Correlations and sequence stratigraphic model for Messinian carbonate platforms of the western and central Mediterranean

Distance correlations of Late Tortonian–Messinian littoral carbonate complexes are proposed from the study of eight platforms in the western and central Mediterranean. Correlations are based on the identification of two major biological sedimentary cycles and of two index surfaces. Surface A is a maximum flooding surface during cycle 1 at around 6.7 Ma. Surface B is a regional marine planation surface at around 5.95 Ma, at the base of cycle 2 (Terminal Carbonate Complex). A general sedimentary model is proposed for the 7–5.6-Ma time-span. The boundary between cycles 1 and 2 is coincident with the onset of the Messinian Salinity Crisis, and appears to be related to major environmental–paleo-oceanographic changes in the Mediterranean, rather than to a major sea-level drop or to climatic change.     

Screening and ranking of sedimentary basins for sequestration of CO<Subscript>2</Subscript> in geological media in response to climate change

Sedimentary basins are suitable to different degrees for CO ₂ geological sequestration as a result of various intrinsic and extrinsic characteristics, of which the geothermal regime is one of the most important. Warm basins are less favorable for CO ₂ sequestration than cold basins because of reduced capacity in terms of CO ₂ mass, and because of higher CO ₂ buoyancy, which drives the upward CO ₂ migration. A set of 15 criteria, with several classes each, has been developed for the assessment and ranking of sedimentary basins in terms of their suitability for CO ₂ sequestration. Using a parametric normalization procedure, a basin's individual scores are summed to a total score using weights that express the relative importance of different criteria. The total score is ranked to determine the most suitable basin or region thereof for the geological sequestration of CO ₂. The method is extremely flexible in that it allows changes in the functions that express the importance of various classes for any given criterion, and in the weights that express the relative importance of various criteria. Examples of application are given for Canada's case and for the Alberta basin in Canada.     

Couplex Benchmark Computations Obtained with the Software Toolbox UG

This paper describes the numerical results for the COUPLEX benchmark obtained with the simulation software UG using vertex centered finite volume and higher order discontinuous Galerkin schemes. Multigrid solvers on unstructured grids, local mesh refinement and parallel computation are employed to yield very accurate solutions. Since the full range of results required in the benchmarks is too large to be displayed in this paper we focus on the comparison of discretization schemes, assessment of numerical errors and the presentation of parallel computations.     

Reef development on a deepening platform: two Early Cretaceous coralgal patch reefs (Catí, Llàcova Formation, eastern Spain) compared

Two coralgal patch reefs of the Hauterivian Llàcova Formation (Maestrat Basin, eastern Spain), exposed at two consecutive stratigraphic levels within a single section, have been studied to document taxonomic implications of a changing environment. These two reefal palaeocommunities differ substantially in coral taxonomic composition, microbialite formation pattern and in abundance and composition of encrusters and bioeroders. Of a total of 14 coral species, just one (Stylina parvistella) occurs in both reefs, yet is abundant in the (lower) reef A and rare, occurring near the reef base, in the reef B assemblage. Reef A is dominated by a phototrophic fauna and coral species with small corallites and imperforate septa (a stylinid-thamnasteriid-heterocoeniid-actinastreid association), along with an encruster association dominated by Bacinella and Lithocodium. Reef B is characterised by a balanced phototrophic-heterotrophic fauna that gradually passes into a heterotrophic-dominated assemblage. During this latest growth stage, microsolenid corals dominated the assemblage. The encruster fauna is characterised by sponges, polychaetes and bryozoans. Moderate deepening during a transgressive systems tract (TST) depositional sequence and elevated nutrient supply are interpreted to represent the driving environmental parameters that caused faunal compositions to differ between these two reefal palaeocommunities. Nine coral taxa, previously known only from younger (Barremian–Cenomanian) strata, have been identified, namely Dimorphocoenia? rudis, Eocomoseris raueni, Eocomoseris sp., Holocoenia jaccardi, Latusastrea irregularis, Mesomorpha sp., Microsolena kugleri, Polyphylloseris mammillata and Polyphylloseris sp. This observation emphasises the importance of the Hauterivian Stage as a period of evolutionary transition in Late Jurassic–Cretaceous coral faunas.     

Anaerobic ammonium oxidation by nitrite (anammox): Implications for N2 production in coastal marine sediments

The respiratory reduction of nitrate (denitrification) is acknowledged as the most important process that converts biologically available nitrogen to gaseous dinitrogen (N₂) in marine ecosystems. Recent findings, however, indicate that anaerobic ammonium oxidation by nitrite (anammox) may be an important pathway for N₂ formation and N removal in coastal marine sediments and in anoxic water columns of the oceans. In the present study, we explored this novel mechanism during N mineralization by ¹⁵N amendments (single and coupled additions of ¹⁵NH₄⁺, ¹⁴NO₃⁻ and ¹⁵NO₃⁻) to surface sediments with a wide range of characteristics and overall reactivity. Patterns of ^29/30N₂ production in the pore water during closed sediment incubations demonstrated anammox at all 7 of the investigated sites. Stoichiometric calculations revealed that 4% to 79% of total N₂ production was due to this novel route. The relative importance of anammox for N₂ release was inversely correlated with remineralized solute production, benthic O₂ consumption, and surface sediment Chl a. The observed correlations indicate competition between reductants for pore water nitrite during early diagenesis and that additional factors (e.g. availability of Mn-oxides), superimposed on overall patterns of diagenetic activity, are important for determining absolute and relative rates of anammox in coastal marine sediments.     

Scaled amplification equation: A key to the folding history of buckled viscous single-layers

The presented equation describes amplitude growth during viscous single-layer folding (buckling) up to high amplitudes. The equation relates the dimensionless fold amplitude (i.e. ratio of amplitude to wavelength) to the stretch (ratio of initial wavelength to instantaneous wavelength) for given values of the viscosity contrast between layer and surrounding material and the initial ratio of amplitude to wavelength. The amplification equation is suitably scaled so that all amplitude versus stretch curves for different values of viscosity contrasts and initial amplitudes fall onto essentially a single curve. The scaled amplification equation allows for representing fold amplification of viscous single-layers by a singular curve. The scaling parameter is the crossover strain, which is an estimate for the amount of strain that is accumulated during the initial stages of folding where the amplitude grows exponentially with strain. The singular curve allows quantifying the universal boundaries between the three folding stages, namely nucleation, amplification and kinematic growth. The scaled amplification equation is verified by numerical (finite element method) simulations of folding of single layers with initial random perturbations of the layer interfaces. The amplification equation describes the amplification of single folds within fold trains successfully, although the folds are neither regular nor periodic and vary considerably in shape. The easily measurable parameters, vertical and horizontal hinge distance, are shown to be good approximations for the analytical parameters amplitude and wavelength, respectively.     

Soil and groundwater pollution of an urban catchment by trace metals: case study of the Addis Ababa region, central Ethiopia

Analysis of the total heavy metal (Cr, Cd, Pb, As, Cu, Ni, Zn, Co) concentration was performed on 33 soil samples taken from different profiles and soil types in a highly urbanized and industrial sector of Addis Ababa, central Ethiopia. They were analyzed using aqua regia extraction coupled with a four-stage sequential extraction (SE) procedure. The objectives of the analysis were to investigate the degree of soil heavy metal contamination, its binding forms, mobility and the implications for the groundwater resource. The results show a relatively high content of the analyzed trace metals in the soil attributed to anthropogenic and geogenic sources. Although most of the trace metals are found in the upper few centimeters of the residual soils, because of churning processes within the black cotton soils, vertical distribution of the trace metals is complex. According to the heavy metal SE analysis, the major heavy metal contribution is from the residual followed by the hydroxide phases. Groundwater heavy metal contamination is present with more than 90 and 50% of the analyzed groundwater samples exceeding WHO guidelines for Cr and Cd, respectively. Since the degree of soil heavy metal contamination has apparently not surpassed the soil’s buffering capacity, it appears that the transport path of these toxic metals to the groundwater is through fractures, joints, and related preferential flow paths.     

Remote Sensing Methods to Investigate Boundary-layer Structures relevant to Air Pollution in Cities

Simultaneous surface-based remote sensing with optical (Ceilometer) and acoustic (Sodar) methods allows the diurnal variation of the structure of the atmospheric boundary layer to be deduced with high temporal resolution. Primarily the convective boundary layer, the nocturnal stable surface layer, and the residual layer can be identified from the measured vertical profiles of aerosol concentration and thermal fluctuations. The ability of the two remote sensing techniques is shown in different examples from two different locations and two seasons. The impact on urban air quality assessment is addressed.