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991.
K. HISADA L. L. PERCHUK T. V. GERYA D. D. VAN REENEN B. K. PAYA 《Journal of Metamorphic Geology》2005,23(5):313-334
Metapelites, migmatites and granites from the c. 2 Ga Mahalapye Complex have been studied for determining the P–T–fluid influence on mineral assemblages and local equilibrium compositions in the rocks from the extreme southwestern part of the Central Zone of the Limpopo high‐grade terrane in Botswana. It was found that fluid infiltration played a leading role in the formation of the rocks. This conclusion is based on both well‐developed textures inferred to record metasomatic reactions, such as Bt ? And + Qtz + (K2O) and Bt ± Qtz ? Sil + Kfs + Ms ± Pl, and zonation of Ms | Bt + Qtz | And + Qtz and Grt | Crd | Pl | Kfs + Qtz reflecting a perfect mobility (Korzhinskii terminology) of some chemical components. The conclusion is also supported by the results of a fluid inclusion study. CO2 and H2O ( = 0.6) are the major components of the fluid. The fluid has been trapped synchronously along the retrograde P–T path. The P–T path was derived using mineral thermobarometry and a combination of mineral thermometry and fluid inclusion density data. The Mahalapye Complex experienced low‐pressure granulite facies metamorphism with a retrograde evolution from 770 °C and 5.5 kbar to 560 °C and 2 kbar, presumably at c. 2 Ga. 相似文献
992.
Mantle xenoliths (lherzolites, clinopyroxene dunites, wehrlites, and clinopyroxenites) in the Early Cretaceous volcanic rocks of Makhtesh Ramon (alkali olivine basalts, basanites, and nephelinites) represent metasomatized mantle, which served as a source of basaltic melts. The xenoliths bear signs of partial melting and previous metasomatic transformations. The latter include the replacement of orthopyroxene by clinopyroxene in the lherzolites and, respectively, the wide development of wehrlites and olivine clinopyoroxenites. Metasomatic alteration of the peridotites is accompanied by a sharp decrease in Mg, Cr, and Ni, and increase of Ti, Al, Ca contents and 3+Fe/2+Fe ratio, as well as the growth of trace V, Sc, Zr, Nb, and Y contents. The compositional features of the rocks such as the growth of 3+Fe/2+Fe and the wide development of Ti-magnetite in combination with the complete absence of sulfides indicate the high oxygen fugacity during metasomatism and the low sulfur concentration, which is a distinctive signature of fluid mode during formation of the Makhtesh Ramon alkali basaltic magma. Partial melting of peridotites and clinopyroxenites is accompanied by the formation of basanite or alkali basaltic melt. Clino- and orthopyroxenes are subjected to melting. The crystallization products of melt preserved in the mantle rock are localized in the interstices and consist mainly of fine-grained clinopyroxene, which together with Ti-magnetite, ilmenite, amphibole, rhenite, feldspar, and nepheline, is cemented by glass corresponding to quartz–orthopyroxene, olivine–orthopyroxene, quartz–feldspar, or nepheline–feldspar mixtures of the corresponding normative minerals. The mineral assemblages of xenoliths correspond to high temperatures. The high-Al and high-Ti clinopyroxene, calcium olivine, feldspar, and feldspathoids, amphibole, Ti-magnetite, and ilmenite are formed at 900–1000°. The study of melt and fluid inclusions in minerals from xenoliths indicate liquidus temperatures of 1200–1250°C, solidus temperatures of 1000–1100°C, and pressure of 5.9–9.5 kbar. Based on the amphibole–plagioclase barometer, amphibole and coexisting plagioclase were crystallized in clinopyroxenites at 6.5–7.0 kbar. 相似文献
993.
Heavy metals in sediments of the Tecate River, Mexico 总被引:1,自引:0,他引:1
F. T. Wakida D. Lara-Ruiz J. Temores-Peña J. G. Rodriguez-Ventura C. Diaz E. Garcia-Flores 《Environmental Geology》2008,54(3):637-642
Ten sites along the Tecate River, Mexico were sampled to evaluate the cadmium, lead, nickel and chromium concentrations in
sediments. The result shows contamination for cadmium in most of the sites, where two sites were class 4 (polluted to strongly
polluted) according to geoaccumulation index proposed by Muller. Two sites were found polluted for all the heavy metals analyzed
(Cr, Cd, Pb and Ni), indicating the effect of anthropogenic activities. A correlation between Ni and Cd concentration had
been found indicating a common source. These metals are usually used in electroplating industry. The results of this study
can be used for decision makers to prioritize measures to control the pollution for these metals. 相似文献
994.
Cu-bearing pyroxene, Mg(Cu.56,Mg.44)Si2O6, has been synthesized by a flux method and crystal structure refinement has been performed by single crystal X-ray diffraction. It is found that the crystal structure is orthorhombic (space group Pbca) with unit cell dimensions of a=18.221(4), b=8.890(1), c=5.2260(7)Å and the cell volume of 846.5( )3Å3. In the M2-site one of the M-O bonds(M-O3B) is extremely expanded from 2.444(2) in enstatite to 2.732(2), thus the coordination polyhedron around M2-site is regarded as square pyramidal rather than square planar or octahedral. It is also found that the M1-site in the pyroxene structure is occupied almost exclusively by Mg, while the M2-site is almost evenly occupied by Mg and Cu. The observed extreme site preference shown by Cu2+ is unusual among the divalent cations with similar ionic sizes. 相似文献
995.
STRESS-METAMORPHISM AND ISOTOPIC AGE OF SHEAR ZONE GRANITOID TECTONITES OF IRTYSH SHEAR ZONE (ALTAI REGION) 总被引:1,自引:0,他引:1
B.M.Chikov V.A.Ponomachuk S.V.Zinoviev B.N.Lapin A.T.Titov A.V.Travin S.V.Palessky 《大地构造与成矿学(英文版)》2002,26(1):36-51
The Irtysh shear zone (ISZ) of Altai region is the lineament structure of the collision-suture type, where granites of Kalba complex and granodiorites of Zmeinogorsk complex are exposed to regional gneiss-formation and stress-metamorphic alterations. This study is based on detailed structural observations at special grounds using optical and electron microscopy, and on the behavior analysis of isotopic systems from altered granitoids.Within the ISZ area we have established the continuous rows of granitoid stress-metamorphism from initial recrystallization of protolite, its cataclasis and mechanical flaring up to complete recrystallization with alteration of mineral composition and formation of the streaky complexes of granite tectonites of blastomylonite and blastocataclasite types. The directed alteration of rocks has several impulse and is expressed by a change in morphology of mineral grains and their relations, magnification of deformation component in the rock structure, and formation of new mineral phases on the basis of initial ones without surface fluidization. At transformation of isotopic systems from granitoid, their feldspars,biotite and hornblende, we can observe “rejuvenation“ of the rock substrate from 270- 290 Ma for Kalba granitoids to 220-235 Ma for their tectonites, and for Rudny Altai granodiorites, their ages changes from 285-317 Ma to 232-257 Ma for their tectonites. 相似文献
996.
997.
Carlos Pecharromán T. González-Carreño Juan E. Iglesias 《Physics and Chemistry of Minerals》1995,22(1):21-29
The infrared complex permittivity functions of three varieties of maghemite, γ-Fe2O3, having different degrees of vacancy ordering, have been determined from their IR reflectance spectra, measured at near to normal incidence on pressed powder pellets. The optical constants therefrom obtained have been verified by using them in the simulation of the corresponding absorption spectra for KBr-diluted pellets, and these are in excellent agreement with the experimental spectra. All calculations are based on a procedure for the estimation of the effective dielectric function of a mixture, which incorporates percolation features, recently developed by the authors. 相似文献
998.
Constraints from Thorium/Lanthanum on Sediment Recycling at Subduction Zones and the Evolution of the Continents 总被引:20,自引:3,他引:20
Arc magmas and the continental crust share many chemical features,but a major question remains as to whether these features arecreated by subduction or are recycled from subducting sediment.This question is explored here using Th/La, which is low inoceanic basalts (<0·2), elevated in the continents(>0·25) and varies in arc basalts and marine sediments(0·090·34). Volcanic arcs form linear mixingarrays between mantle and sediment in plots of Th/La vs Sm/La.The mantle end-member for different arcs varies between highlydepleted and enriched compositions. The sedimentary end-memberis typically the same as local trench sediment. Thus, arc magmasinherit their Th/La from subducting sediment and high Th/Lais not newly created during subduction (or by intraplate, adakiteor Archaean magmatism). Instead, there is a large fractionationin Th/La within the continental crust, caused by the preferentialpartitioning of La over Th in mafic and accessory minerals.These observations suggest a mechanism of fractionation& foundering, whereby continents differentiate intoa granitic upper crust and restite-cumulate lower crust, whichperiodically founders into the mantle. The bulk continentalcrust can reach its current elevated Th/La if arc crust differentiatesand loses 2560% of its mafic residues to foundering. KEY WORDS: arc magmatism; continental crust; delamination; thorium; sediment subduction 相似文献
999.
N. T. Arndt N. A. Teixeira W. M. White 《Contributions to Mineralogy and Petrology》1989,101(2):187-197
Komatiite lava flows in the Crixás greenstone belt, Goiás, Brazil, have textures and volcanic structures typical of Archean
komatiites, but are geochemically most unusual. The flows are porphyritic and massive, or layered with spinifex upper parts
and olivine cumulate lower parts. MgO contents range from 18 to 40%. In such lavas, only olivine (and minor chromite) can
have crystallized, but neither major nor trace elements fall on olivine control lines. In MgO variation diagrams, CaO and
Sr fall on lines with slopes steeper than olivine control lines; SiO2, FeO, Na2O, K2O and Y show little systematic variation; Zr shows a large variation that does not correlate with MgO; and Al2O3 decreases markedly with decreasing MgO. The aberrant behaviour is highlighted by the REE (rare earth elements) in spinifex
and olivine cumulate layers from three flows: in the spinifex layers, chondrite-normalized REE patterns are hump-shaped with
maxima at Nd or Sm ((La/Sm)N=0.6, (Gd/Yb)N=1.6–2.3), whereas cumulate zones in the same flows have steadily sloping patterns, with LREE enriched relative to HREE ((La/Sm)N=1.3, (Gd/Yb)N=1.4). Neither normal magmatic processes acting during emplacement of the komatiites, nor thermal erosion and wall-rock assimilation
can explain these effects, and we speculate that elements commonly thought of as “immobile” (e.g. Al, Zr, REE) migrated during
hydrothermal alteration or metamorphism. A Pb-Pb whole rock isochron gave an age of 2,728±140 Ma and selected Sm-Nd analyses
an apparent isochron age of 2,825±98 Ma (ɛNd≈0). The Pb-Pb age is believed to be the approximate time of emplacement. Interpretation of the Sm-Nd data is complicated
by the evidence of mobility of REE. 相似文献
1000.
Hajer Farroukh T. Mnif F. Kamoun L. Kamoun F. Bennour 《Arabian Journal of Geosciences》2018,11(23):760
Phosphogypsum and cement have been reported to improve the physicochemical properties of clayey soils. The present study aimed to investigate the behavior of various soils with different particle sizes and chemical and mineralogical compositions in the presence of phosphogypsum and cement mixed at various proportions. These hydraulic binders were assayed on three different soil samples, and their effects were examined using a battery of standardized tests, including the Atterberg limit, uniaxial compressive strength, Californian Bearing Rate (CBR) test, thermogravimetric analysis (TGA), microstructure observation (SEM), and X-ray diffraction tests. The results revealed a significant effect associated with the variation of phosphogypsum content in the soils. Keeping the cement content constant in the mixture, the continuous addition of phosphogypsum was noted to allow shifting the domain of plasticity to the highest water contents, which reduces the sensitivity of the soil to water and to increase the strength of soil. An increase of CBR index with the addition of phosphogypsum and cement is obtained. This treatment could have positively influenced the optimum moisture content and the maximal dry density. The mixture of soil-phosphogypsum and cement could give new forms such as ettringite and hydrate indicators of the improvement of the mechanical properties of the soil. This improvement varies from one soil to another, depending on its granularity and its mineralogy. The mineralogical composition of the soil, particularly kaolinite, amount, and size grading, have direct effects on the physical and mechanical properties of the soils under investigation. 相似文献