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Predicting size effect on diffusion-limited current density of oxygen reduction by copper wire

The size effect of copper wire radius (0.04–0.82 mm) on the diffusion-limited current density of an oxygen reduction reaction in stagnant simulated seawater (naturally aerated 0.5 mol/L NaCl) is investigated by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) and compared with the results obtained in 0.5 mol/L H2SO4. In the oxygen diffusion-limited range, size effect is found to occur independent of electrolytes, which is attributed to non-linear diffusion. Additionally, to sati...     

Distribution of nutrients and eutrophication assessment in the Bohai Sea of China

Water samples were collected in 120 stations in the Bohai Sea of China to analyze the distribution of dissolved nutrients and assess the degree of eutrophication in August 2002. The result shows that the average concentration of DIN increased and the PO4-P concentration sharply decreased compared to the previous data of corresponding period. The high concentrations of DIN and PO4-P occurred in coastal waters, especially in the bays and some river estuaries, while the high concentrations of SiO3-Si in the surface and middle depth occurred in the central area of the Bohai Sea. The average ratio of DIN/ PO4-P was much higher than the Redfield Ratio (16:1). Apparently, PO4-P was one of the limiting nutrient for phytoplankton growing in the sea. The average concentrations of DON and DOP were higher than their inorganic forms. The results of eutrophication assessment show that 22.1% of all stations were classified as violating the concentration levels of the National Seawater Quality Standard (GB 3097-1997) for DIN and only 3.9% for PO4-P. The average eutrophication index in the overall area was 0.21±0.22 and the high values occurred in Bohai Bay, Liaodong Bay and near the Yellow River estuary. This means that the state of eutrophication was generally mesotrophic in the Bohai Sea, but relatively worse in the bays, especially some river estuaries.     

Can Eddy Forcing be Responsible for the Spatial Structure of the Northern Hemisphere Annular Mode?

In order to study the origin of the spatial structure of the Northern Hemisphere Annular Mode (NAM),a linear stochastic model is constructed empirically from the output of a GCM run.Optimal stochastic forcing in terms of the maximum variance contribution,which may be potentially related to the maintenance of the NAM,is investigated.Theoretical analysis on the dominant non-modal response to the stochastic forcing shows that this dominance is jointly decided by the properties of forcing and the non-modal grow...     

Correlation Between Total Lightning Activity and Precipitation Particle Characteristics Observed from 34 Thunderstorms

A total of 34 thunderstorms around Shanghai and Wuhan of China are analyzed in order to determine the relationship between total lightning activity and precipitation particle characteristics.Precipitation particle concentration data are obtained from the 2A12 product of TRMM/TMI(Tropical Rainfall Measuring Mission/TRMM Microwave Image) and lightning activity data are from the TRMM/LIS(Lightning Imaging Sensor) and SAFIR3000(Surveillance et Alerte Founder par Interferometric Radioelectirque).On a spatial ...     

The Ground Deformation Disaster in the City of Tianjin Associated with the Tangshan Earthquake

In this paper,a study of the principal characteristics of the ground deformation disasters in the city of Tianjin caused by the Tangshan earthquake is based on the results from the recent remeasurements of the geodetic controlling network of Tianjin and from on-site investigations after the earthquake.These results show that only the ground deformation in the Ninghe and Hangu areas near the epicenter reflect directly the co-seismic crustal stress,while the serious ground deformation and the engineering earthquake damages in the urban districts of Tianjin are controlled to a great extent by the local engineering geological structures,showing a kind of secondary disaster.Several suggestions are also proposed in the paper concerning the counter-measures for reducing the earthquake damage in big cities.     

The Mathematic Models of the Kalman Filtering for Across-Fault Measurement

This paper makes a probe into the application of the Kalman filtering method to the data processing of across-fault measurements.On the basis of statistical regression,the mathematic and stochastic models of filtration are established by combining the regression method with Kalman filtering.In the filtering computation,not only the randomness of fault movements but also the time-dependent variation of environmental effects have been taken into consideration.By use of the adaptive filtering method,an estimation of the dynamic noise variance matrix is obtained through iteration.Models for one measuring line(leveling line or baseline),two measuring lines(both leveling lines or both baselines)and four measuring lines(two leveling lines and two baselines)are derived and established systematically.By means of these models,the data of across-fault measurements can be processed dynamically in real-time to provide the filtered values of height difference between benchmarks or baseline length at different time in     

NUMERICAL EXPERIMENT OF THE INFLUENCES OF HEAT AND WIND STRESS ON THE EQUATORIAL OCEAN CIRCULATION

A time-dependent linear model on the equatorial beta plane is developed in this paper.Its verticalstructure consists of two active layers with equal density and temperature above the thermocline and aquasi-stationary layer with constant density below the thermocline.The results of nurnericat experiments show that the direct influence of heat on the equatorial ocean ismuch smaller than that of wind stress.Nevertheless,through the tropical ocean-atmosphere interaction,the change of wind stress resulting from the thermal forcing may set a determinant effect on the equilibriumand anomalous development of the ocean-almosphere circulation.     

THERMODYNAMIC PROPERTIES AND ROLE OF THERMALS IN THE STRATUS-TOPPED BOUNDARY LAYER

From results of two large-eddy simulation of stratus-topped boundary layer,the structure,thermodynamic prop-erties and role of thermals are investigated by using conditional sampling methods,which divided the thermals into thewarm/moist,cool/dry,warm/dry and cool/moist events.The results show that the main turbulent circulation in thestratus-topped boundary layer is composed of the warm/moist updraft and cool/dry downdraft.Below entrainmentregion,the warm/moist updrafts and cool/dry downdrafts are,respectively,positively and negatively buoyant andcontribute most to total fluxes and variances.Evaporative cooling has important effect on the structure and thermodynamic properties of thermals instratus-topped boundary layer.     

衍射指标h和k的互换问题

通过衍射线指标和面网指标的联系讨论了晶体的对称性对衍射指标h和k互换的影响。在下列情况下衍射指标h和k是不能互换的:在低级晶族;在四方晶系C_(4h)—4/m劳厄点群,六方品系C_(6h)—6/m劳厄点群和立方晶系T_h—m3劳厄点群对于hko和kkl型衍射;在三方晶系选取六方晶胞的情况下,在C_(3i)—3劳厄点群对于hol,okl,hko和hkl型衍射,在D_(3d)—3m劳厄点群对于holokl和hkl型衍射,以及在菱面体点阵除非h和k都是三的倍数。