Effects of the peat acid digestion protocol on geochemically and morphologically diverse tephra deposits

Tephra shards for electron probe microanalysis are most efficiently extracted from peat using acid digestion, which removes organic material that hinders density separation methods. However, strong acids are known to alter glass chemical compositions, and several studies have examined how acid digestion affects rhyolitic volcanic glass. The focus on rhyolitic tephra in these studies leaves considerable uncertainty, as the dissolution rates of natural glasses (including tephra) are determined by the chemical composition and surface area/volume ratio, both of which vary in tephra deposits. Here, we use duplicate samples of basaltic, trachydacitic and rhyolitic tephra to examine physical and geochemical alteration following acid digestion. Scanning electron microscope imagery reveals no discernible degradation of glass surfaces, and electron probe microanalysis results from duplicate samples are statistically indistinguishable. These findings suggest the acid digestion protocol for organic peats does not significantly alter glass geochemistry regardless of shard morphologies or geochemical compositions.     

Salt-induced crestal faults control the formation of Quaternary tunnel valleys in the southern North Sea

Tunnel valleys are major features of glaciated margins and they enable meltwater expulsion from underneath a thick ice cover. Their formation is related to the erosion of subglacial sediments by overpressured meltwater and direct glacial erosion. Yet, the impact of pre-existing structures on their formation and morphology remains poorly known. High-quality 3D seismic data allowed the mapping of a large tunnel valley that eroded underlying preglacial delta deposits in the southern North Sea. The valley follows the N–S strike of crestal faults related to a Zechstein salt wall. A change in downstream tunnel valley orientation towards the SE accompanies a change in the strike direction of salt-induced faults. Fault offsets indicate important activity of crestal faults during the deposition of preglacial deltaic sediments. We propose that crestal faults facilitated tunnel valley erosion by acting as high-permeability pathways and allowing subglacial meltwater to reach low-permeability sediments in the underlying Neogene deltaic sequences, ultimately resulting in meltwater overpressure build-up and tunnel valley excavation. Active faults probably also weakened the near-surface sediment to allow a more efficient erosion of the glacial substrate. This control of substrate structures on tunnel valley morphology is considered as a primary factor in subglacial drainage pattern development in the study area.     

Comparison of ladderane phospholipid and core lipids as indicators for anaerobic ammonium oxidation (anammox) in marine sediments

We investigated anaerobic ammonium oxidation (anammox) in continental shelf and slope sediments of the Irish and Celtic Seas by using anammox specific ladderane biomarker lipids. We used the presence of an intact ladderane phospholipid as a direct indicator for living anammox bacteria, and compared it with the abundance of ladderane core lipids derived from both living and dead bacterial biomass. All investigated sediments contained ladderane core lipids as well as the intact ladderane phospholipid, in agreement with ¹⁵N-labeling experiments, which revealed anammox activity at all sites. Ladderane core lipid and intact ladderane phospholipid concentrations were significantly correlated (R² = 0.957 and 0.464, respectively) with anammox activity over the transect of the continental shelf and slope sediments. In the Irish Sea (50-100 m water depth) highest abundances of the intact ladderane phospholipid were found in the upper 2 cm of the sediment, indicating a zone of active anammox. A sharp decline further down-core suggested a strong decrease in anammox biomass and rapid degradation of the intact lipids. In comparison, ladderane core lipids were 1-2 orders of magnitude higher in concentration than the intact ladderane phospholipid and accumulated as dead cell remnants with depth. In the slope sediments of the Celtic Sea both ladderane core lipids and the intact ladderane phospholipid were found in sediments at water depths ranging from 500 to 2000 m. Here, anammox seemed to be active at greater depths of the sediment (>2 cm). Mean abundances of both intact and core ladderane lipids in whole sediment cores increased downslope, indicating an increasing importance of anammox in deeper slope sediments.     

Structure of the Keck Telescope — An overview

The structure of the Keck Telescope is briefly described. The design required an innovative approach made necessary by the revolutionary nature of the segmented primary mirror, by the very stringent weight and cost limitations, and by observational and operational needs. Analysis of a progressively more detailed computer model predicts that all design objectives will be met, as shown in a summary of performance characteristics. The paper is illustrated with a number of drawings.Paper presented at the Symposium on the JNLT and Related Engineering Developments, Tokyo, November 29–December 2 1988.     

The impact of uncertain emission trading markets on interactive resource planning processes and international emission trading experiments

Interactive resource planning is an increasingly important aspect of emission trading markets. The conferences of Rio de Janeiro, 1992, and Kyoto, 1997, originally focusing on environmental protection at both macro- and micro-economic levels, called for new economic instruments of this kind. An important economic tool in this area is Joint Implementation (JI), defined in Article 6 of the Kyoto Protocol. Sustainable development can be guaranteed only if JI is embedded in optimal energy management. In this contribution we describe and evaluate one international procedure within uncertain markets which helps to establish optimal energy management and interactive resource planning processes within uncertain emission trading markets.     

North Atlantic climate impact on early late‐glacial climate oscillations in the south‐eastern Alps inferred from a multi‐proxy lake sediment record

High‐resolution multi‐proxy analyses of a sediment core section from Lake Jeserzersee (Saissersee) in the piedmont lobe of the Würmian Drau glacier (Carinthia, Austria) reveal pronounced climatic oscillations during the early late glacial (ca. 18.5–16.0k cal a BP). Diatom‐inferred epilimnetic summer water temperatures show a close correspondence with temperature reconstructions from the adjacent Lake Längsee record and, on a hemispheric scale, with fluctuations of ice‐rafted debris in the North Atlantic. This suggests that North Atlantic climate triggered summer climate variability in the Alps during the early late glacial. The expansion of pine (mainly dwarf pine) between ca. 18.5 and 18.1k cal a BP indicates warming during the so‐called ‘Längsee oscillation’. The subsequent stepwise climate deterioration between ca. 18.1 and 17.6k cal a BP culminated in a tripartite cold period between ca. 17.6 and 16.9k cal a BP with diatom‐inferred summer water temperatures 8.5–10 °C below modern values and a shift from wet to dry conditions. This period probably coincides with a major Alpine glacier advance termed the Gschnitz stadial. A warmer interval between ca. 16.9 and 16.4k cal a BP separates this cold phase from a second, shorter and less pronounced cold phase between ca. 16.4 and 16.0k cal a BP, which is thought to correlate with the Clavadel/Senders glacier advance in the Alps. The following temperature increase, coupled with wet (probably snow‐rich) conditions, caused the expansion of birch during the transition period to the late glacial interstadial. Copyright © 2011 John Wiley & Sons, Ltd.     

How does landfill leachate affect the chemical processes in a lake system downgradient from a landfill site?

A field study on the geochemical properties of a chemically-stressed limnic environment was performed in Lake Silbersee, which receives leachate water of high inorganic loading from an upgradient landfill site. The highly concentrated sulfate ion in groundwater, when entering the pore water system of the lake, gives rise to an intensive microbial sulfate reduction. A diagenetic approach was used to explain the existence of a marine-like aqueous system within a geologically slightly acidic aquifer, consisting of a well-buffered lake water and an alkalinity producing, excess sulphide containing sediment pore water system.     

Winter precipitation variability and large-scale circulation patterns in Romania

Summary The spatial and temporal variability of winter precipitation and its links to the large-scale atmospheric circulation patterns in Romania are examined. The data set is composed of observed rainfall at 30 meteorological stations during the 1961–1996 period. The large-scale field is represented by the observed geopotential height at 500 hPa (Z500) over the same period, covering the latitudinal belt between 20° N–90° N (resolution 2.5°×2.5°).The Standard Normal Homogeneity Test (SNHT) is applied to detect inhomogeneities in the data, and the Mann-Kendall and Pettitt non-parametric tests are used in order to identify trends and change points in the winter precipitation time series. The empirical orthogonal functions (EOF) technique is used for data reduction in order to highlight the basic patterns of rainfall variability in Romania. The covariance map between precipitation EOF time series (PCs) and the Z500 field, as well as the correlation coefficients between the PCs and circulation indices are calculated in order to identify the influence of large-scale circulation patterns on winter precipitation in Romania.A significant decreasing trend is identified in winter precipitation with a downward shift in winter 1969/1970, most significant from a statistical point of view in the extra-Carpathian region. This change seems to be real since the SNHT test does not reveal any inhomogeneity during the period tested. Significant relationships are found between winter precipitation variability in Romania and the large-scale circulation pattern, such as the North Atlantic Oscillation and the blocking phenomenon in the Atlantic-European sector. The positive phase of the NAO and the reduction in blocking activity could be one of the causes of the decrease in winter precipitation in Romania.     

Alpen: Verkehr und fremdenverkehr

Alpen: Verkehr und fremdenverkehr