Soilscapes,geomorphic processes and soil taxonomic new subgroups identified in the Ghaggar river basin of Haryana and Punjab

Soilscapes of the Ghaggar river basin falling in Haryana and Punjab were interpreted and studied by using the Landsat imagery and aerial photographs. Five major landform units identified and demarcated in the area were : channel courses, levees, flood-plains undulating, basinal floodplains and relict basins. On the basis of sedimentation, nature of the river pattern and soil characteristics, the whole basin was divided into three reaches — upper, middle and lower. Taxonomically the soils were placed under Typic Ustipsamments, Typic Ustorthents and lypic Ustifluvents on channel courses; Aquic Ustifluvents, Typic Ustifluvents and Typic Ustochrepts on levees; Fluventic Ustochrepts, Udic Ustochrepts and lypic Camborthids on floodplains undulating; Typic Ustorthents and Udic Ustochrepts on basinal floodplains; Typic Natrustalfs and Natric Camborthids on relict basins. Two new subgroups were proposed, i.e., Natric within the order of Entisol and Inceptisol, and Aquic-udic within the order of Inceptisol. Two dominant geomorphic processes were observed, i.e., fluvial and aeolian.     

Crustal growth processes as illustrated by the Neoarchaean intraoceanic magmatism from Gadwal greenstone belt, Eastern Dharwar Craton, India

Geochemical studies on metavolcanic rocks of the Gadwal greenstone belt (GGB), eastern Dharwar craton, have documented several rock types that are indicative of subduction zone tectonics reflecting on the crustal growth processes in the Dharwar craton. The dominance of komatiites in the western Dharwar craton (WDC) and the arc volcanics in the eastern Dharwar craton (EDC) is an indication for the predominance of plume magmatism in the WDC and the intraoceanic subduction zone processes in EDC which together played a significant role in the growth and evolution of continental crust in the Dharwar craton. Boninites of GGB are high calcic type with high MgO (13–24 wt.%) and a characteristic MREE depleted U-shaped REE patterns whereas the basalts have flat REE patterns with no Eu anomalies. Nb-enriched basalts exhibit slightly fractionated REE patterns with high Nb (8–26 ppm) content compared to arc basalts. Adakites of GGB are Sr depleted with highly fractionated REE patterns and no Eu anomaly compared to rhyolites. The occurrence of boninites along with arc basalts, Nb-enriched basalts–basalt–andesite–dacite–rhyolites and adakites association in Gadwal greenstone belt indicate the intraoceanic subduction zone processes with a clear cut evidence of partial melting of metasomatized mantle wedge (boninites), melting of subducting slab (adakites) and residue of adakite–wedge hybridization (Nb-enriched basalts) which have played a significant role in the growth of continental crust in the Dharwar craton during the Neoarchaean.     

Comparison of Kansas Data with High-resolution Large-eddy Simulation Fields

The surface layer of an atmospheric boundary layer (ABL) is most accessible to field measurements and hence its ensemble-mean structure has been well established. The Kansas field measurements were the first detailed study of this layer, providing numerous benchmark statistical profiles for a wide range of stability states. Large-eddy simulation (LES), in contrast, is most suitable for studying the mixed layer of the ABL where the energy-containing range of the vertical velocity field is well resolved. In the surface layer, typical large-eddy simulations barely resolve the energy-containing vertical-velocity fields and hence do not provide sufficient data for a detailed analysis.We carried out a nested-mesh simulation of a moderately convective ABL (-z_i/L = 8) in which the lower 6% of the boundary layer had an effective grid resolution of 512³. We analyze the LES fields above the 6th vertical grid level (z = 23 m) where the vertical velocity field has a well formed inertial subrange, for a detailed comparison with the Kansas results. Various terms in the budgets of turbulent kinetic energy, temperature variance, Reynolds stress, temperature flux, and some higher order moments are compared. The agreement is generally quite good; however, we do observe certain discrepancies, particularly in the terms involving pressure fluctuations.     

Inversion of fold-hinge in superposed folding: An example from the Precambrian of central Rajasthan,India

Axial culminations and depressions of folds are common in regions of superposed deformations involving two sets of folds at high angles to each other. If the intensity of the later folding in these cases exceeds a particular limit, plunge reversal of the early folds gives way to “plunge inversion”. In such instances, segments of early folds rotate through end-on or reclined geometry while being refolded. And instead of plunge reversal at the hinge zones of later folds, the early folds plunge in the same direction in both limbs of the later folds. As a result, an antiform will pass along the axial trend to a synform. A particularly clear instance of plunge inversion has been noted from the “Sawar outlier” comprising a metasedimentary sequence within the older Banded Gneissic Complex in central Rajasthan. In Sawar, the southern segment of a south-southwest-trending synformal early fold has been inverted to attain an antiformal geometry because of superposition of a later fold at high angles to the early fold axes and axial planes. The deformation history of the large-scale folds has been traced and the stratigraphic implications of the plunge inversion discussed. From the movement pattern, it seems justifiable to correlate the metasedimentary sequence of the outlier with the Late Precambrian Delhi Group of parametamorphic rocks.     

Cation diffusion in aluminosilicate garnets: experimental determination in spessartine-almandine diffusion couples,evaluation of effective binary diffusion coefficients,and applications

We present new experimental data on diffusion of divalent cations in almandine-spessartine diffusion couples in graphite capsules in the P-T range of 14–35 kb, 1100–1200° C. The tracer diffusion coefficients of the major divalent cations, viz. Fe, Mg and Mn, retrieved from the multicomponent diffusion profiles, have been combined with earlier data from our laboratory at 29–43 kb, 1300–1480° C (Loomis et al. 1985) to derive expressions of the P-T dependence of the diffusion coefficients at fO₂ approximately corresponding to that defined by equilibrium in the system graphite-O₂. We review the conditions, discussed earlier by Cooper, under which the flux of a component in a multicomponent system becomes proportional to its concentration gradient (Fickian diffusion), as if the entire solvent matrix behaves as a single component, and also suggest a method of incorporating the thermodynamic effect on diffusion in the same spirit. Regardless of the magnitude or sign of the off-diagonal terms of the D matrix, it is always possible to define an effective binary diffusion coefficient (EBDC) of a component in a semi-infinite multicomponent diffusion-couple experiment such that it has the property of the Fickian diffusion coefficient, provided that there is no inflection on the diffusion profiles. It is shown that the success of Elphick et al. in fitting the experimental diffusion profiles of all components over a limited concentration range by a single diffusion coefficient is due to fortuitous similarity of the EBDCs of the components (Fe, Mg, Mn and Ca) in their diffusion couple experiments. In common metapelitic garnets showing compositional zoning, the EBDCs of the divalent cations do not differ from each other by more than a factor of 2.5. However, the EBDC of a component changes from core to rim by a factor of 3 to 12, depending on the composition. We suggest a method of volume averaging of the EBDC which should prove useful in approximate calculations of diffusion flux during relaxation of compositional zoning. The EBDC of Mn is found to reduce essentially to D _MnMn, the main diagonal term of the D matrix, and consequently can be calculated quite easily. Evaluation of EBDC of Fe, Mg and Mn in garnets from a prograde Barrovian sequence did not reveal any significant dependence on the extent of relaxation of garnet. The diffusion data have been applied to calculate the cooling rate of natural biotite-garnet diffusion couple from eastern Finland and diffusional modification of growth zoning in garnet in early Proterozoic Wopmay orogen, Canada. The results are in good agreement with geochronological and other independent constraints.Symbols and abbreviations a Radius of a spherical garnet crystal - BSE Back-scattered electron imaging - C Column vector of (n-1) independent components - D Diffusion coefficient matrix - D _ij An element of the diffusion matrix on the i th row and j th column - D _* ⁱ Tracer diffusion coefficient of component i - D(i) Effective interdiffusion coefficient (EIC) of various components in a multicomponent solution rich in the component i - D(i-j) Interdiffusion coefficient of components i and j in a binary solution - D _i (EB) Effective binary diffusion coefficient of component i in a multicomponent solution - D _i (EB:Ideal) D _i (EB) under condition of ideal thermodynamic mixing of the diffusing species - D _i (EB:thermo) Thermodynamic component of D _i(EB) - D _O ^A Interdiffusion coefficient at peak temperature T ₀ in the phase A - D ₀ Pre-exponential factor in an Arrhenius relation - EBDC Effective binary diffusion coefficient between a solute and a multicomponent solvent matrix - FEC Fixed edge composition model - EIC Effective interdiffusion coefficient - f _i Fugacity of component i - HM Hematite-magnetite oxygen fugacity buffer - kb Kilobars - P Pressure - Q Activation energy (enthalpy) of diffusion - Extent of relaxation defined as the difference between core and rim compositions normalized to the same difference in the initial zoning profile - R Gas constant - s Cooling rate - T ₀, T _Ch Peak temperature and characteristic temperature, respectively - t Time - VEC Variable edge composition model - V ⁺ Activation volume - W _ij Simple mixture interaction parameter between i and j - W _i(EB) Effective simple mixture interaction parameter of a component i in a multicomponent solution - _ij Margules interaction parameter between i and j - X _i Mole fraction of component i - _i Activity coefficient of component i - A dimensionless variable =D t/a ² - _ij Kronecker delta (i=j, _ij =1; ij, _ij =0) - Z_i Charge on the ion i     

Sun-Sky Radiometer Synthesis of Interplay Between Aerosols and Monsoon Activity Over Pune,India

Besides several thematic campaigns, utilizing a variety of platforms including satellites, ground-based networks have been established to improve our understanding of the role of aerosols in the changing monsoon climate. Two such widely known networks over the globe are ‘SKYNET’ and ‘AERONET’ with sun-sky radiometers as the principal equipment that characterizes aerosols and gases over different geographical locations under varied air mass conditions. Pune (18°43′N, 73°51′E, 559 m above mean sea level), a fast growing low-latitude, urban city in India, is one of the sites where Prede (POM-01L, SKYNET) and Cimel (CE-318, AERONET) Sun-sky radiometers have been in operation since 2004. These radiometers have been extensively used in several studies related to stand-alone and coupled aerosol-cloud-climate processes. The Prede instrument at this site is being augmented for the network of the Global Atmospheric Watch program of the World Meteorological Organization to facilitate data coordination through the World Data Center for Aerosols. The present study envisages understanding the response of atmospheric constituents, through simultaneous operation of the radiometers amongst others, for the rainfall activity over Pune during two contrasting monsoon years of 2008 (active, 98 % of long period average (LPA) rainfall over the whole country) and 2009 (weak, 78 % of LPA). The synthesis of data indicates that, apart from excellent agreement between the direct Sun observations, both radiometers capture well the monsoon features within the instrument density and efficacy of data retrieval algorithms involved. The meteorological fields from the ECMWF re-analysis and NOAA-HYSPLIT air-mass back-trajectory analysis during the study period have been utilized to explain the variations observed in the radiometer products.     

Coupling Between Seismic Activity and Hydrogeochemistry at the Shillong Plateau, Northeastern India

Transient hydrogeochemical anomalies were detected in a granite-hosted aquifer, which is located at a depth of 110 m, north of the Shillong Plateau, Assam, India, where groundwater chemistry is mainly buffered by feldspar alteration to kaolinite. Their onsets preceded moderate earthquakes on December 9, 2004 (M_W = 5.3) and February 15, 2005 (M_W = 5.0), respectively, 206 and 213 km from the aquifer. The ratios [Na+K]/Si, Na/K and [Na+K]/Ca, conductivity, alkalinity and chloride concentration began increasing 3–5 weeks before the M_W = 5.3 earthquake. By comparison with field, experimental and theoretical studies, we interpret a transient switchover between source aquifers, which induced an influx of groundwater from a second aquifer, where groundwater chemistry was dominantly buffered by the alteration of feldspar to smectite. This could have occurred in response to fracturing of a hydrological barrier. The ratio Ba/Sr began decreasing 3–6 days before the M_W = 5.0 earthquake. We interpret a transient switchover to anorthite dissolution caused by exposure of fresh plagioclase to groundwater interaction. This could have been induced by microfracturing, locally within the main aquifer. By comparison with experimental studies of feldspar dissolution, we interpret that hydrogeochemical recovery was facilitated by groundwater interaction and clay mineralization, which could have been coupled with fracture sealing. The coincidence in timing of these two hydrogeochemical events with the only two M_W ≥ 5 earthquakes in the study area argues in favor of cause-and-effect seismic-hydrogeochemical coupling. However, reasons for ambiguity include the lack of similar hydrogeochemical anomalies coupled with smaller seismic events near the monitoring station, the >200 km length scale of inferred seismic-hydrogeochemical coupling, and the potential for far-field effects related to the Great Sumatra–Andaman Islands Earthquake of December 26, 2004.     

Preparation and Characterisation of Two Geochemical Reference Materials: DG‐H (Granite) and AM‐H (Amphibolite) from the Himalayan Orogenic Belt

Two geochemical reference materials of Himalayan origin named DG‐H (a granite) and AM‐H (an amphibolite) prepared by the Wadia Institute of Himalayan Geology Dehradun are described. Both samples were collected from the NW Himachal Himalaya in India. With the participation of analysts from more than forty international laboratories, element determination data collected during the past 10 years for characterisation of the samples was processed to assign working values using statistical procedures in use for this purpose. Earlier work published on these samples is incorporated in the present communication making it an updated document. The typical chemical and petrological characteristics of these two samples may prove useful for method validation and calibration of analytical instruments used for analysing similar rock types, and for widening the analytical range of several analytical methods used for geochemical analysis.