Characterisation and quality assessment of groundwater with a special emphasis on irrigation utility: Thirumanimuttar sub-basin, Tamil Nadu, India

Thirumanimuttar sub-basin is of particular importance in the study of groundwater quality due to the release of effluents from industries, agricultural, sewage and urban runoff, brining considerable change in water quality. An investigation was carried out by collecting a total of 194 groundwater samples for two seasons to decipher hydrogeochemistry and groundwater quality for determining its suitability for agricultural purposes. The water is neutral to alkaline in nature with pH ranging from 6.78 to 9.22 with an average of 7.37. Higher electrical conductivity (EC) was noted in NW and mid-downstream parts of the study area. Higher NO ₃ ^? was observed during post-monsoon (POM) due to the action of leaching and anthropogenic process. The piper plot reveals the dominance of Na⁺?CCl^? and Na⁺?CHCO ₃ ^? , mixed Ca²⁺?CNa⁺?CHCO ₃ ^? , mixed Ca²⁺?CMg²⁺?CHCO ₃ ^? and Ca²⁺?CSO ₄ ^? types of hydrogeochemical facies. Higher total hardness in the groundwater is due to the effect of dyeing and bleaching industries discharging effluents affects the quality of water. Residual Sodium Carbonate value indicates 56% of the samples are not suitable for irrigation purposes in both seasons. Higher sodium percentage is noted during PRM indicating the dominance of ion exchange and weathering. Higher sodium adsorption ratio was observed during POM indicating the effect of leaching and dissolution of salts into the aquifer matrix. USSL plot indicates 15% of samples record high salinity to medium sodicity. The Permeability Index indicates water is moderate to good for irrigation purposes. In general, groundwater in the study area is influenced by both natural and anthropogenic activities.     

Zircon U‐Pb/Lu‐Hf and monazite chemical dating of the Tirodi biotite gneiss: implication for latest Palaeoproterozoic to Early Mesoproterozoic orogenesis in the Central Indian Tectonic Zone

In this investigation, we reconstruct the latest Palaeoproterozoic to Early Mesoproterozoic orogenic events along the southern margin of the Central Indian Tectonic Zone (CITZ), using sensitive high resolution ion microprobe (SHRIMP) U‐Pb zircon dating and Lu‐Hf isotope analyses of zircon and Th‐U‐Pb chemical dating of monazite from samples of the Tirodi biotite gneiss (TBG) unit in the Sausar Mobile Belt (SMB), the latter constituting the southernmost litho‐tectonic component of the CITZ. U‐Pb zircon dating of one migmatitic gneiss sample from the type locality of the Tirodi biotite gneiss in the northern domain of the SMB has yielded an age of 1618 ± 8 Ma, which is considered to be the time of magmatic crystallization of its protolith. Combined U‐Pb zircon and monazite chemical dating of two granite gneiss samples from the southern domain of the SMB broadly constrain magmatic crystallization between 1603 ± 23 Ma and 1584 ± 17 Ma and an overprinting metamorphic recrystallization event at 1572 ± 7 Ma. Monazites from the granite gneiss samples also record a terminal metamorphic event at 1415 ± 23 Ma. Lu‐Hf isotopic analyses of zircons reveal fundamentally different source rock reservoirs for the protoliths of these magmatic rocks across the SMB. While the type TBG from the northern domain was derived from an Early Palaeoproterozoic source T(Hf) from 2093 to 2523 Ma, with a mean value at 2379 Ma) of essentially juvenile material with minor crustal components (εHf(t) from −3.3 to + 3.7), the granite from the southern domain had a mature crustal source (εHf(t) from −12.5 to −21.9) of Palaeoarchaean age T(Hf) from 3051 to 3630 Ma, with a mean value at 3218 Ma). When integrated with metamorphic information previously obtained from the 1.6 Ga ultra‐high temperature granulite facies metamorphic event in the SMB, the discrete magmatic and metamorphic events between 1.62/1.60 Ga and 1.42 Ga can be correlated with the formation of an Early Mesoproterozoic accretionary orogen in the CITZ. Copyright © 2011 John Wiley & Sons, Ltd.     

Assessment of seawater mixing in a coastal aquifer by high resolution electrical resistivity tomography

Seawater intrusion is a major problem in urbanized coastal regions of India which is due to over exploitation of groundwater for various purposes. This study was carried out with the objective of assessing the zone of mixing between seawater and groundwater in the coastal aquifer in south of Chennai, Tamil Nadu, India using high resolution electrical resistivity tomography. High resolution electrical resistivity tomography was carried out in five profiles perpendicular to the sea using IRIS make SYSCAL Pro-96 system with 2.5 m or 5 m inter-electrode separation. The maximum length of the profile was 170 m which resulted in a depth of investigation of 28.7 m. The apparent resistivity measured in this area varies from 0.3 ohm-m to 30,000 ohm-m. The apparent resistivity of saturated zone decreases towards the sea, indicating the influence of seawater. This was also confirmed by measuring the electrical conductivity of groundwater, which gradually increases from 156 μS/cm to 3430 μS/cm towards the sea. Further, the concentration profiles of electrical conductivity, sodium, chloride and chloride / bicarbonate ratio are compared with the high resolution electrical resistivity tomography profile. The distance of influence of seawater is comparatively high in northern part than in southern part of the area. The high resolution electrical resistivity tomography was effectively used to determine the effect of seawater mixing with groundwater.     

VV Orionis – improved elements

TheUBV light curves obtained by Duerbeck (1975) andHa (wide) and Ha (narrow) light curves obtained by Chambliss & Davan (1987) of the detached eclipsing binary VV Orionis (VV Ori) were analysed using the Wilson-Devinney method fixing the two parametersT _h (25,000 K) and q(0.4172), resulting in the following absolute elements:A = 13.605 ± 0.03 LR_⊙,R _h = 5.03 ±0.03R _⊙, R_c = 2.43 ±0.02R _⊙,M _bol,h = -5.18 ± 0.11,M _bol,c = -1.54 ± 0.06,m _h =10.81 + 0.42m _⊙ andm _c = 4.51 ± 0.41m _⊙. The de-reddened colours obtained from applying the reddening corrections ofE(B-V) = 0^m.05 andE(U-B) = O ^m .04, and the derived temperatures of the components, gave spectral types ofB 1.5V for the primary and 54-5V with anUV excess of 0 ^m ·3 for the secondary component. A comparison of the logL and logT _e of the components with the observed ZAMS shows the primary component to be a little above and the secondary component to be a little below/or on the ZAMS. A comparison of the properties of the components of VV Ori and a few other detached systems with the normal stars in the logL, logR and logT _e versus logm planes, indicated a need for either a readjustment of the scales of the above parameters or modifications in the theoretical models. From the position of the components on the evolutionary tracks of Pop I composition computed by Schaller et al. (1992) it is noticed that while the primary component of W Ori had slightly evolved along the main-sequence, its secondary is still unevolved. The age of VV Ori is found to be 10 ± 1 million years and it is at a distance of 368 ± 10 pc.     

Characteristics of an open coast tidal flat: Example from Daman,west coast of India

This study highlights lithofacies and biofacies characteristics of the open coast tidal flat near Daman on the eastern flank of Gulf of Khambhat. Sedimentological and biological observation record six facies within the tidal flat area including older beach, beach face, sand flat, mud flat/mixed flat, sand bar and beach rock. Distinct sedimentary structures, foraminiferal assemblage and bioturbation intensity characterize each facies. A wide variety of wave and current generated sedimentary features characterize the sand flat facies. Semiconsolidated sands of older beach running parallel the coastline at a level higher than the present beach face possibly records the latest sea level highstand. The beach rock reflects early cementation of sands in tropical environments. Foraminifera are widely distributed in sand flats, mixed flats and mud flats and grouped into two biofacies — Ammonia-Elphidium-Quinqueloculina biofacies (sand flat and mixed flat) and Trochammina-Miliammina biofacies (mud flats). The beach face and sand bar facies contain forminifera reworked from sand flat and mud/mixed flat. Seasonal variation in depositional style is marked by deposition of fresh mud deposited over large areas of the intertidal flat during monsoon time, most of which is washed away by waves and current actions well before the onset of the next monsoon.     

Methane and carbon dioxide sorption on a set of coals from India

Complete sorption isotherm characteristics of methane and CO₂ were studied on fourteen sub-bituminous to high-volatile bituminous Indian Gondwana coals. The mean vitrinite reflectance values of the coal samples are within the range of 0.64% to 1.30% with varying maceral composition. All isotherms were conducted at 30 °C on dry, powdered coal samples up to a maximum experimental pressure of ~ 7.8 MPa and 5.8 MPa for methane and CO₂, respectively.The nature of the isotherms varied widely within the experimental pressure range with some of the samples remained under-saturated while the others attained saturation. The CO₂ to methane adsorption ratios decreased with the increase in experimental pressure and the overall variation was between 4:1 and 1.5:1 for most of the coals. For both methane and CO₂, the lower-ranked coal samples generally exhibited higher sorption affinity compared to the higher-ranked coals. However, sorption capacity indicates a U-shaped trend with rank. Significant hysteresis was observed between the ad/desorption isotherms for CO₂. However, with methane, hysteresis was either absent or insignificant. It was also observed that the coal maceral compositions had a significant impact on the sorption capacities for both methane and CO₂. Coals with higher vitrinite contents showed higher capacities while internite content indicated a negative impact on the sorption capacity.     

Palynology, palaeoecology and palaeodepositional environment of Eocene lignites and associated sediments from Matanomadh mine, Kutch Basin, western India

Extensive Cenozoic lignite-bearing sediments in the western part of Kutch, western India provide a unique opportunity to study the floral diversity at a crucial time of early Eocene Climatic Optimum (EECO). Rock samples representing a lignite-bearing sequence from the open cast mine at Matanomadh, Gujarat, western India were collected to study the palynofloral composition and to interpret the palaeoclimate and environment of deposition. The sequence mainly composed of lignites, shales and calcareous mudstones yielded rich assemblage consists of pteridophytic spores (7 genera, 10 species), angiosperm pollens (20 genera, 26 species), fungal remains (14 genera, 16 species) and dinoflagellate cysts. The palynofloral assemblage is marked with dominance of angiospermic pollen, particularly those having affinity with the family Arecaceae. Occurrence of fungal remains in high abundance is also noticed. Based on palynomorph contents, the studied sequence is divisible into two palynozones. It is inferred that lower part of the sequences was deposited in a near-shore environment with intermittent marine incursions whereas the depositional regime of upper part was shallow marine. The climate is found to be tropical-subtropical, humid with heavy precipitation during the deposition of Matanomadh lignite-bearing sequence.     

Growth of Plankton (Scenedesmus acutus (Chlorophyceae) and Moina macracopa (Cladocera)) on Domestic Wastewater

The population growth of the freshwater chlorophyte, Scenedesmus acutus and the cladoceran Moina macrocopa cultured in the laboratory and in microcosms of a wastewater treatment plant was studied. S. acutus was cultured in a defined algal medium and mixed with wastewater. On diets of S. acutus cultured using Bold medium or a mixture with wastewater, the peak densities of M. macrocopa were 6–7 ind. mL^?1, while on a diet of algae cultured on wastewater alone the cladoceran density fluctuated around 2 ind. mL^?1. Population growth rates of M. macrocopa, which ranged from 0.3 to 0.4 d^?1, were significantly lower on alga cultured in wastewater alone. The body size structure of M. macrocopa was larger on algae cultured in Bold medium than in wastewater. Peak densities of M. macrocopa were around 700 ind. L^?1 when the organic matter in the containers was supplemented with algae but it reached lower densities (400 ind. L^?1) when cultured on the organic matter in wastewater alone. Our study indicates that the nutrients in the final stages of wastewater treatment can support the growth of both phytoplankton and zooplankton.