenstatite and cristobalite in the system Mg₂SiO₄–SiO₂, as well as for fluids in the system H₂O–CO₂. In each case the a–x relations allow the corresponding, experimentally determined phase diagrams to be reproduced faithfully. The asymmetric formalism provides a powerful and flexible way of handling a–x relations of complex phases in multicomponent systems for petrological calculations.     

青藏高原东部全新世冬夏季风变化的高分辨率泥炭记录

在建立了全新世泥炭沉积物高分辨率冬夏季风代用指标时间序列的基础上, 发现青藏高原若尔盖地区全新世冬夏季风的变化具有此消彼长和同时消长两种基本的模式, 冬季风与夏季风在不同时间尺度上两种模式又相互嵌套. 由冬夏季风指标叠加效应合成的气候状况却有与全球同步的规律性, 表现出千年-百年尺度的不稳定性, 6.2 ka的季风突然减弱事件要比8.0 ka的事件更显著, 反映了亚洲季风的区域特点或它本身就是全球气候的一个窗口.     

The effect of organic materials on the mobility and toxicity of metals in contaminated soils

Organic materials such as compost are often proposed as suitable materials for the remediation of contaminated brownfield sites intended for soft end-use. In addition to vitalising the soil, they are also believed to immobilise metals thereby breaking contaminant-receptor pathways and reducing the ecotoxicity of the contaminants. However, some research has demonstrated contradictory effects between composts on metal immobilisation. In the present study, four different composts and a liming product containing organic matter (LimeX70) were tested to examine both their metal retention and toxicity reduction capabilities on three different metal contaminated soils. Leaching tests, a plant growth test with Greek cress (Lepidium sativum), an earthworm (Eisenia fetida) survival and condition test and a bacterial toxicity test using Vibrio fischeri were carried out. The leaching test results showed that spent mushroom compost caused an increase in metal concentration in the leachates, while LimeX70 caused a decrease. The variation in behaviour between different amendments for each soil was high, so a generic conclusion could not be drawn. Toxicity tests showed significant reduction of metal bioavailability and toxicity for Greek cress, earthworms and bacteria. The results also suggest that more research should be undertaken to understand the mechanisms involved in metal complexation using different types of organic matter, in order to optimise the use of organic materials like compost for soil remediation.     

A Discussion of IGS Solutions and Their Impact on Geodetic and Geophysical Applications

The International Association of Geodesy officially established the International GPS Service (IGS) on Janaury 1, 1994. Its prime objective is to provide support and a rerefence system for a wide variety of scientific and practical applications involving GPS. To fulfill its role the IGS also generates, in addition to its fundamental products (orbital/staion positions and consistent Earth orientation parameters), additional reference-system products providing the necessary infrastructure, standards, and means of calibrations for timing and various atmospheric applications of GPS. The generation and efficient application of IGS products and their impact on a number of positioning and atmospheric applications, including low earth orbit satellites, is reviewed and discussed. @ 1998 John Wiley & Sons, Inc.     

Tropical Cyclone Size Change under Ocean Warming and Associated Responses of Tropical Cyclone Destructiveness: Idealized Experiments

The power dissipation index (PDI), which is defined as the sum of the cube of tropical cyclone (TC) maximum wind speed during TC lifetime, is widely used to estimate the TC destructive potential. However, due to the lack of high-resolution observations, little attention has been paid to the contribution of TC size change to TC destructive potential in response to ocean warming. In this study, sensitivity experiments are performed by using the high-resolution Weather Research and Forecasting (WRF) model to investigate the responses of TC size and TC destructive potential to prescribed sea surface temperature (SST) increase under the present climate condition. The results show that TC size increases with the ocean warming. Possible reasons for TC size change are investigated with a focus on the outer air-sea moisture difference (ASMD). As SST increases, ASMD in the outer zone of the TC is larger than that in the inner zone, which increases the surface entropy flux (SEF) of the outer zone. This change in the radial distribution of SEF causes the increase of tangential wind in the outer zone, which further increases SEF, resulting in a positive feedback between outer-zone SEF and outer-zone tangential wind. This feedback leads to the increase of the radius of gale-force wind, leading to the expansion of TC size. Moreover, to estimate the contribution of TC size change to TC destructiveness, we calculate TC size-dependent destructive potential (PDS) as the storm size information is available in the model outputs, as well as PDI that does not consider the effect of TC size change. We find that PDS increases exponentially as SST increases from 1 to 4°C, while PDI increases linearly; hence the former is soon much greater than the latter. This suggests that the growth effect of TC size cannot be ignored in estimating destructiveness under ocean warming.     

基于植被状态指数的全国干旱遥感监测试验研究(Ⅰ)--资料分析与处理部分

在收集处理了了1981～1994年连续504旬的由NOAA AVHRR第1、2通道的反射率计算得的NDVI时间系列数据,以及1980～1994年全国102个固定农气观测站的旬土壤湿度资料(-20cm)和相应测站的田间持水量资料基础上,分析了全国NDVI及植被状态指数VCI的时空变化特征,发现NDVI值随季节(旬)分别表现为“双峰型”和“单峰型”的变化,在第17～27旬之间达到极大值,并与作物生长有关,VCI的变化与NDVI的变化呈相反趋势;对资料因站点的分布和密度以及时序位相等差异可能影响资料代表性的探讨认为：因旱情发展有一个过程,故NDVI、SHI的时空特性应该不会影响其分析结果的代表性。综合分析了资料的时空代表性,为干旱遥感监测模型的建立作准备。     

Little River Experimental Watershed,a keystone in understanding of coastal plain watersheds

The US Department of Agriculture-Agricultural Research Service Southeast Watershed Research Laboratory (SEWRL) initiated a hydrologic research program on the Little River Experimental Watershed (LREW) in 1967. Long-term (52 years) streamflow data are available for nine sites, including rainfall-runoff relationships and hydrograph characteristics regularly used in research on interactive effects of climate, vegetation, soils, and land-use in low-gradient streams of the US EPA Level III Southeastern Plains ecoregion. A summary of prior research on the LREW illustrates the impact of the watershed on building a regional understanding of hydrology and water quality. Climatic and streamflow data were used to make comparisons of scale across the nine nested LREW watersheds (LRB, LRF, LRI, LRJ, LRK, LRO, LRN, LRM, and LRO3) and two regional watersheds (Alapaha and Little River at Adel). Annual rainfall for the largest LREW, LRB, was 1200 mm while average annual streamflow was 320 mm. Annual rainfall, streamflow, and the ratio between annual streamflow and rainfall (Sratio) were similar (α = 0.05) across LREWs LRB, LRF, LRI, LRJ, LRK, and LRO. While annual rainfall within the 275 ha LRO3 was found to be similar to LRO and LRM (α = 0.05), annual streamflow and Sratio were significantly different (α = 0.05). Comparisons of annual rainfall, streamflow, and Sratio between LRB and the regional watersheds indicated no differences (α = 0.05). Based upon this analysis, most regional watersheds shared similar hydrologic characteristics. LRO3 was an exception, where increases in row crops and decreases in forest coverage resulted in increased streamflow. LREW data have been instrumental in building considerable scientific understanding of flow and transport processes for these stream systems. Continued operation of the LREW hydrologic network will support hydrologic research as well as environmental quality and riparian research programs that address emerging and high priority natural resource and environmental issues.     

Reporting negative results to stimulate experimental hydrology: discussion of “The role of experimental work in hydrological sciences – insights from a community survey”*

ABSTRACT

Experimental work in hydrology is in decline. Based on a community survey, Blume et al. showed that the hydrological community associates experimental work with greater risks. One of the main issues with experimental work is the higher chance of negative results (defined here as when the expected or wanted result was not observed despite careful experimental design, planning and execution), resulting in a longer and more difficult publishing process. Reporting on negative results would avoid putting time and resources into repeating experiments that lead to negative results, and give experimental hydrologists the scientific recognition they deserve. With this commentary, we propose four potential solutions to encourage reporting on negative results, which might contribute to a stimulation of experimental hydrology.