Composition,oxygen isotope geochemistry and origin of smectite in the metalliferous sediments of the Bauer Deep,southeast Pacific

The sediments of the Bauer Deep, an open ocean basin situated on the northwest Nazca Plate in the southeast Pacific, constitute a regional metalliferous deposit dominated by authigenic smectite.Two 2-metre long cores from the Bauer Deep were examined to investigate the nature and origin of the smectite.Infra-red and Mossbauer spectroscopy and wet chemical analysis (LiBO₂ fusion) of isolated smectite, indicate the mineral is a Mg-rich, Al-rich nontronite. Oxygen isotopic compositions for isolated smectite are uniform and translate to a non-hydrothermal temperature of formation of about 3°C. SEM observations show an abundance of well-preserved biogenic opal in surface and near surface sediment but postburial dissolution and transformation of this phase to smectite is evident at depth.Smectite formation is the result of interaction between iron oxyhydroxide, ponded in the Bauer Deep following a hydrothermal origin at the adjacent East Pacific Rise, and biogenic opal. A reaction mechanism is proposed.Regional factors control smectite formation. In particular, formation is inhibited in areas of CaCO₃ accumulation (topographic elevations) but favoured in areas of oxyhydroxide and opal ponding (topographic depressions).     

SIMPLE ANALYTICAL SOLUTIONS FOR THE HP41CV PROGRAMMABLE CALCULATOR

Abstract. Two useful programs have been developed for the Hewlett Packard HP41CV programmable calculator. The THEIS program is designed to simulate a well pumping from a confined or unconfined aquifer. Drawdown, residual drawdown, t/t₁ and t/r² are calculated. The BOUN program is designed to solve for drawdown in a well pumping from an aquifer bounded by two parallel impermeable barriers. The programs can be used in aquifer pumping test design, pumping test analysis, and aquifer response predictions.     

Tarawera 1886, New Zealand — A basaltic plinian fissure eruption

New Zealand's biggest and most destructive volcanic eruption of historical times was that of Tarawera in 1886. The resulting scoria fall has a dispersal very similar in extent to that of the Vesuvius A.D. 79 pumice fall and is one of the few known examples of a basaltic deposit of plinian type. A new estimate of the volume (2 km³) is significantly greater than previous estimates. The basalt came mainly from a 7-km length of fissure, and emission and exit velocity were fairly uniform along at least 4 km of it, this is one of the few documented examples of a plinian eruption from a fissure vent. Primary welding of the scoria fall resulted where the accumulation rate exceeded about 250 mm min⁻¹. A model of the eruption dynamics is proposed which leads to an estimate of 28 km for the height of the eruption cloud and implies a magma volatile fraction of 1.5–3%. Violent phreatic explosions occurred in the southwestern extension of the fissure across the Rotomahana geothermal field, and it is thought that some of the water responsible for the power of the plinian eruption came from this source, though its amount was not sufficient to turn the eruption into a phreatoplinian one.     

Distribution and mode of occurrence of zinc and lead in glacial soils

The distribution and mode of occurrence of zinc and lead have been examined in glacial soils developed over a complex Precambrian marble-paragneiss terrain in the Adirondack Mountains of New York. Based on distribution within the soil profiles, zinc is enriched in the B₁ horizon of soils sampled over marble and lead is generally enriched in the A horizon, particularly in soils developed over paragneiss. Contrast is calculated using

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, where is the mean of n_A anomalous and n_B background samples, and S_p is the pooled standard deviation) for zinc, lead and cold-extractable heavy metals in soils sampled over marble and paragneiss. The t-values indicate that the B₁, soil horizon is the most suitable for sampling on a regular basis, even though lead is most concentrated in the A horizon.The distribution of zinc and lead among exchangeable, organic, iron-manganese oxide, clay, silt and sand fractions of B₁ horizons from two anomalous and one background soil indicates that both zinc and lead are tied up principally in iron and manganese oxides. The anomalous samples exhibit zinc enrichment in the Fe-oxide digestion and high Mn/Fe ratios for the Mn-oxide digestion (as well as the total analysis). In terms of total contribution to the sample, significant proportions of zinc in the clastic fraction can be attributed to zinc substitution into clays plus the ineffective removal of Fe-oxides by the ammonium oxalate extraction procedure. Lead, on the other hand, occurs in significant concentrations in clay, silt and sand as well as Fe- and Mn-oxides, probably as a trace constituent in feldspars or adsorbed onto clay surfaces.     

Buried trees,water table fluctuations,and 3000 years of changing climate in west-central Oklahoma

A sequence of radiocarbon-dated buried trees, buried soils, a carbonate zone, and a molluscan fauna from Carnegie Canyon indicate that between 3200 and 2600 yr B.P. the climate of west-central Oklahoma was drier than today. A high water table accompanied a period of moister climate 2000 to 1000 yr B.P. The water table dropped after 1000 yr B.P. due to a change toward dry conditions.     

Hydrogen speciation in synthetic quartz

The dominant hydrogen impurity in synthetic quartz is molecular H₂O. H-OH groups also occur, but there is no direct evidence for the hydrolysis of Si-O-Si bonds to yield Si-OH HO-Si groups. Molecular H₂O concentrations in the synthetic quartz crystals studied range from less than 10 to 3,300 ppm (H/Si), and decrease smoothly by up to an order of magnitude with distance away from the seed. OH^? concentrations range from 96 to 715 ppm, and rise smoothly with distance away from the seed by up to a factor of three. The observed OH^? is probably all associated with cationic impurities, as in natural quartz. Molecular H₂O is the dominant initial hydrogen impurity in weak quartz. The hydrolytic weakening of quartz may be caused by the transformation H₂O + Si-O-Si → 2SiOH, but this may be a transitory change with the SiOH groups recombining to form H₂O, and the average SiOH concentration remaining very low. Synthetic quartz is strengthened when the H₂O is accumulated into fluid inclusions and cannot react with the quartz framework.     

Computer simulations of the structural and physical properties of the olivine and spinel polymorphs of Mg2SiO4

The aim of the work presented is to develop a computer simulation technique which will predict the structure and physical properties of forsterite and ringwoodite, the major mantle-forming polymorphs of Mg₂SiO₄. The technique is based upon energy minimization, in which all structural parameters are varied until the configuration with the lowest energy is achieved. The lattice energy and physical properties (e.g. elasticity and dielectric constants) are calculated from interatomic potentials, which generally include electrostatic and short-range terms. We investigate several types of traditional potential models, and present a new type of model which includes partial ionic charges and a Morse potential to describe the effect of covalency on the Si-O bond. This new form of potential model is highly successful, and not only reproduces the zero-pressure structural, elastic and dielectric properties of forsterite and ringwoodite, but also accurately describes their pressure dependence.     

Comparative growth of juvenile white sturgeon and striped bass: Effects of temperature and hypoxia

The influences of temperature and environmental hypoxia on the growth rates of two California anadromous fishes, white sturgeon (Acipenser transmontanus) and striped bass (Morone saxatilis) were examined. Fish (0.5–0.6 g initial weight) were fedad libitum rations ofArtemia in flow-through aquaria regulated for temperature (15, 20, and 25°C) and oxygen tension (130 and 90 torr P_{o 2}). Growth of sturgeon was significantly greater at 20 °C compared with 15 °C, but there was no difference between 20 and 25 °C. Striped bass growth increased with each 5° increment of temeprature elevation to 3.2% body weight per d at 25 °C, the fastest growth rate measured. The temperature of maximum growth reflected the temperature of the native estuarine rearing area. Environmental hypoxia (90 torr P_{o 2}) reduced growth of sturgeon within each temperature level, whereas striped bass growth was reduced by hypoxia only at the upper two temperatures. Sturgeon were much more active in the growth chambers than striped bass. Sturgeon activity increased with each 5 °C temperature increase under normoxia and hypoxia, except at 25 °C (hypoxia) where activity was insignificantly different from that at 20 °C (hypoxia).     

Forecasting in the social and natural sciences: An overview and analysis of isomorphisms

This article identifies and analyzes several points of similarity in the structure and context of forecasting in the social and natural sciences. These include: the limits of identities or universal laws as a basis for forecasts; the corresponding need for simplifying parametric representations of one or more of the variables that enter into identities; various sources of uncertainty about parameterizations; intrinsic limitations on predictability or forecasting accuracy in large-scale systems; the need for sensitivity analyses of model responses to changes in exogenous variables and/or parametric structures; problems of model linkage; and the social (organizational and political) context of forecasts. Suggestions for future lines of inquiry are made in each case. Several of these are such that they can benefit from a sharing of experience and expertise across disciplinary lines.The research reported herein was supported in part by the IC² Institute, The University of Texas at Austin, and in part by National Science Foundation Grant Number SES-8411702. However, the opinions expressed in the paper are those of the authors and do not necessarily reflect those of the sponsoring organizations. We appreciate the advice and comments of Jesse H. Ausubel, Robert S. Chen, Judith Jacobsen, and Richard C. Rockwell on earlier versions of this paper.The National Center for Atmospheric Research is sponsored by the National Science Foundation.