MM5-HPAC simulation experiments

Summary We evaluate mesoscale model predicted boundary-layer flow and the subsequent HPAC (Hazard Prediction and Assessment Capability) dispersion computation. The HPAC software allows for prediction of the effects of surface release of hazardous material into the atmosphere and collateral damage on civilian populations using either observed or numerical weather model data. The advanced mesoscale weather model MM5 was employed in the study. The real-data MM5 model simulations were verified with high-resolution observations from the West Texas Mesonet. MM5 worked well in simulating meteorologically relatively quiescent conditions. We examined the sensitivity of HPAC computations to the MM5 model’s grid resolution, lateral boundary conditions, and input weather data. Results suggest that the MM5-HPAC conjugation can provide useful prediction of airborne transport of hazardous materials near the surface. However, the accuracy of diffusion computations strongly depends on the performance of MM5, which in turn is likely to be a function of weather scenarios. A given state-of-the-art mesoscale model may perform well in some cases but not in others. There is a potential benefit of using several different model winds separately to run HPAC. A composite result of the HPAC runs could give a more comprehensive depiction of the transport of surface hazardous agents.     

The isotopic composition and elemental abundance of lutetium in meteorites and terrestrial samples and the 176Lu cosmochronometer

The isotopic composition of lutetium has been measured in a range of terrestrial and meteoritic materials using solid-source mass spectrometric techniques. The meteoritic and terrestrial isotopic abundances are identical within experimental errors. The absolute ¹⁷⁵Lu/¹⁷⁶Lu ratio as determined in this work is 37.36 ± 0.07 at the 95% confidence level. On the basis of this measurement the atomic weight of lutetium has been calculated to be 174.967 ± 0.002, which is in good agreement with the currently accepted figure of 174.97 ± 0.01.Using the stable isotope dilution technique the abundance of lutetium has been determined in 25 stone, 1 stony-iron and 8 iron meteorites, and in 12 standard rocks, with an accuracy of ±5% at the 95% confidence level. In general, there is good agreement between this work and other published data.The ¹⁷⁶Lu-¹⁷⁶Hf pair has been proposed as an s process nucleocosmochronometer, because of the long half-life of ¹⁷⁶Lu and the unique fact that both are s process isobars. The isotopic and elemental abundances of lutetium as measured in this work have been used with published nuclear data to estimate the mean age of s process nucleosynthesis for this isobaric pair, using the Schramm-Wasserburg formalism. The mean age cannot be accurately determined at the present time because of the lack of 30 keV neutron capture cross-section data for s only process nuclides and an accurate measurement of the branching ratio of ¹⁷⁵Lu + n. However, it is possible to place constraints on the nuclear parameters in this mass region using a reasonable s process chronology based on the decay of ¹⁷⁶Lu.     

Correlation of the Meishucunian Stage in South Asia

The determination of boundary points and their correlation are prerequisites for defining the PrecambrianCambrian boundary and the intercontinental correlation. A large number of good Precambrian-Cambrian boundary sections in South Asia not only possess the conditions for selection of a boundary stratotype, but also provide the basis for the long-distance correlation of those boundary sections.Through a detailed study of the latest data obtained from the typical sections in South China, the Lesser Himalaya Mountains and the Alborz Mountains. the locations of boundary points have been defined, and a correlation scheme is proposed, which contributes to the solution of the problem of worldwide correlation of boundary sections.     

Redetermination of the transformation enthalpies of the xanthoconite–proustite, pyrostilpnite–pyrargyrite and trechmannite–smithite phase transitions

 We report here refined values of the transformation enthalpy for xanthoconite to proustite (54.81 kJ/mol) and pyrostilpnite to pyrargyrite (40.32 kJ/mol). Additionally, the enthalpy for the transformation of trechmannite to smithite (5.82 kJ/mol) has been determined. The refinement was possible by taking into account a previously unknown dependence of electrochemical signals on the amount of substance undergoing the reduction process. Received December 21, 1995/Revised, accepted June 29, 1996     

Specifying the mesoscale numerical forecast of heavy showers

Actual surface fields of meteorological variables 1–3 hours before the heavy showers are analyzed in detail for the purpose of their specification with WRF-ARW model. The complex of hygrothermodynamic characteristics needed for this purpose is discovered. The detailed satellite, radar, and synoptic data are also considered.