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21.
Stephan R. de Roode Harm J. J. Jonker Peter G. Duynkerke Bjorn Stevens 《Boundary-Layer Meteorology》2004,112(1):179-196
Large-eddy simulations of a clear convective boundary layer (CBL)and a stratocumulus-topped boundary layer are studied. Bottom-upand a top-down scalars were included in the simulations, and theprinciple of linear superposition of variables was applied toreconstruct the fields of any arbitrary conserved variable.This approach allows a systematic analysis of countergradient fluxesas a function of the flux ratio, which is defined as the ratio betweenthe entrainment flux and the surface flux of the conserved quantity.In general, the turbulent flux of an arbitrary conserved quantityis counter to the mean vertical gradient if the heights where thevertical flux and the mean vertical gradient change sign do notcoincide. The regime where the flux is countergradient is thereforebounded by the so-called zero-flux and zero-gradient heights. Becausethe vertical flux changes sign only if the entrainment flux has anopposite sign to the surface flux, countergradient fluxes arepredominantly found for negative flux ratios. In the CBL the fluxratio for the virtual potential temperature is, to a good approximation,constant, and equal to -0.2. Only if the moisture contribution to thevirtual potential temperature is negligibly small will the flux ratio forthe potential temperature be equal to this value. Otherwise, theflux ratio for the potential temperature can have any arbitrary(negative) value, and, as a consequence, the fluxes for thepotential temperature and the virtual potential temperature willbe countergradient at different heights. As a practical application ofthe results, vertical profiles of the countergradient correction termfor different entrainment-to-surface-flux ratios are discussed. 相似文献
22.
The position of the transition from spinel peridotite to garnet peridotite in a simplified chemical composition has been determined experimentally at high pressures and high temperatures. The univariant reaction MgCr2O4+2Mg2Si2O6=Mg3Cr2Si3O12+Mg2SiO4, has a negative slope in P–T space between 1200 °C and 1600 °C. The experimental results, combined with assessed thermodynamic data for MgCr2O4, MgSiO3 and Mg2SiO4 give the entropy and enthalpy of formation of knorringite garnet (Mg3Cr2Si3O12). Thermodynamic calculations in simplified chemical compositions indicate that Cr shifts the garnet-in reaction to much higher pressures than previously anticipated. Moreover, in Cr-bearing systems a pressure–temperature field exists where garnet and spinel coexist. The width of this divariant field strongly depends on the Cr/(Cr+Al) of the system. 相似文献
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Neil F. Glasser Stephan Harrison 《Geografiska Annaler: Series A, Physical Geography》2005,87(3):421-430
Whalebacks are convex landforms created by the smoothing of bedrock by glacial processes. Their formation is attributed to glacial abrasion either by bodies of subglacial sediment sliding over bedrock or by individual clasts contained within ice. This paper reports field measurements of sediment depth around two whaleback landforms in order to investigate the relationship between glacigenic deposits and whaleback formation. The study site, at Lago Tranquilo in Chilean Patagonia, is situated within the Last Glacial Maximum (LGM) ice limits. The two whalebacks are separated by intervening depressions in which sediment depths are generally 0.2 to 0.3 m. Two facies occur on and around the whalebacks. These facies are: (1) angular gravel found only on the surface of the whalebacks, interpreted as bedrock fracturing in response to unloading of the rock following pressure release after ice recession, and (2) sandy boulder‐gravel in the sediment‐filled depressions between the two whalebacks, interpreted as an ice‐marginal deposit, with a mixture of sediment types including basal glacial and glaciofluvial sediment. Since the whalebacks have heavily abraded and striated surfaces but are surrounded by only a patchy and discontinuous layer of sediment, the implication is that surface abrasion of the whalebacks was achieved primarily by clasts entrained in basal ice, not by subglacial till sliding. 相似文献
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Effect of melt composition on the partitioning of trace elements between titanite and silicate melt 总被引:7,自引:0,他引:7
Isobaric and isothermal experiments were performed to investigate the effect of melt composition on the partitioning of trace elements between titanite (CaTiSiO5) and a range of different silicate melts. Titanite-melt partition coefficients for 18 trace elements were determined by secondary ion mass spectrometry (SIMS) analyses of experimental run products. The partition coefficients for the rare earth elements and for Th, Nb, and Ta reveal a strong influence of melt composition on partition coefficients, whereas partition coefficients for other studied monovalent, divalent and most quadrivalent (i.e., Zr, Hf) cations are not significantly affected by melt composition. The present data show that the influence of melt composition may not be neglected when modelling trace element partitioning.It is argued that it is mainly the change of coordination number and the regularity of the coordination space of trace elements in the melt structure that controls partition coefficients in our experiments. Furthermore, our data also show that the substitution mechanism by which trace elements are incorporated into titanite crystals may be of additional importance in this context. 相似文献
26.
Partitioning of trace elements between rutile and silicate melts: Implications for subduction zones 总被引:9,自引:0,他引:9
Mineral/melt trace element partition coefficients were determined for rutile (TiO2) for a large number of trace elements (Zr, Hf, Nb, Ta, V, Co, Cu, Zn, Sr, REE, Cr, Sb, W, U, Th). Whilst the high field strength elements (Zr, Hf, Nb, Ta) are compatible in rutile, other studied trace elements are incompatible (Sr, Th, REE). In all experiments we found DTa > DNb, DHf > DZr and DU > DTh. Partition coefficients for some polyvalent elements (Sb, W, and Co) were sensitive to oxygen fugacity. Melt composition exerts a strong influence on HFSE partition coefficients. With increasing polymerization of the melt, rutile/melt partition coefficients for the high field strength elements Zr, Hf, Nb and Ta increase about an order of magnitude. However, DNb/DTa and DHf/DZr are not significantly affected by melt composition. Because DU ? DTh, partial melting of rutile-bearing eclogite in subducted lithosphere may cause excesses of 230Th over 238U in some island arc lavas, whereas dehydration of subducted lithosphere may cause excesses of 238U over 230Th. From our partitioning results we infer partition coefficients for protactinium (Pa) which we predict to be much lower than previously anticipated. Contrary to previous studies, our data imply that rutile should not significantly influence observed 231Pa-235U disequilibria in certain volcanic rocks. 相似文献
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Lise Byskov Herslund Fatemeh Jalayer Nathalie Jean-Baptiste Gertrud Jørgensen Sigrun Kabisch Wilbard Kombe Sarah Lindley Patrik Karlsson Nyed Stephan Pauleit Andreas Printz Trond Vedeld 《Natural Hazards》2016,82(2):149-172
In this paper, we develop and apply a multi-dimensional vulnerability assessment framework for understanding the impacts of climate change-induced hazards in Sub-Saharan African cities. The research was carried out within the European/African FP7 project CLimate change and Urban Vulnerability in Africa, which investigated climate change-induced risks, assessed vulnerability and proposed policy initiatives in five African cities. Dar es Salaam (Tanzania) was used as a main case with a particular focus on urban flooding. The multi-dimensional assessment covered the physical, institutional, attitudinal and asset factors influencing urban vulnerability. Multiple methods were applied to cover the full range of vulnerabilities and to identify potential response strategies, including: model-based forecasts, spatial analyses, document studies, interviews and stakeholder workshops. We demonstrate the potential of the approach to assessing several dimensions of vulnerability and illustrate the complexity of urban vulnerability at different scales: households (e.g., lacking assets); communities (e.g., situated in low-lying areas, lacking urban services and green areas); and entire cities (e.g., facing encroachment on green and flood-prone land). Scenario modeling suggests that vulnerability will continue to increase strongly due to the expected loss of agricultural land at the urban fringes and loss of green space within the city. However, weak institutional commitment and capacity limit the potential for strategic coordination and action. To better adapt to urban flooding and thereby reduce vulnerability and build resilience, we suggest working across dimensions and scales, integrating climate change issues in city-level plans and strategies and enabling local actions to initiate a ‘learning-by-doing’ process of adaptation. 相似文献
30.
Stephan Steinke Till J.J. Hanebuth Christoph Vogt Karl Stattegger 《Marine Geology》2008,250(3-4):199-210
Variations in clay mineral composition of sediment cores from the margin and continental slope of the Sunda Shelf (southern South China Sea, SE Asia) covering the past 17,000 yr reflect changing influences of sediment sources together with clay mineral partitioning processes in shallow waters. We identify the deglacial sea level rise as the principal factor driving these changes. During the late glacial, high values of kaolinite are interpreted to reflect a higher contribution of clays from soils that have formed on the exposed Sunda Shelf and in the southern archipelagos of Indonesia. At this time core sites were located in close proximity to the mouths of the Sunda Shelf palaeo-drainage systems on the emerged shelf (“Sundaland”). The progressive landward displacement of the coastline and breakdown of these vast drainage systems during deglaciation led to a decrease in influence of the kaolinite-rich southern sources. When the coastline had retreated closely to its present-day position in mid-Holocene times, the former dominance of southern sources was replaced by a stronger influence of illite-rich sources (e.g. Borneo). The overriding control of sea level changes on the clay mineral distribution patterns precludes a definite climatic interpretation of clay mineral data in terms of climatic/monsoonal changes in such highly dynamic sedimentary environment. 相似文献