Powder- and single crystal Mössbauer spectroscopy on synthetic fayalite

Mössbauer measurements on synthetic iron orthosilicate Fe₂SiO₄ (fayalite) were carried out in the antiferromagnetic spin state below T _N 65 K. The Mössbauer parameters isomer shift , inner magnetic field H(0), angle between H(0) and the z-component of the electric field gradient (efg), quadrupole splitting QS and asymmetry parameter were determined as a function of temperature. These parameters could be attributed to the two crystallographic sites M1 and M2.The smaller isomer shift on M1 with respect to M2 displays the more covalent character of the Fe-O bond on M1, which is supported by previous neutron diffraction experiments. H(0) shows a Brillouin-type behaviour with different fields on the two crystallographic sites (stronger on M1) and a small discontinuity at T = 23 K which corresponds with previous magnetic measurements. The quadrupole splitting is equal on both sites within error bars, in agreement with previous theoretical results and in contradiction to previous Mössbauer refinements published elsewhere.     

Ionospheric Joule dissipation as a damping mechanism for high latitude ULF pulsations: Observational evidence

On 9 January 1979 an SI-excited pulsation event was observed by the Scandinavian Magnetometer Array. The pulsation period shows a clear variation with latitude which suggests decoupled oscillations of individual magnetic field shells. The pulsation amplitudes exhibit an e-fold decay with the damping rate γ varying both in longitudinal and latitudinal directions. Assuming Joule heating in the ionosphere as the dominant damping mechanism (and thus γ ～ Σ^?1_p) approximate height-integrated Pedersen conductivity profiles were calculated which fit well with previously observed Σ_p distributions. This is interpreted as observational evidence for ionosopheric Joule dissipation as the major damping mechanism for high-latitude ULF-pulsations.     

Multi-decadal synthesis of benthic–pelagic coupling in the western arctic: Role of cross-shelf advective processes

Using geographic information systems (GIS) software and geostatistical techniques, we utilized three decades of water-column chlorophyll a data to examine the relative importance of autochthonous versus allochthonous sources of reduced carbon to benthic communities that occur from the northern Bering to the eastern Beaufort Sea shelf. Spatial trend analyses revealed areas of high benthic biomass (>300 g m⁻²) and chlorophyll (>150 mg m⁻²) on both the southern and northern Chukchi shelf; both areas are known as depositional centers for reduced organic matter that originates on the Bering Sea shelf and is advected northward in Anadyr and Bering shelf water masses. We found a significant correlation between biomass and chlorophyll a in the Chukchi Sea, reflective of the strong benthic–pelagic coupling in a system that is utilized heavily by benthic-feeding marine mammals. In contrast, there was no significant correlation between biomass and chlorophyll in the Beaufort Sea, which by comparison, is considerably less productive (biomass and chlorophyll, <75 g m⁻² and <50 mg m⁻², respectively). One notable exception is an area of relatively high biomass (50–100 g m⁻²) and chlorophyll (80 mg m⁻²) near Barter Island in the eastern Beaufort Sea. Compared to other adjacent areas in the Beaufort Sea, the chlorophyll values in the vicinity of Barter Island were considerably higher and likely reflect a long-hypothesized upwelling in that area and close coupling between the benthos and autochthonous production. In the Bering Sea, a drop in benthic biomass in 1994 compared with previous measurements (1974–1993) may support earlier observations that document a decline in biomass that began between the 1980s and 1990s in the Chirikov Basin and south of St. Lawrence Island. The results of this study indicate that the benthos is an excellent long-term indicator of both local and physical advective processes. In addition, this work provides further evidence that secondary production on arctic shelves can be significantly augmented by reduced carbon advected from highly productive adjacent shelves.     

Dissolved oxygen variations in alpine glacial meltwaters

Recent models of chemical weathering in alpine glacial meltwaters suggest that sulphide oxidation is a major source of solute in the distributed component of the subglacial hydrological system. This reaction requires O₂, and may lower dissolved oxygen levels to below saturation with respect to the atmosphere. This should result in an inverse association between SO₇^2- and dissolved oxygen saturation. However, measurements of O₂ saturation in bulk meltwaters draining the Haut Glacier d'Arolla, Switzerland, show that there is a positive association between SO₄^2- and O₂ saturation. The O₂ content of glacial meltwaters depends on the initial content of snow and icemelt, which may be controlled by the rate of melting, and the kinetic balance between O₂ losses (e.g. sulphide oxidation, microbial respiration) and gains (e.g. diffusion of O₂ into solution).     

Misconceptions about the Hubble recession law

Almost all astronomers now believe that the Hubble recession law was directly inferred from astronomical observations. It turns out that this common belief is completely false. Those models advocating the idea of an expanding universe are ill-founded on observational grounds. This means that the Hubble recession law is really a working hypothesis. One alternative to the Hubble recession law is the tired-light hypothesis originally proposed by Zwicky (Proc. Nat. Acad. Sci. 15:773, 1929). This hypothesis leads to a universe that is an eternal cosmos continually evolving without beginning or end. Such a universe exists in a dynamical state of virial equilibrium. Observational studies of the redshift-magnitude relation for Type Ia supernovae in distant galaxies might provide the best observational test for a tired-light cosmology. The present study shows that the model Hubble diagram for a tired-light cosmology gives good agreement with the supernovae data for redshifts in the range 0<z<2. This observational test of a static cosmology shows that the real universe is not necessarily undergoing expansion nor acceleration. An erratum to this article can be found at     

Nature of the small main belt Asteroid 3169 Ostro

We present a set of rotational lightcurve measurements of the small main belt Asteroid 3169 Ostro. Our observations reveal an unambiguous, double-peaked rotational lightcurve with a peak-to-peak variation up to 1.2±0.05 mag and a synodic period of 6.509±0.001 h. From the large flux variation and the overall shape of the lightcurves, we suggest that 3169 Ostro could be a tightly bound binary or a contact binary, similar to the Trojan Asteroid 624 Hektor. A shape model of this system is proposed on the assumption that 3169 Ostro is a Roche binary described by a pair of homogeneous elongated bodies, with a size ratio of 0.87, in hydrostatic equilibrium and in circular synchronous motion around each other. The direction of the spin axis is determined modulo 180° by its J2000 ecliptic coordinates λ₀=50±10°, β₀=±54±5°. The binary interpretation and the pole solution adequately fit the earlier photometric observations made in 1986 and 1988. However, additional supporting lightcurves are highly desirable especially in the next mutual events occurrence of 2008 and 2009 in order to remove the pole ambiguity and to confirm unambiguously the binary nature of 3169 Ostro.     

Temperature dependence of the cation distribution in nickel aluminate (NiAl2O4) spinel: a powder XRD study

NiAl₂O₄ is a largely inverse spinel, which in detail shows increasing randomisation with temperature of Ni and Al between the octahedral and tetrahedral cation sites of the spinel structure. We have used powder XRD to determine this cation distribution in various samples of NiAl₂O₄ quenched after annealing between 700 and 1400° C. The inversion parameter (x) can be measured with a precision of ± 0.004 (one standard deviation), and a comparison of different methods of synthesis, X-ray diffraction and refinement techniques, suggests a probable accuracy of better than 0.01. The results are supported by some preliminary single crystal refinements on flux-grown samples.Below 800° C the rate of cation ordering becomes very slow, and, despite reaching an apparently steady state, it is doubtful if our samples attained complete internal equilibrium. Above 1250° C the cation redistribution becomes so fast that the quenching method becomes unreliable. Between 800 and 1250° C inclusive, the degree of inversion changes smoothly from 0.87 at 800° C to 0.79 at 1250° C, and is accompanied by linear changes in u, the oxygen parameter, from 0.2555 to 0.2563 (±0.0002), and a₀, the lattice parameter, from 8.0462 to 8.0522 Å (±0.0002 Å).     

Planetary nebulae in the Galaxy

It is shown that the planetary nebulae can be divided into three types according to the values of the mass of shell and a central star. The criteria are given using which one can determine the mass type of the nebula. The distance scale of each mass-type planetary nebulae is given. The distribution of planetary nebulae in the Galaxy, their formation rate, scale-height and other physical and kinematic characteristics are investigated. A catalogue of planetary nebulae emitting in the radio range is given.     

Mineralogical, chemical, and crystallographic properties of supergene jarosite-group minerals from the Xitieshan Pb-Zn sulfide deposit, northern Tibetan Plateau, China

Supergene jarosite-group minerals are widespread in weathering profiles overlying Pb-Zn sulfide ores at Xitieshan, northern Tibetan Plateau, China. They consist predominantly of K-deficient natrojarosite, with lesser amounts of K-rich natrojarosite and plumbojarosite. Electron microprobe (EMP) analyses, scanning electron microcopy (SEM) investigation, and X-ray mapping reveal that the jarosite-group minerals are characterized by spectacular oscillatory zoning composed of alternating growth bands of K-deficient and K-bearing natrojarosite (K₂O >1 wt.%). Plumbojarosite, whenever present, occurs as an overgrowth in the outermost bands, and its composition can be best represented by K_0.29Na_0.19Pb_0.31Fe_2.66Al_0.22(SO₄)_1.65(PO₄)_0.31(AsO₄)_0.04(OH)_7.37. The substitution of monovalent for divalent cations at the A site of plumbojarosite is charge balanced by the substitution of five-valent for six-valent anions in XO₄ at the X site. Thermogravimetric analysis (TGA) of representative samples reveal mass losses of 11.46 wt.% at 446.6 °C and 21.42 wt.% at 683.4 °C due to dehydroxylation and desulfidation, respectively. TGA data also indicate that the natrojarosite structure collapses at 446.6 °C, resulting in the formation of NaFe(SO₄)₂ and minor hematite. The decomposition products of NaFe(SO₄)₂ are hematite and Na₂SO₄. Powder X-ray diffraction (XRD) analyses show that the jarosite-group minerals have mean unit-cell parameters of a?=?7.315 Å and c?=?016.598 Å. XRD and EMP data support the view that substitutions of Na for K in the A site and full Fe occupancy in the B site can considerably decrease the unit-cell parameter c, but only slightly increase a. The results from this study suggest that the observed oscillatory zoning of jarosite-group minerals at Xitieshan resulted mainly from substitutions of K for Na at the A site and P for S at the X site.