The formation and evolution of an isolated submarine valley in the North Channel,Irish Sea: an investigation of Beaufort's Dyke

Beaufort's Dyke is a submarine depression located in the North Channel of the Irish Sea. With a maximum depth of 312 m, the dyke is one of the deepest areas within the European continental shelf. Integration and interpretation of 450 km of sparker seismic data and full‐coverage bathymetric data derived from multi‐beam echo sounder surveys allow for the investigation of the formation processes of Beaufort's Dyke and the evolution of geomorphological features within it. The dyke, formed by composite subglacial processes dominated by subglacial meltwater discharge, is interpreted as a tunnel valley. The regional isolation of Beaufort's Dyke may be explained by the bounding of the North Channel by the bedrock masses of Ireland and Scotland, coupled with the exploitation of structural weakness along a fault plane and presence of halite in the eroded substrate enhancing the erosive potential of the overlying glacier. Beaufort's Dyke has probably been maintained as an open feature by strong rectilinear tidal currents. The morphology of lunate sediment waves and a large parabolic bedform towards the south of the dyke contradict the observed dominant S–N mean hydrodynamic flow recorded within the North Channel, suggesting an alternative hydrodynamic regime either within the dyke or during bedform creation. Copyright © 2011 John Wiley & Sons, Ltd.     

Vertical cross contamination of trichloroethylene in a borehole in fractured sandstone

Boreholes drilled through contaminated zones in fractured rock create the potential for vertical movement of contaminated ground water between fractures. The usual assumption is that purging eliminates cross contamination; however, the results of a field study conducted in a trichloroethylene (TCE) plume in fractured sandstone with a mean matrix porosity of 13% demonstrates that matrix-diffusion effects can be strong and persistent. A deep borehole was drilled to 110 m below ground surface (mbgs) near a shallow bedrock well containing high TCE concentrations. The borehole was cored continuously to collect closely spaced samples of rock for analysis of TCE concentrations. Geophysical logging and flowmetering were conducted in the open borehole, and a removable multilevel monitoring system was installed to provide hydraulic-head and ground water samples from discrete fracture zones. The borehole was later reamed to complete a well screened from 89 to 100 mbgs; persistent TCE concentrations at this depth ranged from 2100 to 33,000 microg/L. Rock-core analyses, combined with the other types of borehole information, show that nearly all of this deep contamination was due to the lingering effects of the downward flow of dissolved TCE from shallower depths during the few days of open-hole conditions that existed prior to installation of the multilevel system. This study demonstrates that transfer of contaminant mass to the matrix by diffusion can cause severe cross contamination effects in sedimentary rocks, but these effects generally are not identified from information normally obtained in fractured-rock investigations, resulting in potential misinterpretation of site conditions.     

Great Lakes Hydrology Under Transposed Climates

Historical climates, based on 43 years of daily data from areas south and southwest of the Great Lakes, were used to examine the hydrological response of the Great Lakes to warmer climates. The Great Lakes Environmental Research Laboratory used their conceptual models for simulating moisture storages in, and runoff from, the 121 watersheds draining into the Great Lakes, over-lake precipitation into each lake, and the heat storages in, and evaporation from, each lake. This transposition of actual climates incorporates natural changes in variability and timing within the existing climate; this is not true for General Circulation Model-generated corrections applied to existing historical data in many other impact studies. The transposed climates lead to higher and more variable over-land evapotranspiration and lower soil moisture and runoff with earlier runoff peaks since the snow pack is reduced up to 100%. Water temperatures increase and peak earlier. Heat resident in the deep lakes increases throughout the year. Buoyancy-driven water column turnover frequency drops and lake evaporation increases and spreads more throughout the annual cycle. The response of runoff to temperature and precipitation changes is coherent among the lakes and varies quasi-linearly over a wide range of temperature changes, some well beyond the range of current GCM predictions for doubled CO₂ conditions.     

Petroleum hydrocarbon contamination of ground water in Tiverton,Rhode Island,USA

Ground water samples from several private wells serving individual homes in Tiverton, Rhode Island were analyzed for petroleum contamination over a 19-month period. The hydrocarbon concentrations initially ranged from 68 to 2350 ppb and then gradually decreased to lower values, ranging from 6 to 1650 ppb, at the end of the study. Samples from the well with the highest hydrocarbon concentration (2350 to 1650 ppb) were investigated in some detail because this was considered a possible source of the petroleum contamination in the area. These studies indicated that most of the hydrocarbons were in the dissolved phase (<1.0 μm) of the ground water and that it contained large amounts of naphthalene, methyl and dimethyl naphthalenes, and ethyl naphthalenes. In addition, the qualitative distribution of hydrocarbons changed as the concentration decreased over the course of the investigation. There appeared to be preferential loss of the more volatile and easily degraded components relative to the higher molecular weight and more refractory hydrocarbons. Some of the wells at this location are contaminated with at least two different petroleum products, i.e. gasoline and fuel oil. The exact nature and source of the contaminant is not known; it may be spilled or leaking petroleum products, or other materials containing petroleum hydrocarbons (e.g. commercial or industrial cleaning solutions). Based on differences in the qualitative distribution of components, some of the wells contain hydrocarbons that have been environmentally altered or that originate from a source other than the most contaminated well     

Spatial and temporal predictions of soil moisture dynamics,runoff, variable source areas and evapotranspiration for plynlimon,mid-wales

For many years hydrologists have tried to build physically realistic models which are still simple enough to be fitted to a range of observations made in the field. This is an ongoing process which will become even more difficult as the quality and variety of field and remotely sensed data improves. Hence models must be able to predict soil moisture patterns in time and in space as well as the outflow hydrograph. The model presented here (TOPMODEL) aims to predict the nature of variable source areas in a way that reflects their dynamics over space and time. All component processes are described and shown in operation. As TOPMODEL and similar models have a growing popularity, this paper can be seen as a demonstration of the model's predictive capabilities. The model is applied to the catchments of Plynlimon, mid-Wales for 1984, 1985 and 1986 data sets. The model has been thoroughly tested and cross-validated against independent data sets for different time periods, for a separate catchment, for internal gauges and for wet and dry periods. The resulting predicted soil moisture patterns show a small, semi-permanent variable source area that has the ability during large storms to expand dynamically over short time periods. Spatial predictions of evapotranspiration are also shown which reflect the influence of soil moisture patterns on this process. The weakest component of the model is the representation of root zone evaporation and how this pre-sets the antecedent condition of the catchment during long dry periods.     

Dissolved copper and copper-organic complexes in the Narragansett Bay estuary

The geochemistry of dissolved copper-organic complexes was investigated in the estuarine waters of Narragansett Bay. A transect survey was conducted in August 1980, while one mid-bay station was monitored from March through August of that year. The transect data indicated that most of the copper-organic complexes enter the bay via sewage effluent which is discharged into the Providence River at the head of the bay. Organic copper concentrations in the estuary ranged from 0.12 to 2.30 μg kg^?1 and comprised from 14 to 70% of the total dissolved copper. The concentration of copper-organic complexes was not directly related to the amount of dissolved organic matter; and recently generated organic material from phytoplankton production within the bay had a negligible influence on the fraction of dissolved copper which was organically bound.The major source of total copper to the bay is anthropogenic inputs from sewage effluents. Particulate and dissolved copper concentrations ranged from 0.06 to 2.42 and 0.23 to 16.4 μg kg^?1, respectively, giving average values of about 40% particulate and 60% dissolved copper. Particulate copper concentrations decreased rapidly from the upper to the lower bay as a result of both removal and dilution. About 75% of the dissolved copper entering the bay is rapidly removed in the Providence River and upper bay, and the remaining portion (which is largely organic copper) follows conservative mixing in the mid to lower bay. The data suggest that copper binding by dissolved organic matter may be an important control on the riverine flux of dissolved copper through estuaries into coastal and oceanic waters.