The effect of microorganisms on Fe precipitation rates at neutral pH

The effect of microorganisms on Fe precipitation rates at neutral pH in the field was examined. The studied area was a cave having Fe-stalactites composed mainly of ferrihydrite and associated microorganisms. The microorganisms were covered with ferrihydrite. Water associated with stalactites was slightly supersaturated with respect to ferrihydrite, and had a dissolved oxygen concentration of 2 ppm, a pH of 6, and an Fe concentration of approximately 14 ppm. Fe precipitation rates were estimated from decreases in Fe concentrations in water during flowing through the Fe-stalactites. The estimated Fe precipitation rate in the field ranges from 6.8×10⁻⁸ to 4.0×10⁻⁷ mol/l/s. These values are in good agreement with bulk estimates of Fe-stalactite growth rates derived from the length increase (1.3 cm) of one formation over 30 days. The estimated Fe precipitation rates are faster by about four orders of magnitude than expected inorganic precipitation rates. On-site Fe precipitation experiments with sterilized and unsterilized Fe-stalactites and without Fe-stalactites indicate that microorganisms are the controlling factor accelerating Fe precipitation rates at neutral pH. These results suggest that microbially accelerated Fe precipitation rates are more likely related to exopolysaccharides and microbial surface properties than metabolic precipitation mechanisms.     

Electrokinetic phenomena associated with a water injection experiment at the Nojima fault on Awaji Island, Japan

Abstract Self-potential variations were measured to estimate the magnitude of electrokinetic and hydrological parameters (zeta potential and permeability) of the Nojima Fault zone in Awaji, Japan. The study observed self-potential variations that seemed to be associated with water flow from the injection well to the fracture zone, which were induced by turning the injection on and off. Amplitudes of the variations were a few to 0.03 V across 320–450 m dipoles. These variations can be explained well with an electrokinetic model. The quantity k/ζ (permeability/zeta potential) is in the range 1.6 × 10⁻¹³− 5.4 × 10⁻¹³ m²/V. Permeability of the Nojima fault zone can be estimated as approximately 10⁻¹⁶–10⁻¹⁵ m² on the assumption that the zeta potential is in the range –0.01 to –0.001 V.     

Effects of deposit feeder Stichopus japonicus on algal bloom and organic matter contents of bottom sediments of the enclosed sea

Algae growing in an enclosed sea may inhibit eutrophication because they absorb nutrients in the water. However, dead algae often cause anaerobic conditions in the water just above and on sediment after they are deposited on the bottom. We found that Stichopus japonicus inhibited the anaerobic processes coupling water sulfite production in sediment. The present study investigates whether S. japonicus inhibits algal flourish and influences sediment properties such as organic matter contents. Aquarium experiments were carried out at Komatsushima port in Tokushima Prefecture, western Japan. The aquaria used in the experiments were supplied with water directly from the adjacent sea (6 L/min), laid with sand of 10 cm depths, and lighted at 12 h intervals. Six aquaria each containing a sea cucumber from Komatsushima port and six aquaria without any were used in the experiments. Water temperature ranged between 9 and 15 degrees C during December 2000 and April 2001. Salinity ranged between 32 per thousand and 34 per thousand. Algae began to cover the bottom of the aquaria without S. japonicus after 2 weeks, whereas no growth was evident in the aquaria containing sea cucumbers. Chlorophyll a concentration in the surface sediment of the aquaria with S. japonicus (6.1+/-3.6 microg/g, mean S.D.+/-standard deviation) was significantly lower than that without it (60+/-17 microg/g, U-test, p<0.05). Phaeophytin concentration in the surface sediment of the aquaria with S. japonicus (0.9+/-0.09 microg/g) was also significantly lower than that without it (4.5+/-1.0 microg/g, U-test, p<0.05). TOC concentration in the surface sediment of the aquaria with S. japonicus (2.6+/-1.3 microg/g) was slightly lower than that without it (4.0+/-1.2 microg/g). These results showed that algal biomass and organic matter concentration of the bottom were decreased in the presence of S. japonicus. Therefore, S. japonicus inhibits algal bloom and decrease the contents of organic matter deposited on the bottom of enclosed sea areas.     

Interstadial coral reef terraces and relative sea-level changes during marine oxygen isotope stages 3–4, Kikai Island, central Ryukyus, Japan

Coral reef terraces are one of the best recorders of relative sea-level changes during the last glacial cycle. Thus far, knowledge of relative sea-level record based on coral reefs during the marine Oxygen Isotope Stage (OIS) 3 has been limited to studies of the Huon Peninsula, Papua New Guinea. High-precision a α-spectrometric ²³⁰Th/²³⁴U dating demonstrated an offlapping sequence of five coral reef complexes, ages of which are 66, 64, 62, 55 and 52 ka, in the northern part of Kikai Island, central Ryukyus of Japan. Interstadial reefs, characterized by deepening-upward sequences of coral assemblages, recorded three hemicycles from transgression to highstand at 52, 62, and 66 ka, during which these reefs were drowned. These highstands in the relative sea-level record can be correlated with the eustatic record reconstructed from the Huon reef terraces and with the interstadials 14, 18, and 19 of the GISP 2 oxygen isotope record. This consistency confirms the Huon sea-level record of OIS 3 and implies that the eustatic sea level responded to the millennial-scale climate changes even during the glacial period of OIS 4.     

Seismic stratigraphy and structural characteristics of back-arc rifts on the Izu-Ogasawara Arc

Abstract Seven back-arc rifts are recognized in the Izu-Ogasawara Arc, namely, the Hachijo, the Aogashima, the Myojin, the Sumisu, the Torishima, the Sofu and the Nishinoshima Rifts from north to south. The acoustic stratigraphy is divided into three units (Units A, B and C) based on the seismic reflection profiles crossing the rifts. The structure of the rifts systematically changes from a half-graben type to a full graben type in the back-arc rifts from the Hachijo Rift to the Torishima Rift. The Hachijo and the Aogashima Rifts have a structure of half-graben, and the Myojin Rift has both structural characteristics of a half-graben and a full graben. The Sumisu and the Torishima Rifts are an asymmetric full graben. The Sofu and the Nishinoshima Rifts have different structural characteristics from the remaining rifts, from the Hachijo Rift to the Torishima Rift. The boundary faults in the back-arc rifts from the Hachijo to the Torishima Rifts cut to Unit B. Unit B correlates with volcaniclastic sediments during pre-rift volcanism between 4 and 2 Ma. The pre-rift volcanism was probably widespread on the northern Izu-Ogasawara Arc as is the present arc volcanism. These factors suggest that the beginning of rifting is dated at some time after 2 Ma. The developing process of the rift consists of three stages; (i) a sag stage in the crust at the location of the large offset boundary fault; (ii) a stage of half-graben formation; (iii) a stage of full graben formation. The offset of the boundary faults becomes larger from the Hachijo Rift to the Torishima Rift and the east-west width of the rifts also widens to the south. This is presumably because the Hachijo Rift is an earlier rifting stage than the Sumisu and the Torishima Rifts. The more primitive structure in the rifting stage from the Torishima Rift to the Hachijo Rift is probably caused by the propagation of rifting from south to north. The structural difference between the rifts in the northern part and the Sofu and the Nishinoshima Rifts seems to be due to structural differences in the crust between the northern and the southern parts from the tectonic gap.     

Iron oxidation state of a 2.45-Byr-old paleosol developed on mafic volcanics

The 2.45-Byr-old weathering profile developed on early Proterozoic mafic volcanics located near Cooper Lake, Ontario, Canada, was examined geochemically and mineralogically for a better understanding of the atmospheric oxygen evolution. Ferrous to ferric ion, Fe(II) and Fe(III), respectively, ratios of the bulk rock samples were analyzed by Mössbauer spectrometry. The total Fe (Fe(T)) and Fe(II) concentrations decrease from 12.0 and 11.2 wt.% to 1.85 and 0.89 wt.%, respectively, from the bottom to the top of the weathering profile. The Fe(T) and Fe(II) concentrations normalized to Ti and Zr, as well as the Fe(II)/Fe(III) ratio of raw data, linearly decrease with depth toward the top, while the Fe(III) concentration remains nearly constant throughout the profile. The linear decrease of Fe(II), accompanied by the nearly constant distribution of Fe(III), is difficult to be explained by the scenario of oxidizing weathering and subsequent reducing hydrothermal alteration. The behaviors of Fe(II) and Fe(III) can be simply explained by anoxic weathering. The anoxic weathering suggests that the 2.45-Ga atmosphere was anoxic. The slight increase of Fe/(Fe+Mg) in the octahedral sites of chlorite toward the top and no Ce anomaly in the REE patterns are also consistent with anoxic weathering.     

Chemical composition of primary cosmic rays with energies from 10 to 10 eV

The chemical composition of primary cosmic rays with energies from 10¹⁵ to 10^16.5 eV, so called “knee” region, is examined. We have observed the time structures of air Čerenkov light associated with air showers at Mt. Chacaltaya, Bolivia, since 1995. The distribution of a parameter that characterizes the observed time structures is compared with that calculated with a Monte Carlo technique for various chemical compositions. Then the energy dependence of the average logarithmic mass numbers ln A of the primary cosmic rays is determined. The present result at 10^15.3 eV is almost consistent with the result of JACEE (A12) and shows gradual increase in ln A as a function of the primary energy (A24 at 10¹⁶ eV). Form the comparison of the observational results with several theoretical models, we conclude that the supernova explosion of massive stars is a plausible candidate for the origin of cosmic rays around the “knee” region.     

Strengthening of the Walker circulation under globalwarming in an aqua-planet general circulation model simulation

Most climate models project a weakening of the Walker circulation under global warming scenarios. It is argued, based on a global averaged moisture budget, that this weakening can be attributed to a slower rate of rainfall increase compared to that of moisture increase, which leads to a decrease in ascending motion. Through an idealized aqua-planet simulation in which a zonal wavenumber-1 SST distribution is prescribed along the equator, we find that the Walker circulation is strengthened under a uniform 2-K SST warming, even though the global mean rainfall–moisture relationship remains the same. Further diagnosis shows that the ascending branch of the Walker cell is enhanced in the upper troposphere but weakened in the lower troposphere. As a result, a "double-cell" circulation change pattern with a clockwise(anti-clockwise) circulation anomaly in the upper(lower) troposphere forms, and the upper tropospheric circulation change dominates. The mechanism for the formation of the "double cell" circulation pattern is attributed to a larger(smaller) rate of increase of diabatic heating than static stability in the upper(lower) troposphere. The result indicates that the future change of the Walker circulation cannot simply be interpreted based on a global mean moisture budget argument.     

Countermeasures for enhancing the stability of composite breakwater under earthquake and subsequent tsunami

Many breakwaters have collapsed in the past due to earthquakes and subsequent tsunamis, resulting in considerable devastation as the breakwaters failed to prevent the tsunami from entering the coastal plain areas. Breakwater failures are mainly caused by damage to its foundation ground. However, the damage mechanism of breakwater foundation during earthquakes and tsunamis remains unclear. This study focuses on the breakwater failure mechanism due to collapse of its foundation under the action of an earthquake and subsequent tsunami. In addition, reinforcing countermeasures for breakwater foundation to mitigate damage due to compound geodisasters triggered by earthquakes and tsunamis are proposed. Sheet piles and gabions were used in the breakwater foundation as reinforcing countermeasures. To evaluate the effectiveness of the reinforced foundation, a series of shaking table tests and hydraulic model tests were performed. The tsunami overflow tests were conducted on the same model after the earthquake loadings, and comparisons were made between the conventional and reinforced foundations. It was observed during the tests that the reinforced foundation could effectively reduce the damage to the breakwater caused by earthquake and tsunami-induced forces. Numerical analyses were performed to clarify the mechanism of the soil–breakwater–reinforcement–fluid system. Overall, this study is useful in practical engineering, and the reinforcing foundation model could be adopted for offshore structures to reduce damage from earthquakes and tsunamis in the future.