Quantitative Separation of As(III) and As(V) from a Synthetic Water Solution Using Ion Exchange Columns in the Presence of Fe and Mn Ions

The quantitative separation of As(III) from a water sample containing As(III) and As(V) in the presence of Fe and Mn in an ion exchange resin (AG1 X8) column for the speciation of arsenic is described. Individual and combined effects of Fe and Mn on the separation of As(III) from the solution have been studied separately. In absence of Fe and Mn, the ratio between the As(T) concentration in the eluent and the As(III) concentration in the original sample has been found to be 0.9717 under optimum process conditions. The presence of Fe(II) in the water sample increased the As(T) concentration in the eluent whereas Mn(II) decreased it. Combined effects of Fe and Mn on the percentage increment in the eluent arsenic concentration have been expressed by additive and interactive models. The interactive model has been developed by a statistical software with a 95 % confidence level. In most of the cases the error on the determination of the As(III) concentration had a minimum when using the interactive model.     

Platinum group element (PGE) geochemistry to understand the chemical evolution of the Earth’s mantle

Platinum group elements (PGE: Os, Ir, Ru, Rh, Pt, Pd) are important geochemical and cosmochemical tracers. Depending on physical and chemical behaviour the PGEs are divided into two subgroups: IPGE (Ir, Os, Ru) and PPGE (Pd, Pt, Rh). Platinum group elements show strong siderophile and chalcophile affinity. Base metal sulfides control the PGE budget of the Earth’s mantle. Mantle xenoliths contain two types of sulfide populations: (1) enclosed within silicate minerals, and (2) interstitial to the silicate minerals. In terms of PGE characters the included variety shows IPGE enriched patterns — similar to the melt-depleted mantle harzburgite, whereas the interstitial variety shows PPGE enriched patterns — resembling the fractionated PGE patterns of the basalt. These PGE characters of the mantle sulfides have been interpreted to be representative of multi-stages melting process of the mantle that helped to shape the chemical evolution of the Earth.     

Assessing the oscillation of channel geometry and meander migration cardinality of Bhagirathi River,West Bengal,India

Journal of Geographical Sciences - Lateral migration of the Bhagirathi River temporally creates unavoidable geomorphic hazards in West Bengal, India. The Bhagirathi River flows SW for ~67.30 km...     

Effects of vertical irregularity and thickness of unreinforced masonry infill on the robustness of RC framed buildings

Presence of irregularities in reinforced concrete (RC) buildings increases seismic vulnerability. During severe seismic shaking, such buildings may suffer disproportionate damage or even collapse that can be minimized by increasing robustness. Robustness is a desirable property of structural systems that can mitigate susceptible buildings to disproportionate collapse. In this paper, the effects of vertical irregularity and thickness of unreinforced masonry infill on the robustness of a six‐story three‐bay RC frame are quantified. Nonlinear static analysis of the frame is performed, and parametric study is undertaken by considering two parameters: absence of masonry infill at different floors (i.e., vertical irregularities) and infill thickness. Robustness has been quantified in terms of stiffness, base shear, ductility, and energy dissipation capacity of the frame. It was observed that the infill thickness and vertical irregularity have significant influence on the response of RC frame. The response surface method is used to develop a predictive equation for robustness as a function of the two parameters. The predictive equation is validated further using 12 randomly selected computer simulations. Copyright © 2013 John Wiley & Sons, Ltd.     

Water Intake and Utilization in Mithun (Bos frontalis):Effect of Environmental Temperature, Rearing System and Concentrate Feed Supplement

Seasonal and sexual variations as well as the effect of dry feed supplement on total drinking water intake and its utilization were observed in mithun (Bos frontalis)-a semi-wild animal found in North Eastern Hill Region (NEHR) of India. In a completely randomized design, twelve adult mithuns (B. frontalis) as per their sex and body weight were assigned in two different rearing systems (free grazing and free grazing with dry concentrate feed supplementation), and ten growing male mithuns as per their body weight assigned in two different levels of dry concentrate feed supplementation (1.0 kg and 2.0 kg dry concentrate feeds on green forage based diet) and in two different seasons (summer and winter). It was observed that the environmental temperature had a significant effect on drinking water intake by mithuns. Drinking water consumption (per unit of body weight) was significantly (P < 0.05) higher in summer than in winter. Supplementation of concentrate feed on free grazing animals resulted in increase in water consumption. Total water consumption (drinking as well as performed water) was found to be 15.18 litres per 100 kg body weight by growing mithun. Feed dry matter and digestible nutrient intakes by growing mithun were observed to be increased with the increase of supplementation of dry concentrate feed. Roughage to concentrate ratio did not affect the nutrient digestibility. Mithun calves drank an average of 4.30 litres water for each kg of dry matter intake. Metabolic water was significantly (P<0.01) increased with the increase of supplementation of concentrate feed whereas water turn over, which depends upon the body weight of the animals, did not differ significantly on offering of lower or higher level of dry feed. Faecal water loss of growing mithun was decreased with the increase in intake of concentrate feed and was estimated to be 33～46% of total water intake. Excretion of water through faeces of mithun was about 3.8% of body weight. It could, therefore, be inferred that water intake by mithun varied with seasons, rearing systems and dry feed consumption. As far as the water nutrition is concerned, it is needed to give an attention while feeding mithun in summer with dry feed supplementation under semi-intensive system of rearing.     

Gravitational wave emission from a companion black hole in the presence of an accretion disc around a super-massive Kerr black hole

Gravitational wave signal characteristics from a binary black hole system in which the companion moves through the accretion disc of the primary are studied. We chose the primary to be a super-massive  ( M = 10⁸ M_⊙)  Kerr black hole and the companion to be a massive black hole  ( M = 10⁵ M_⊙)  to clearly demonstrate the effects. We show that the drag exerted on the companion by the disc is sufficient to reduce the coalescence time of the binary. The drag is primarily due to the fact that the accretion disc on a black hole deviates from a Keplerian disc and becomes sub-Keplerian due to inner boundary condition on the black hole horizon. We consider two types of accretion rates on to the companion. The companion is deeply immersed inside the disc and it can accrete at the Bondi rate which depends on the instantaneous density of the disc. However, an accretion disc can also form around the smaller black hole and it can accrete at its Eddington rate. Thus, this case is also studied and the results are compared. We find that the effect of the disc will be significant in reducing the coalescence time and one needs to incorporate this while interpreting gravitational wave signals emitted from such a binary system.     

Investigation of fluoride contamination and its mobility in groundwater of Simlapal block of Bankura district,West Bengal,India

The occurrence of dental/skeletal fluorosis among the people in the study area provided the motivation to assess the distribution, severity and impact of fluoride contamination in groundwater of Bankura district at Simlapal block, West Bengal, India. To meet the desired objective, groundwater samples were collected from different locations of Laxmisagar, Machatora and Kusumkanali regions of Simlapal block at different depths of tube wells in both pre- and post-monsoon seasons. Geochemical results reveal that the groundwaters are mostly moderate- to hard-water type. Of total groundwater samples, 37% are situated mainly in relatively higher elevated region containing fluoride above 1.5 mg/L, indicating that host aquifers are severely affected by fluoride contamination. Machatora region is highly affected by fluoride contamination with maximum elevated concentration of 12.2 mg/L. Several symptoms of fluorosis among the different age-groups of people in Laxmisagar and Machatora areas are indicating consumption of fluoridated water for prolonged period. The groundwater samples were mainly Na–Ca–HCO₃ type and rock dominance indicating the dissolution of minerals taking place. Ion exchange between OH^? ion and F^? ion present in fluoride-bearing mineral is the most dominant mechanism of fluoride leaching. High concentration of Na⁺ and HCO₃ ^? increases the alkalinity of the water, providing a favorable condition for fluoride to leach into groundwater from its host rocks and minerals.     

Modeling of the Removal of Arsenic Species from Simulated Groundwater Containing As,Fe, and Mn: A Neural Network Based Approach

The present paper deals with the modeling of the removal of total arsenic As(T), trivalent arsenic As(III), and pentavalent arsenic As(V) from synthetic solutions containing total arsenic (0.167–2.0 mg/L), Fe (0.9–2.7 mg/L), and Mn (0.2–0.6 mg/L) in a batch reactor using Fe impregnated granular activated charcoal (GAC‐Fe). Mass ratio of As(III) and As(V) in the solution was 1:1. Multi‐layer neural network (MLNN) has been used and full factorial design technique has been applied for the selection of input data set. The developed models are able to predict the adsorption of arsenic species with an error limit of ?0.3 to +1.7%. Combination of MLNN with design of experiment has been able to generalize the MLNN with less number of experimental points.     

Evaluating the Performance of Multi-Class and Single-Class Classification Approaches for Mountain Agriculture Extraction Using Time-Series NDVI

Supervised multi-class classification (MCC) approach is widely being used for regional-level land use–land cover (LULC) mapping and monitoring. However, it becomes inefficient if the end user wants to map only one particular class. Therefore, an improved single-class classification (SCC) approach is required for quick and reliable map production purpose. In this regard, the current study attempts to evaluate the performance of MCC and SCC approaches for extracting mountain agriculture area using time-series normalized differential vegetation index (NDVI). At first, samples of eight LULC classes were acquired using Google Earth image, and corresponding temporal signatures (TS) were extracted from time-series NDVI to perform classification using minimum distance to mean (MDM) and spectral angle mapper (i.e., multi-class SAM—MCSAM) under MCC approach. Secondly, under SCC approach, the TS of three agriculture classes (i.e., agriculture, mixed agriculture and plantation) were utilized as a reference to extract agriculture extent using Euclidean distance (ED) and SAM (i.e., single-class SAM—SCSAM) algorithms. The area of all four maps (i.e., MDM—19.77% of total geographical area (TGA), MCSAM—21.07% of TGA, ED—15.23% of TGA, SCSAM—13.85% of TGA) was compared with reference agriculture area (14.54% of TGA) of global land cover product, and SCC-based maps were found to have close agreement. Also, the class-wise detection accuracy was evaluated using random sample point-based error matrix which reveals the better performance of ED-based map than rest three maps in terms of overall accuracy and kappa coefficient.     

Natural zeolites enhance groundwater quality: evidences from Deccan basalts in India

The zeolite minerals characterized with hydrated aluminosilicates, negative ionic charge and 3D framework structure are well known for purifying the groundwater occurring in basaltic aquifer systems. However, the filtering mechanism at in situ field conditions is a complex process, which is rarely studied, and hence, it needs to be demonstrated. This paper explores the mechanism of hydrochemical processes and evolution of natural zeolites associated with basaltic rock to enhance groundwater quality. We present the hydrochemical findings and evolution processes derived from 46 groundwater samples (N_t = 46) belong to zeolitic (N_z = 25) and non-zeolitic (N_nz = 21) zones of a micro-watershed (4.4 km²) beset over basaltic terrain, Deccan Volcanic Province (DVP), India. The groundwater samples collected for one hydrological cycle (pre- and post-monsoons) are examined for major ion chemistry to determine the aqueous solution mechanism and ion-exchange process occurred in zeolitic and non-zeolitic zones. Further, the hydrochemical parameters are appraised by means of dominancy of ions, rock–water interactions, silicate weathering, chloro-alkaline indices, cation-exchange bivariate plots and the mechanism controlling groundwater chemistry. The results show that: 1) the purifying efficiency of zeolites for total ionic strength is observed as 63.85 and 68.58% during pre- and post-monsoons, respectively, 2) the significant reduction (36.51%) in total hardness attributed to the positive trend of chloro-alkaline indices depicting the ion-exchange phenomenon between Na⁺ and K⁺ (alkalies) and Ca²⁺ and Mg²⁺ (alkali-earth) elements in the zeolitic zone, 3) Gibbs plot shows the rock–water interaction as the predominant mechanism controlling groundwater chemistry in the zeolitic zone, and 4) the groundwater quality parameters from zeolitic zone are found within the permissible limit of WHO drinking water standards.