Determination of trace and rare-earth elements in Chinese soil and clay reference materials by ICP-MS

Inductively coupled plasma mass spectrometry(ICP-MS) has become a powerful tool for providing reliable analytical results in many laboratories around the word. In this study, the mixture of HF and HNO3 acids in high-temperature and high-pressure closed-vessel digestion technique were used to decompose some Chinese reference materials, and thirty seven elements were determined by ICP-MS. Most of the results for Chinese soil reference materials were found to be in reasonable agreement with the reference values, except Cs, Ta, Li, Ge, Zn, Nd, Tb and Ta whose values need to be revised. Their precisions were typically lower than 5% RSD. However, the Precisions of Chinese clay reference materials, especially for GBW03102 and GBW03102a, were significantly different with reference values, probably reflecting the existence of a coarser-grained fraction(70 μm) in samples, and the formation of fluorides in Al-rich samples during sample decomposition by using the mixture of HF and HNO3 acids. Moreover, thirty-seven trace elements covering the mass range from Li to U in four Chinese clay reference materials were firstly provided with good precision and accuracy in this study.     

Thermal simulation of basic volcanic fluid influence on different source rocks

Based on thermal simulation experiment, interactions between volcanic fluids and source rocks were studied. Gas generations in the dry system and fluid system under different temperatures were analyzed. The results showed that the various types of source rocks are similar in composition, containing gaseous C1-C5 hydrocarbons, H2 and CO2 whose gas yields increase with increasing temperature. The gas yield of source rocks of type I is the high- est, followed by type II, and that of source rocks of type III is the lowest, indicating that the yield of hydrocarbon gases is related to their hydrocarbon generating potential. Although the generating potential of type III is the lowest, it can still be regarded as a useful gas source when it is buried deeply enough. The basic volcanic fluid restrains the generation of gaseous hydrocarbons in different types of source rocks, but promotes the generation of inorganic gases.     

Early Permian–Late Triassic Magmatism in the Tuotuohe Region of the Qinghai–Tibet Plateau: Constraints on the Tectonic evolution of the Western Segment of the Jinshajiang Suture

In this paper we present new zircon U–Pb ages, whole-rock major and trace element analyses, and zircon Hf isotopic data for magmatic rocks in the Tuotuohe region of the western segment of the Jinshajiang suture. Our aim is to constrain the Early Permian–Late Triassic tectonic evolution of the region. Zircons from the magmatic rocks of the Tuotuohe region are euhedral–subhedral in shape and display fine-scale oscillatory zoning as well as high Th/U ratios(0.4–4.6), indicating a magmatic origin. The zircon U–Pb ages obtained using LA–ICP–MS are 281 ± 1 Ma, 258 ± 1 Ma, 244 ± 1 Ma, and 216 ± 1 Ma, which indicate magmatism in the Early Permian–Late Triassic. A diorite from Bashihubei(BSHN) has SiO2 = 57.18–59.97 wt%, Al2O3 = 15.70–16.53 wt%, and total alkalis(Na2O + K2O) = 4.46–6.34 wt%, typical of calc-alkaline and metaluminous series. A gabbro from Bashibadaoban(BSBDB) belongs to the alkaline series, and is poor in SiO2(45.46–54.03 wt%) but rich in Al2O3(16.19–17.39 wt%) and total alkalis(Na2O + K2O = 5.48–6.26 wt%). The BSHN diorite and the BSBDB gabbro both display an enrichment of LREEs and LILEs and depletion of HFSEs, and they have no obvious Eu anomaly; they have relatively low MgO contents(2.54–4.93 wt%), Mg# values of 43 to 52, and low Cr and Ni contents(8.07–33.6 ppm and 4.41–14.2 ppm, respectively), indicating they differentiated from primitive mantle magmas. They have low Nb/U, Ta/U, and Ce/Pb ratios(1.3–9.6, 0.2–0.8, and 0.1–18.1, respectively), and their initial Hf isotopic ratios range from +9.6 to +16.9(BSHN diorite) and +6.5 to +12.6(BSBDB gabbro), suggesting their primary magmas were derived mainly from the partial melting of a mantle wedge that had been metasomatized by subduction fluids. Taking all the new data together, we conclude that the western and eastern segment of the Jinshajiang suture regions underwent identical processes of evolution in the Early Permian–Late Triassic: oceanic crust subduction before the Early Permian, continental collision during the Early–Middle Triassic, and post-collisional extension from the Late Triassic.     

The Metastable Phase Equilibria of the MeX-MgCl_2-H_2O Systems

正1 Introduction The Pingluoba brine,which characterized as high concentration with sodium,potassium,boron,lithium,and rubidium,possess great development value.The main composition of the brine can be summarized to the     

Disaster Risk Science Development and Disaster Risk Reduction Using Science and Technology

Based on a series of international conferences for establishing HFA2 framework, this paper analyzed key issues of frontier of disaster risk science, integrated disaster prevention and mitigation strategies and integrated disaster risk governance. The future direction of disaster risk science was comprehensively discussed according to the widely discussed Post 2015 Hyogo Framework for Action (HFA2). It was proposed to deepen the cognition of the complexity of disaster system in terms of recognizing the complexity of disaster system from the interaction among various elements of the system, recognizing the complexity of climate change risk from the regional characteristics and formation mechanism of the global climate change and recognizing the complexity of the catastrophe risk from the regional development levels and patterns. Furthermore, it was suggested to make integrated disaster risk reduction strategies and countermeasures from the perspective of the complexity of the disaster system, including the establishment of regional integrated disaster risk governance framework to face climate change, the establishment of integrated disaster risk governance system in multi-spatial scale, the establishment of disaster risk governance financial system integrating the insurance, bonds and lottery, the establishment of consilience mode in integrated risk governance considering multi-stakeholder and the establishment of modeling and simulation platform integrated disaster risk information services and disaster risk reduction strategies. Finally, it was pointed out that the assessment of disaster risk levels for different regions in multi spatial scale can provide robust scientific support for integrated disaster risk governance of the world and regions, industries and enterprises so as to improve response to global change and guarantee a global and regional sustainable development.     

中国植物地理学研究进展与展望

中国植物地理学从20世纪20年代初创到当前繁荣经历了100年的发展,近30年来测序技术和生物信息技术的进步,促进了分类、进化和生态等学科交叉融合,中国植物地理学在诸多方面取得了突破性进展,主要包括：① 植物类群和区系在中国整体上按纬度、经度和海拔呈现出规律性;物种丰富度、系统发生多样性和特有性热点集中分布在南部山地,少数分布在北方山地和干旱地区。② 关于大尺度植物多样性格局及形成机制,多数热带起源科的物种多样性格局受冬季低温的限制,而多数温带起源科的物种多样性格局由末次冰期以来的气候变化主导;中国山地植物和群落具有显著的垂直地带性和空间分布异质性,热量因子是中国高山植物区系地理分异的首要气候因子。③ 中国大多数现生被子植物属（约66%）是在中新世及其以后分化;500 mm年等降水线是中国植物区系年龄和植被分区最重要的分界线;中国植物区系、区系中的特征或关键类群的起源和多样化与青藏高原抬升和亚洲季风加强密切相关。未来,时间和空间的结合仍是植物地理学研究的主旋律,类群、群落和区系分化时间的估算及物种分布数据的分辨率是研究者关注的焦点,植物大数据的持续积累和完善将为学科发展提供强大动力和广阔前景。     

基于PLSR的典型沼泽湿地植物叶片性状与光谱模型构建——以三江国家级自然保护区为例

通过植物光学特性测量叶片性状是一种非破坏性的、长期的湿地动态监测方法。选择三江国家级自然保护区多种典型湿地植物为研究对象,探究植物性状与叶片光谱之间的联系。研究表明：叶片氮含量与光谱的模型构建效果最好,模型R²为0.61,均方根误差（RMSE）为2.3862;叶片含水量、叶片磷、可溶性糖、纤维素和木质素含量之和的模型一般,R²在0.38~0.55范围内,RMSE在0.0004~10.7019范围内;淀粉含量拟合效果较差, R²为0.29,RMSE为0.0106。光谱预测重要性的结果表明,可见光与近红外边缘范围内的光谱信息对于叶片含水量、叶片氮含量、叶片磷含量、单位叶面积质量、纤维素和木质素之和、可溶性糖和淀粉的预测具有最高的重要性。     

广西国土空间格局演变特征与形成机理

国土空间格局演化与形成机理是人地系统交互关系研究的科学问题和国土空间规划的关键前提。采用地学图谱、标准差椭圆和空间自相关方法,分析2000—2018年广西国土空间格局演变特征,并运用地理探测器揭示其形成机理。结果表明：① 广西城镇空间加速挤占农业、生态空间形成了“一增双减”的面积变化特征,国土空间动态变化速度加快;② 广西国土空间相互转化频繁,转移轨迹多样性特征明显,农业空间与生态空间加速互换以及生态空间内部结构加快重组;③ 城镇空间与农业空间互竞主导了广西国土空间的迁移路径,城镇、农业空间存在“南高北低”和生态空间存在“北高南低”的集聚特征;④ 广西国土空间格局演变受自然地理与社会经济因素的共同作用影响,自然环境条件的限制作用减弱,社会经济发展水平驱动力增强,政策调控力度驱动作用深远。下一步可通过国土空间规划、调整产业布局和引导生产生活方式优化国土空间格局。     

中国城市流动人口心理融入的地区差异与影响因素

基于2017年流动人口动态监测调查数据,分析了中国城市流动人口心理融入的区域差异和影响因素。结果表明：① 流动人口心理融入处于较高水平;② 流动人口心理融入区域差异显著。东南沿海及少数西部城市心理融入低于全国平均水平,东北、山东和川渝等地区心理融入高于全国平均水平;③ 流动人口心理融入存在空间集聚效应。除川渝地区外,热点区集中于北方地区,冷点区集中于东南地区。④ 拥有房产、雇主身份和较高受教育水平加快流动人口的心理融入;工资收入的增加不利于心理融入,这与相对剥夺感有关;参与“新农合”对流动人口心理融入具有约束效应;暂住证/居住证及基本公共服务均等化是实现心理融入的重要途径。城市经济快速发展利于流动人口心理融入。跨省流动存在抑制作用,经济发展水平、家庭规模和本地居留时间的作用不显著。     

旅游驱动型传统村落“三生”空间功能更新的特征、模式与逻辑——以湖南省张谷英村为例

以湖南省传统村落张谷英村为例,利用GIS技术构造土地利用转移矩阵,探讨旅游驱动型传统村落“三生”空间功能更新特征和逻辑模式。结果表明：1）张谷英村“三生”功能更新主要表现出生活功能产居一体化、生产功能旅游化、生态功能景观化、旅游功能多样化的旅游适应性特征及圈层分化和阶段有序的时空分异特征。2）张谷英村通过生活空间的人文景观开发与民俗文脉挖掘、生产空间的多元高质旅游服务模块构建、生态空间的生态环境保育与自然景观修复,实现传统物质空间的旅游功能更新和功能融合发展。3）旅游驱动型乡村社会通过供需关系构建、示范效应延伸、主客交往反馈,扩展功能更新范围、加深功能更新程度、提升多元功能质量。“三生”功能的更新存在一种相互促进、相互演化的共生耦合关系,其旅游化过程体现了空间结构有序变迁和空间属性质量提升的协同演化进程,以多功能交互、多层次联动的综合路径推助乡村振兴。