Effect of melt composition on the partitioning of trace elements between titanite and silicate melt

Isobaric and isothermal experiments were performed to investigate the effect of melt composition on the partitioning of trace elements between titanite (CaTiSiO₅) and a range of different silicate melts. Titanite-melt partition coefficients for 18 trace elements were determined by secondary ion mass spectrometry (SIMS) analyses of experimental run products. The partition coefficients for the rare earth elements and for Th, Nb, and Ta reveal a strong influence of melt composition on partition coefficients, whereas partition coefficients for other studied monovalent, divalent and most quadrivalent (i.e., Zr, Hf) cations are not significantly affected by melt composition. The present data show that the influence of melt composition may not be neglected when modelling trace element partitioning.It is argued that it is mainly the change of coordination number and the regularity of the coordination space of trace elements in the melt structure that controls partition coefficients in our experiments. Furthermore, our data also show that the substitution mechanism by which trace elements are incorporated into titanite crystals may be of additional importance in this context.     

The Tauern Window (Eastern Alps, Austria): a new tectonic map, with cross-sections and a tectonometamorphic synthesis

We present a tectonic map of the Tauern Window and surrounding units (Eastern Alps, Austria), combined with a series of crustal-scale cross-sections parallel and perpendicular to the Alpine orogen. This compilation, largely based on literature data and completed by own investigations, reveals that the present-day structure of the Tauern Window is primarily characterized by a crustal-scale duplex, the Venediger Duplex (Venediger Nappe system), formed during the Oligocene, and overprinted by doming and lateral extrusion during the Miocene. This severe Miocene overprint was most probably triggered by the indentation of the Southalpine Units east of the Giudicarie Belt, initiating at 23–21 Ma and linked to a lithosphere-scale reorganization of the geometry of mantle slabs. A kinematic reconstruction shows that accretion of European lithosphere and oceanic domains to the Adriatic (Austroalpine) upper plate, accompanied by high-pressure overprint of some of the units of the Tauern Window, has a long history, starting in Turonian time (around 90 Ma) and culminating in Lutetian to Bartonian time (45–37 Ma).     

Sedimentology of early Pliocene sandstones in the south-western Taiwan foreland: Implications for basin physiography in the early stages of collision

This work presents sedimentological observations and interpretations on three detailed sections of the Pliocene Yutengping/Ailiaochiao formations, deposited in the early stages of collision in Taiwan. Seven facies associations record paleoenvironments of deposition ranging from nearshore to lower offshore with a strong influence of tidal reworking, even in shelfal sub-tidal environments, and a pro-delta setting characterized by mass-flows. The association of shallow facies of the upper offshore to lower shoreface with pro-delta turbidite facies sourced in the orogen to the east suggests a peculiar setting in which turbidite deposition occurred below wave base but on the shelf, in water depths of probably less than 100 m. This adds to the examples of “shallow turbidites” increasingly commonly found in foreland basins and challenges the classical view of a “deep” early underfilled foreland basin. Time series analysis on tidal rhythmites allow us to identify a yearly signal in the form of periodic changes of sand-supply, energy and bioturbation that suggests a marked seasonality possibly affecting precipitation and sediment delivery as well as temperature. The Taiwan foreland basin may also present a potentially high-resolution record in shallow sediments of the early installation of monsoonal circulation patterns in east Asia. We confirm partly the paleogeography during the early stages of collision in Taiwan: the Chinese margin displayed a pronounced non-cylindrical geometry with a large basement promontory to the west in place of the modern Taiwan mountain range. Collision in Taiwan may have happened at once along the whole length of the modern mountain range, instead of progressively from north to south as classically considered.     

Varved sediments of Lake Yoa (Ounianga Kebir,Chad) reveal progressive drying of the Sahara during the last 6100 years

The sedimentological and geochemical properties of a 7·47 m long laminated sequence from hypersaline Lake Yoa in northern Chad have been investigated, representing a unique, continuous 6100 year long continental record of climate and environmental change in the eastern Central Sahara. These data were used to reconstruct the Mid to Late Holocene history of this currently hyper‐arid region, in order to address the question of whether the Mid Holocene environmental transition from a humid to a dry Sahara was progressive or abrupt. This study involved a suite of analyses, including petrographic and scanning electron microscope examination of thin sections, X‐ray diffraction, X‐radiography, granulometry, loss on ignition and magnetic susceptibility. The potential of micro‐X‐ray fluorescence core scanning was tested at very high resolution. Detailed microscopic investigation revealed the sedimentary processes responsible for the formation of the fine laminations, identified the season during which they were formed, and confirmed their annually rhythmic nature. High‐resolution X‐ray fluorescence core scanning allowed the distinction of each individual lamination over the entire record, opening new perspectives for the study of finely laminated sediment sequences. Geochemical and mineralogical data reveal that, due to decreasing monsoon rainfall combined with continuous and strong evaporation, the hydrologically open and fresh Mid Holocene Lake Yoa slowly evolved into the present‐day hypersaline brine depleted in calcium, which has existed for about the past 1050 years. During the oldest part of the investigated period, Lake Yoa probably contained a permanently stratified lower water column that was nevertheless disrupted relatively frequently by mixing events. Deep‐water anoxia became more stable because of increased salinity‐driven density stratification. In parallel, the sediment grain‐size proxies record a progressive increase of aeolian input in the course of the last 6100 years. Altogether, all geochemical and sedimentological indicators point to a progressive drying of the eastern Central Sahara, strengthening previous conclusions based on palaeoecological indicators.     

The lunar geochemistry of chromium and vanadium

Crystal/liquid partition coefficients for Cr, V, Mn, and Fe have been determined experimentally between olivine, orthopyroxene, clinopyroxene and silicate melt possesing the composition of a primitive lunar green glass, at oxygen fugacities appropriate to the lunar interior. These species all behave essentially as compatible elements and possess crystal/liquid partition coefficients mostly between 0.3 and 0.9. Partition coefficients for Cr, V, and Mn are generally similar to those of Fe. This implies that crystal/liquid fractionation processes in the lunar interior which do not involve the participation of spinels would not have been effective in fractionating MnO, CrO, and VO from FeO. The well-known constancy of FeO/MnO ratios in nearly all lunar rocks is a reflection of this behaviour. It is shown that comparably strong correlations between CrO-;FeO and VO-;FeO exist for lunar highland breccias and soils from all sites and that these correlations extend to primitive lunar volcanic glasses associated with mare volcanism, strongly suggesting that the CrO/FeO and VO/FeO ratios so derived are of global importance. The observed ratios characterizing differentiated regions of the Moon can be combined with the corresponding ratios for residual refractory portions of the Moon, using measured partition coefficients for Fe, Mg, Cr, V, and Mn between olivine, orthopyroxene and liquid. Bulk Moon abundances for Cr and V have been calculated for a range of reasonable assumptions concerning the petrogenetic relationships between differentiated portions of the Moon and complementary refractory residua consisting of olivine and orthopyroxene mineralogies. Because of the small differences in crystal liquid partition coefficients between FeO, CrO, and VO, these estimates are insensitive to large variations in the models. The bulk Moon is accordingly estimated to contain 2190–2463 ppm Cr and 79–95 ppm V. These values are very similar to the Cr and V contents of the Earth's mantle, estimated as 3010 ppm Cr and 81 ppm V by Sun (1982). The geochemical implications of these similarities are discussed.     

Correction to: Leveraging HPC accelerator architectures with modern techniques — hydrologic modeling on GPUs with ParFlow

Computational Geosciences - A Correction to this paper has been published: https://doi.org/10.1007/s10596-021-10065-y     

New major element analyses of proximal tephras from the Azores and suggested correlations with cryptotephras in North-West Europe

The Azores Archipelago is one of the most active volcanic areas in the North Atlantic region. Approximately 30 eruptions have been reported over the last 600 years with some major VEI 5 (Volcanic Explosivity Index) eruptions further back in time. The geochemical composition of associated tephra-derived glass, however, is not well characterized. An Azorean origin of cryptotephras found in distal areas such as North Africa, the British Isles and Greenland has been suggested, but proximal data from the Azores are scarce and the correlations have only been tentative. These tephras have a traychtic composition, which excludes an Icelandic origin. In a previous study, we presented major element analyses of proximal tephra-derived glass from five Holocene eruptions on the Azores Islands. There is a striking geochemical similarity between tephras from volcanoes on São Miguel and Irish cryptotephras, and especially with eruptives from the Furnas volcano. Here we present new analyses of proximal tephras that confirm and strengthen a link between Furnas and cryptotephras found in south-west Ireland. We also suggest a correlation between a previously unsourced tephra found in a Swedish bog with an eruption of the Sete Cidades volcano c. 3880 a cal BP.     

Assessing anthropogenic impacts on limited water resources under semi-arid conditions: three-dimensional transient regional modelling in Jordan

Both increasing aridity and population growth strongly stress freshwater resources in semi-arid areas such as Jordan. The country’s second largest governorate, Irbid, with over 1 million inhabitants, is already suffering from an annual water deficit of 25 million cubic meters (MCM). The population is expected to double within the next 20 years. Even without the large number of refugees from Syria, the deficit will likely increase to more then 50 MCM per year by 2035 The Governorate’s exclusive resource is groundwater, abstracted by the extensive Al Arab and Kufr Asad well fields. This study presents the first three-dimensional transient regional groundwater flow model of the entire Wadi al Arab to answer important questions regarding the dynamic quality and availability of water within the catchment. Emphasis is given to the calculation and validation of the dynamic groundwater recharge, derived from a multi-proxy approach, including (1) a hydrological model covering a 30-years dataset, (2) groundwater level measurements and (3) information about springs. The model enables evaluation of the impact of abstraction on the flow regime and the groundwater budget of the resource. Sensitivity analyses of controlling parameters indicate that intense abstraction in the southern part of the Wadi al Arab system can result in critical water-level drops of 10 m at a distance of 16 km from the production wells. Moreover, modelling results suggest that observed head fluctuations are strongly controlled by anthropogenic abstraction rather than variable recharge rates due to climate changes.