Rare earth elements in modern coral sands: an environmental proxy

The concentration rare earth elements and Yttrium (REE + Y) were determined in coral sands from Kavaratti Island, Arabian Sea, India. Chondrite-normalized REE + Y patterns show: (1) high REE concentration particularly light REE (LREE) enrichment; (2) consistent negative Ce anomaly; (3) nearly chondritic Y/Ho ratios. All these features are consistent with the geochemistry of well oxygenated seawater with significant terrestrial contribution. The seawater composition of Nd/Yb ratio inferred from the coral record point to the dominance of LREE more than the heavy REE (HREE). The high terrestrial input rich in LREE and property of adsorption/scavenging processes of LREE than that of HREE may be the cause. Terrigenous contributions were detected on the basis of co-occurring trace element concentrations (Sc, Hf and Th) and Y/Ho ratio. Except for La, the REE distribution coefficients, KD(REE)s, are between 100 and 300. KDs are high comparing to the other elements in biogenic calcite which is attributed to detrital contamination during elemental incorporation. This study may not reflect original seawater chemistry but it can be a good proxy to indicate proximity of corals to terrigenous input sources.     

Bacterial flora and antibiotic resistance from eggs of green turtles Chelonia mydas: An indication of polluted effluents

Sea turtles migrate to various habitats where they can be exposed to different pollutants. Bacteria were collected from turtle eggs and their resistance to antibiotics was used as pollutant bio-indicators of contaminated effluents. Eggs were collected randomly from turtles when they were laying their eggs. A total of 90 eggs were collected and placed into sterile plastic bags (3 eggs/turtle) during June-December of 2003. The bacteria located in the eggshell, albumen and yolk were examined, and 42% of the eggs were contaminated with 10 genera of bacteria. Pseudomonas spp. were the most frequent isolates. The albumen was found to be the part of the egg to be the least contaminated by bacterial infection. Bacterial isolates tested with 14 antibiotics showed variations in resistance. Resistance to ampicillin was the highest. The presence of antibiotic resistant bacteria in eggs indicates that the green turtle populations were subjected to polluted effluents during some of their migratory routes and feeding habitats. Scanning electron microscopy revealed that Salmonella typhimurium penetrated all eggshell layers.     

Qualitative and Quantitative Characterization of Mangrove Vegetation Structure and Dynamics in a Peri-urban Setting of Douala (Cameroon): An Approach Using Air-Borne Imagery

Qualitative and quantitative characterization of mangrove vegetation structure and dynamics is required for assessment of coastal habitat vulnerability. Changes in mangrove forests around Douala, Cameroon, have been documented using aerial photography between 1974 and 2009. The distribution pattern of tree species was also assessed in 2009 following the point-centered quarter method (PCQM+) protocol. Pristine mangroves observed in 1974 had been disturbed markedly in 2003 and 2009. Some of the pre-existing mangroves were entirely replaced by settlements, road, and crops (maize, bean, banana, oil palm, green vegetables, and sugar cane plantations). From 1974 to 2003, 39.86 % of mangrove forests have disappeared; the net loss of 22.10 % occurred between 2003 and 2009 alone. Mangrove forest area had decreased 53.16 % around Douala over a 35-year period from 1974 to 2009 concurrent with a substantial increase of settlements (60 %), roads (233.33 %), agriculture areas (16 %), non-mangrove areas (193.33 %), and open water (152.94 %). Field survey showed that almost one third of the quadrants in the remaining mangrove forest were empty. The disrupted mangrove forest has an overall mean height, absolute density, and basal area of 19.80 m, 158 trees ha^?1, and 110.44 m² ha^?1, respectively. In comparison with scientific literature on mangrove degradation, this puts the mangroves around Douala at the top of the “peri-urban mangrove degradation” list. In addition, beyond listing of mangrove plants on the Red List of Threatened Species which will seldom lead to widely distributed species being listed, we call for the creation of a Red List of Locally Threatened Ecosystems, which in contrast is likely to list mangroves as an ecosystem under critical risk of (local) extinction in many countries around the globe, in particular, peri-urban sites.     

Role of vegetation in shaping Early Pennsylvanian braided rivers: Architecture of the Boss Point Formation,Atlantic Canada

Vegetation is a major driver of fluvial dynamics in modern rivers, but few facies models incorporate its influence. This article partially fills that gap by documenting the stratigraphy, architecture and palaeobotany of the Lower Pennsylvanian Boss Point Formation of Atlantic Canada, which contains some of the Earth's earliest accumulations of large woody debris. Braided‐fluvial systems occupied channel belts of varied scale within valleys several tens of metres deep and more than 12 km wide, and their deposits predominantly consist of sandy and gravelly bedforms with subordinate accretionary macroforms, high flow‐strength sand sheets and rippled abandonment facies. Discrete accumulations of clastic detritus and woody debris are up to 6 m thick and constitute at least 18% of the in‐channel deposits; they represent lags at the base of large and small channels, fills of minor channels and sandy macroforms that developed in central positions in the upper parts of channel fills. Sandstones with roots and other remnants of in situ vegetation demonstrate that vegetated islands were present, and the abundance of discrete channel fills suggests that the formation represents an anabranching, island‐braided sandbed river, the earliest example documented to date. Although some sphenopsid and lycopsid remains are present, most woody fragments are derived from cordaitalean trees, and the evolution of this group late in the Mississippian is inferred to have exerted a significant influence on fluvial morphodynamic patterns. The formation records a landscape in which active channel belts alternated with well‐drained floodplains colonized by dense, mature forests and local patches of pioneering, disturbance‐tolerant vegetation. Lakes and poorly drained floodplains dominated by carbonate and organic deposition, respectively, were also present. A large supply of woody debris triggered channel blockage and avulsion, and active channel margins and islands within the channel belts were initially colonized by pioneer vegetation and subsequently stabilized by large trees. A similar alternation of stable and unstable conditions is observed in modern braided rivers actively influenced by vegetation.     

Groundwater quality of Yemen volcanic terrain and their geological and geochemical controls

One hundred thirty boreholes of volcanic aquifers in rural Yemen Highland Groundwaters (YHGs) were chemically investigated to assess the suitability of water for drinking. Focus is to identify inorganic constituents of significant risk to health that occur in groundwaters of this area. Results showed that a number of boreholes contain, apart from fluoride, levels of nitrate, some heavy metals, total dissolved solids, and sulfates that could pose a health risk for consumers. The lateral variations of major ions with depth varied within the same aquifer based on the dynamic equilibrium of groundwater and hydrogeological conditions. The main inorganic groundwater contaminant in volcanic YHG is fluoride which is attributed to groundwater lithology and water type. Fluoride appears high in Ca-poor groundwater and where cation exchanges of Ca for Na are dominant. High F concentration in YHG is an extension of East African fluoride-rich groundwater. Majority of tube wells show that Fe concentration exceeds WHO guideline many folds. Much of the iron and manganese in groundwaters are naturally occurring, since the source rocks are enriched in ferromagnesian minerals. NO ₃ ^? and Cl^? concentrations that have been detected in some wells may indicate sewage and/or agricultural runoff. Elevated concentration of chemical constituents in groundwater is a sign of groundwater degradation.