Stable carbon and nitrogen isotopic characteristics of PM2.5 and PM10 in Delhi,India

This study presents the chemical composition (carbonaceous and nitrogenous components) of aerosols (PM_2.5 and PM₁₀) along with stable isotopic composition (δ¹³C and δ¹⁵N) collected during winter and the summer months of 2015–16 to explore the possible sources of aerosols in megacity Delhi, India. The mean concentrations (mean?±?standard deviation at 1σ) of PM_2.5 and PM₁₀ were 223?±?69 µg m^?3 and 328?±?65 µg m^?3, respectively during winter season whereas the mean concentrations of PM_2.5 and PM₁₀ were 147?±?22 µg m^?3 and 236?±?61 µg m^?3, respectively during summer season. The mean value of δ¹³C (range: ??26.4 to ??23.4‰) and δ¹⁵N (range: 3.3 to 14.4‰) of PM_2.5 were ??25.3?±?0.5‰ and 8.9?±?2.1‰, respectively during winter season whereas the mean value of δ¹³C (range: ??26.7 to ??25.3‰) and δ¹⁵N (range: 2.8 to 11.5‰) of PM_2.5 were ??26.1?±?0.4‰ and 6.4?±?2.5‰, respectively during the summer season. Comparison of stable C and N isotopic fingerprints of major identical sources suggested that major portion of PM_2.5 and PM₁₀ at Delhi were mainly from fossil fuel combustion (FFC), biomass burning (BB) (C-3 and C-4 type vegitation), secondary aerosols (SAs) and road dust (SD). The correlation analysis of δ¹³C with other C (OC, TC, OC/EC and OC/WSOC) components and δ¹⁵N with other N components (TN, NH₄⁺ and NO₃^?) are also support the source identification of isotopic signatures.

     

The Indian summer monsoon drought of 2002 and its linkage with tropical convective activity over northwest Pacific

The Indian subcontinent witnessed a severe monsoon drought in 2002, which largely resulted from a major rainfall deficiency in the month of July. While moderate El Nino conditions prevailed during this period, the atmospheric convective activity was anomalously enhanced over northwest and north-central Pacific in the 10–20°N latitude belt; and heavy rainfall occurred over this region in association with a series of northward moving tropical cyclones. Similar out-of-phase rainfall variations over the Indian region and the northwest (NW) Pacific have been observed during other instances of El Nino/Southern Oscillation (ENSO). The dynamical linkage corresponding to this out-of-phase rainfall variability is explored in this study by conducting a set of numerical experiments using an atmospheric general circulation model. The results from the model simulations lend credence to the role of the tropical Pacific sea surface temperature anomalies in forcing the out-of-phase precipitation variability over the NW Pacific and the Indian monsoon region. It is seen that the ENSO induced circulation response reveals an anomalous pattern comprising of alternating highs and lows which extend meridionally from the equatorial region into the sub-tropic and mid-latitude regions of west-central Pacific. This meridional pattern is associated with an anomalous cyclonic circulation over NW Pacific, which is found to favor enhanced tropical cyclonic activity and intensified convection over the region. In turn, the intensified convection over NW Pacific induces subsidence and rainfall deficiency over the Indian landmass through anomalous east-west circulation in the 10–20°N latitude belt. Based on the present findings, it is suggested that the convective activity over NW Pacific is an important component in mediating the ENSO-monsoon teleconnection dynamics.     

A verification framework for interannual-to-decadal predictions experiments

Decadal predictions have a high profile in the climate science community and beyond, yet very little is known about their skill. Nor is there any agreed protocol for estimating their skill. This paper proposes a sound and coordinated framework for verification of decadal hindcast experiments. The framework is illustrated for decadal hindcasts tailored to meet the requirements and specifications of CMIP5 (Coupled Model Intercomparison Project phase 5). The chosen metrics address key questions about the information content in initialized decadal hindcasts. These questions are: (1) Do the initial conditions in the hindcasts lead to more accurate predictions of the climate, compared to un-initialized climate change projections? and (2) Is the prediction model’s ensemble spread an appropriate representation of forecast uncertainty on average? The first question is addressed through deterministic metrics that compare the initialized and uninitialized hindcasts. The second question is addressed through a probabilistic metric applied to the initialized hindcasts and comparing different ways to ascribe forecast uncertainty. Verification is advocated at smoothed regional scales that can illuminate broad areas of predictability, as well as at the grid scale, since many users of the decadal prediction experiments who feed the climate data into applications or decision models will use the data at grid scale, or downscale it to even higher resolution. An overall statement on skill of CMIP5 decadal hindcasts is not the aim of this paper. The results presented are only illustrative of the framework, which would enable such studies. However, broad conclusions that are beginning to emerge from the CMIP5 results include (1) Most predictability at the interannual-to-decadal scale, relative to climatological averages, comes from external forcing, particularly for temperature; (2) though moderate, additional skill is added by the initial conditions over what is imparted by external forcing alone; however, the impact of initialization may result in overall worse predictions in some regions than provided by uninitialized climate change projections; (3) limited hindcast records and the dearth of climate-quality observational data impede our ability to quantify expected skill as well as model biases; and (4) as is common to seasonal-to-interannual model predictions, the spread of the ensemble members is not necessarily a good representation of forecast uncertainty. The authors recommend that this framework be adopted to serve as a starting point to compare prediction quality across prediction systems. The framework can provide a baseline against which future improvements can be quantified. The framework also provides guidance on the use of these model predictions, which differ in fundamental ways from the climate change projections that much of the community has become familiar with, including adjustment of mean and conditional biases, and consideration of how to best approach forecast uncertainty.     

Comparative analysis of contributing parameters for rainfall-triggered landslides in the Lesser Himalaya of Nepal

In the Himalaya, people live in widely spread settlements and suffer more from landslides than from any other type of natural disaster. The intense summer monsoons are the main factor in triggering landslides. However, the relations between landslides and slope hydrology have not been a focal topic in Himalayan landslide research. This paper deals with the contributing parameters for the rainfall-triggered landslides which occurred during an extreme monsoon rainfall event on 23 July 2002, in the south-western hills of Kathmandu valley, in the Lesser Himalaya, Nepal. Parameters such as bedrock geology, geomorphology, geotechnical properties of soil, and clay mineralogy are described in this paper. Landslide modeling was performed in SEEP/W and SLOPE/W to understand the relationship of pore water pressure variations in soil layers and to determine the spatial variation of landslide occurrence. Soil characteristics, low angle of internal friction of fines in soil, medium range of soil permeability, presence of clay minerals in soil, bedrock hydrogeology, and human intervention were found to be the main contributing parameters for slope failures in the region.     

Photodegradation of amaranth in aqueous solution catalyzed by immobilized nanoparticles of titanium dioxide

The use of suspensions of nanoparticles of titanium dioxide in photocatalytic degradation of dye solution has disadvantages of inconvenient separation of fine particles for reuse and limited penetration of light for effective degradation. These problems can be minimized by supporting titanium dioxide on various inert supports. The present study involves the preparation of immobilized titanium dioxide films by three different techniques and characterization of the prepared films. The immobilized films of nanocrystals of titanium dioxide were prepared using sol?Cgel technique, polyvinyl alcohol?Cformaldehyde binder and acrylic emulsion. The photocatalytic performance of the prepared films for degradation of amaranth dye has also been evaluated and compared. Combination of photodegradation and adsorption processes induces strong beneficial effects on removal of dyes. Addition of high adsorption capacity activated carbon to photoactive titanium dioxide in photodegradation of dyes improves the efficiency of dye mineralization. The activated carbon has also been immobilized along with titanium dioxide in the present work to examine the dual effect of photodegradation and adsorption in the removal of amaranth. The films formed with the help of polyvinyl alcohol?Cformaldehyde binder showed better dye degradation capabilities.     

Is the interdecadal variation of the summer rainfall over eastern China associated with SST?

The present study examined the major features of the interdecadal variation of the summer rainfall over eastern China (IVRC) and the possible association with sea surface temperature (SST). We noted that the first leading mode of IVRC (accounting for nearly half of the total variance and with maximum loading for the summer rainfall anomalies over South China) may be not forced by SST. On the other hand, the second and third leading modes [accounting for 17.1 and 13.6 % of the total variance and mainly associated with the summer rainfall anomalies over the Yangtze River valley (YRV) and North China, respectively] in some extent are forced by SST anomalies. These observational results are confirmed by atmospheric general circulation model (AGCM) simulations forced by observed SST. By eliminating the internal dynamical process driven rainfall though ensemble mean, the simulations further suggest an overall enhancement of the intensity of IVRC in the corresponding ensemble mean, especially in the YRV and North China regions, but not in South China. That implies the different role of SST in driving IVRC over different regions.     

An analysis of prediction skill of monthly mean climate variability

In this paper, lead-time and spatial dependence in skill for prediction of monthly mean climate variability is analyzed. The analysis is based on a set of extensive hindcasts from the Climate Forecast System at the National Centers for Environmental Prediction. The skill characteristics of initialized predictions is also compared with the AMIP simulations forced with the observed sea surface temperature (SST) to quantify the role of initial versus boundary conditions in the prediction of monthly means. The analysis is for prediction of monthly mean SST, precipitation, and 200-hPa height. The results show a rapid decay in skill with lead time for the atmospheric variables in the extratropical latitudes. Further, after a lead-time of approximately 30?C40?days, the skill of monthly mean prediction is essentially a boundary forced problem, with SST anomalies in the tropical central/eastern Pacific playing a dominant role. Because of the larger contribution from the atmospheric internal variability to monthly time-averages (compared to seasonal averages), skill for monthly mean prediction associated with boundary forcing is also lower. The analysis indicates that the prospects of skillful prediction of monthly means may remain a challenging problem, and may be limited by inherent limits in predictability.     

Prediction and monitoring of monsoon intraseasonal oscillations over Indian monsoon region in an ensemble prediction system using CFSv2

An ensemble prediction system (EPS) is devised for the extended range prediction (ERP) of monsoon intraseasonal oscillations (MISO) of Indian summer monsoon (ISM) using National Centers for Environmental Prediction Climate Forecast System model version 2 at T126 horizontal resolution. The EPS is formulated by generating 11 member ensembles through the perturbation of atmospheric initial conditions. The hindcast experiments were conducted at every 5-day interval for 45 days lead time starting from 16th May to 28th September during 2001–2012. The general simulation of ISM characteristics and the ERP skill of the proposed EPS at pentad mean scale are evaluated in the present study. Though the EPS underestimates both the mean and variability of ISM rainfall, it simulates the northward propagation of MISO reasonably well. It is found that the signal-to-noise ratio of the forecasted rainfall becomes unity by about 18 days. The potential predictability error of the forecasted rainfall saturates by about 25 days. Though useful deterministic forecasts could be generated up to 2nd pentad lead, significant correlations are found even up to 4th pentad lead. The skill in predicting large-scale MISO, which is assessed by comparing the predicted and observed MISO indices, is found to be ~17 days. It is noted that the prediction skill of actual rainfall is closely related to the prediction of large-scale MISO amplitude as well as the initial conditions related to the different phases of MISO. An analysis of categorical prediction skills reveals that break is more skillfully predicted, followed by active and then normal. The categorical probability skill scores suggest that useful probabilistic forecasts could be generated even up to 4th pentad lead.     

气候变化对喜马拉雅中部甘达基河流域濒危物种的影响预测（英文）

甘达基河流域位于喜马拉雅山脉中部,是众多濒危野生物种的重要栖息地。然而气候变化使该流域的生态环境变得愈发脆弱。本研究利用最大熵物种分布模型(Max Ent)评估气候变化对喜马拉雅黑熊(Ursus thibetanus laniger)和印度花豹(Panthera pardus fusca)等濒危物种空间分布变化的潜在影响。研究基于物种出没地点、生物气候和地形(海拔、坡度和坡向)等数据拟合模拟并预测物种在目前与未来的潜在分布情况。研究结果显示,目前喜马拉雅黑熊的高度适宜区面积约为1642 km²,占流域面积的5.01%,预计至2050年,其高度适宜区面积在甘达基河流域内将会增加约51 km²;印度花豹的高度适宜区面积约为3999 km²,占流域面积的12.19%,预计至2050年可能会增加到4806 km²。喜马拉雅黑熊的栖息地面积可能会在研究区域的东部(伯塞里、塔托潘尼和班塞以北)增加,而在东部(颂当、切坎帕)、西部(布尔提邦和波邦)和北部(桑波切、玛南、切坎帕)减少;印度花豹的栖息地面积则将在研究...     

Surface layer turbulence spectra and dissipation rates during low winds in tropics

Spectral characteristics of surface layer turbulence in an urban atmosphere are investigated. The observations used for this purpose represent low wind conditions in the tropics. The normalized power spectral shapes exhibit the usual characteristics in the inertial subrange and obey Monin-Obukhov scaling. However, the low-frequency behaviours do not conform to the previous observed relations. For horizontal components, large energy is contained in the low frequencies in contrast to the vertical component where roll-off to zero frequency is faster.The turbulent kinetic energy dissipation rate estimated from the spectra using Kolmogorov's inertial subrange law is found to be isotropic unlike the velocity variances. The expressions for the dimensionless dissipation rate do not seem to work well in low winds in an urban atmosphere. For the data considered, the dissipation rate exhibits a power law relationship with the mean windspeed and the friction velocity.