Strontian-loparite and strontio-chevkinite: Two new minerals in rheomorphic fenites from the Paraná Basin carbonatites,South America

Contributions to Mineralogy and Petrology - Strontian-loparite is recognized at Sarambi and Chiriguelo, Paraguay and at Salitre I, Brazil as an accessory mineral in rheomorphic...     

Shoreline erosion rates along barrier islands of the north central gulf of Mexico

Rates of shoreline change and overwash penetration distances were calculated for barrier islands along the Louisiana, Mississippi, and Alabama coasts with the orthogonal grid mapping system (OGMS). Average rates of shoreline change are exceptionally high in Louisiana, being of the order ?4.7 to ?7.4 m yr^?1. Mississippi and Alabama recession rates are lower and range from ?2.0 to ?3.1 m yr^?1 over the period of record. Erosion rates along the shorelines of these islands have remained relatively constant over the period of study with five exceptions in coastal Louisiana and the Chandeleur-Breton Islands Arc, and two exceptions along the Mississippi-Alabama barrier islands where they have accelerated. Mean overwash penetration is greatest along Dauphin Island, Alabama, and Cat Island, Mississippi: 207.6 and 197.9 m, respectively. The Chandeleur-Brenton Islands Arc range from 88.1 m at the central barrier to 180.4 along the flanks. The Mississippi islands range from 105.2 m on Ship Island to 200.5 m along central Horn Island. Mean overwash penetration along the Louisiana barriers is highly variable: 46.3 to 211.4 m.     

Komatiites and nickel sulfide ores of the Black Swan area,Yilgarn Craton,Western Australia. 3: Komatiite geochemistry,and implications for ore forming processes

The Black Swan komatiite sequence is a package of dominantly olivine-rich cumulates with lesser volumes of spinifex textured rocks, interpreted as a section through an extensive komatiite lava flow field. The sequence hosts a number of nickel sulfide orebodies, including the Silver Swan massive shoot and the Cygnet and Black Swan disseminated orebodies. A large body of whole rock analyses on komatiitic rocks from the Black Swan area has been filtered for metasomatic effects. With the exception of mobile elements such as Ca and alkalis, most samples retain residual igneous geochemistry, and can be modelled predominantly by fractionation and accumulation of olivine. Whole rock MgO–FeO relationships imply a relatively restricted range of olivine compositions, more primitive than the olivine which would have been in equilibrium with the transporting komatiite lavas, and together with textural data indicate that much of the cumulus olivine in the sequence was transported. Flow top compositions show evidence for chromite saturation, but the cumulates are deficient in accumulated chromite. Chromite compositions are typical of those found in compound flow-facies komatiites, and are distinct from those in komatiitic dunite bodies. Incompatible trace element abundances show three superimposed influences: control by the relative proportion of olivine to liquid; a signature of crustal contamination and an overprint of metasomatic introduction of LREE, Zr and Th. This overprint is most evident in cumulates, and relatively insignificant in the spinifex rocks. Platinum and palladium behaved as incompatible elements and are negatively correlated with MgO. They show no evidence for wholesale depletion due to sulfide extraction, which was evidently restricted to specific lava tubes or pathways. The lack of correspondence between PGE depletion and contamination by siliceous material implies that contamination alone is insufficient to generate S-saturation and ore formation in the absence of sulfide in the assimilant. Contamination signatures in spinifex-textured rocks may be a guide to Ni-sulfide mineralisation, but are not entirely reliable in the absence of other evidence. The widespread vesicularity of the sequence may be attributable to assimilated water rather than to primary mantle-derived volatiles, and cannot be taken as evidence for primary volatile-rich magmas. The characteristic signature of the Black Swan Succession is the presence of highly localised disseminated sulfide within a sequence showing more widespread evidence for crustal contamination and interaction with its immediate substrate. This has important implications for the applicability of trace element geochemistry in exploration for komatiite-hosted nickel deposits.Electronic Supplementary Material Supplementary material is available in the online version of this article at Editorial handling: Peter Lightfoot     

Komatiites and nickel sulfide ores of the Black Swan area,Yilgarn Craton,Western Australia. 4. Platinum group element distribution in the ores,and genetic implications

The Black Swan komatiite sequence, in the Eastern Goldfields province of the Archaean Yilgarn Craton in Western Australia, is a body of dominantly olivine-rich cumulates with lesser volumes of spinifex textured rocks, interpreted as a section through an extensive komatiite lava flow field. The sequence hosts a number of nickel sulfide orebodies, including the Silver Swan massive shoot and the Cygnet and Black Swan disseminated orebodies. The massive sulfide orebodies of the Black Swan Succession are pervasively depleted in all platinum group elements (PGEs), particularly Pt and Pd, despite very high Ni contents. This depletion cannot be explained by R-factor variations, which would also require relatively low Ni tenors. The PGE depletion could be explained in part if the ores are enriched in a monosulfide solid solution (MSS) cumulate component, but requires some additional fractional segregation of sulfide melt upstream from the site of deposition. The Silver Swan orebody shows a remarkably consistent vertical zonation in PGE contents, particularly in Ir, Ru, Rh, Os, which increase systematically from very low levels at the stratigraphic base of the sulfide body to maxima corresponding roughly with the top of a lower layer of the orebody rich in silicate inclusions. Platinum shows the opposite trend, but is somewhat modified by remobilisation during talc carbonate alteration. A similar pattern is also observed in the adjacent White Swan orebody. This zonation is interpreted and modelled as the result of fractional crystallisation of MSS from the molten sulfide pool. The strong IPGE depletion towards the base of the orebody may be a consequence of sulfide liquid crystallisation in an inverted thermal gradient, between a thin rapidly cooling upper rind of komatiite lava and a hot substrate.Electronic Supplementary Material Supplementary material is available in the online version of this article at Editorial handling: Peter Lightfoot     

Velocity and runout simulation of destructive debris flows and debris avalanches in pyroclastic deposits,Campania region,Italy

The Campanian Apennines are characterized by the presence of monocline ridges, mainly formed by limestone. During the periods of volcanic activity of the Somma-Vesuvius and Phlegrean Fields, the ridges were mantled with pyroclastic materials in varying thickness. The pyroclastics have been involved in destructive landslides both in historical time and in the recent past (1997, 1998, 1999). The landslides occur following intense and prolonged rainfalls. In some cases, landslides extended up to 4 km into the surrounding lowlands and reached towns, causing severe destruction and over 200 deaths. Generally, the landslides begin as small debris slides that develop into large, shallow debris avalanches or debris flows involving pyroclastic horizons and colluvial soils (0.5–2 m thick) on steep and vegetated slopes, often at the heads of gullies. During motion, the landslide materials eroded vegetation and soils from the slope, so that the moving material volume tended to increase. Then, proceeding towards and beyond the base of the slopes, the phenomena evolved into hyperconcentrated streamflow due to dilution by incorporating water. The results of motion analyses are described. An empirical rheological relationship was used including two principal terms that depend on the total normal stress and on the flow velocity. On this basis, the model has simulated the velocity and duration of debris avalanches and the distribution of the deposits. The selected areas were those of Sarno/Quindici and Cervinara, where a large amount of data is available both on the material properties and geomorphological setting. It was found that the majority of the cases at the two sites can be simulated successfully with only one specific pair of rheologic parameters. This provides the possibility for first-order predictions to be made of the motion of future landslides. Such predictions will be a valuable tool for outlining potential hazard areas and designing remedial measures.     

Distribution of heavy metals in marine bivalves, fish and coastal sediments in the Gulf and Gulf of Oman

An assessment of marine contamination due to heavy metals was made in the Gulf and Gulf of Oman based on marine biota (fish and various bivalves) and coastal sediment collected in Bahrain, Oman, Qatar, and the United Arab Emirates (UAE) during 2000-2001. Sediment metal loadings were generally not remarkable, although hot spots were noted in Bahrain (Cu, Hg, Pb, Zn) and on the east coast of the UAE (As, Co, Cr, Ni). Concentrations of As and Hg were typically low in sediments and the total Hg levels in top predator fish commonly consumed in the region were < 0.5 microg g(-1) and posed no threat to public health. Very high Cd concentrations (up to 195 microg g(-1)) in the liver of some fish from southern Oman may result from food-chain bioaccumulation of elevated Cd levels brought into the productive surface waters by upwelling in the region. Very high As concentrations (up to 156 microg g(-1)) were measured in certain bivalve species from the region. Although not certain, the As is probably derived from natural origins rather than anthropogenic contamination.     

Evidence of chromosomal damage in common eiders (Somateria mollissima) from the Baltic Sea

Common eiders nesting in the Baltic Sea are exposed to generally high levels of contaminants including potentially genotoxic polycyclic aromatic hydrocarbons and organochlorines. Blood samples were collected from eiders at eight sites in the Baltic Sea and two sites in the Beaufort Sea. DNA content variation was estimated using the flow cytometric method, and subsequently utilized as a biomarker of genetic damage. We observed no significant differences in genetic damage among populations within either the Baltic or Beaufort Seas. However, eider populations from the Baltic Sea had significantly elevated estimates of genetic damage compared to populations from the Beaufort Sea.     

Influence of impact ionisation detection methods on determination of dust particle flux in space

Results are presented for a series of experiments investigating effects which can influence the interpretation of data from ionisation-based dust detectors carried on spacecraft. First, the variation of the impact ionisation yield with angle of impact was studied for impacts of iron microparticles onto gold at speeds of 1-. The angle of incidence was from 0° (normal incidence) to 80° (glancing incidence). Little or no variation was observed at angles up to 60°, but at 80° the total impact ionisation signal was around an order of magnitude lower than at smaller angles. In addition, the fast rising component of the ionisation signal rise time showed no variation with impact angle, but the total signal rise time showed a steady decrease. The effect of secondary impact ionisation resulting from particle impacts on detector side walls was also studied. Iron microparticles were fired on to an aluminium target at various angles, and the impact ionisation signal on a nearby gold target was measured. It was found that ionisation signals were observed on the gold target, and that these were very similar in appearance to those observed in direct impacts.The effect of reduction in particle charge on an impact ionisation signal was investigated. Iron microparticles were fired on to a gold target after passing through a thin film which reduced the charge which was used to accelerate them. It was found that there was a measurable drop in ionisation signal in the reduced-charge case. The empirical relation I_IONISATION=1.67×10⁻⁹Q_PARTICLE^0.35 (units of C) was found. This implies there is a component in the observed ionisation signal that is not related to the impact. To test this, charged tungsten carbide particles were dropped at very low velocity onto a replica of a dust detector used in space whilst placed in a vacuum chamber. Ionisation signals were frequently recorded by the detector. It was concluded that this signal originated from the incident particle charge.In the final section of work, as an example, the influence of oblique incidence, side-wall impacts and particle charge effects on data collected by the Gorid dust detector in Earth orbit were investigated. Corrections were applied to the mass and velocity distributions derived from Gorid data. In extremis, oblique incidence effects were found to shift the mass distribution down by an order of magnitude, and the velocity distribution up by a factor of two to three. If all the data had come from unrecognised side-wall impacts, the mass distribution would be shifted downwards to lower masses by three orders of magnitude, and the velocity distribution upwards by a factor of five. Possible particle charge effects were found to shift the mass distribution down by 30%, and did not alter the velocity distribution.Overall we have investigated a variety of impact-related phenomena and conclude that these can affect the interpretation of data from instruments deployed in space.     

Whole-bird models for the magnetic cleansing of oiled feathers

Iron powder, a promising dry-cleansing agent for oiled feathers where both the contaminant and the cleansing agent may be harvested magnetically, has been tested on the plumage of whole-bird models. The breast and back plumage of Mallard Duck (Anas platyrhynchos) and Little Penguin (Eudyptula minor) carcasses were patch-contaminated with commercial-grade engine oil, three different crude oils, and an oil/seawater emulsion. The plumage was then subjected to a magnetic cleansing protocol. The contaminant removal was assessed gravimetrically and was found to reflect the outcomes for a previously reported in vitro study using feather clusters. Between 92-98% of the contaminants, and effectively all of the cleansing agent, were removed from the feathers.