Amplitudes of long-period PcP and the core-mantle boundary

The amplitudes of the core reflection PcP are sensitive to the wave velocities and densities in the neighborhood of the core-mantle boundary (CMB). We study the amplitude ratio of the long-period phases PcP and P from two South American deep-focus earthquakes with favorable fault-plane solution, depth and magnitude, as recorded by WWNSS and CSN stations in North America.Comparison is made with long-period PcP/P amplitude ratios, derived from theoretical seismograms for a variety of CMB models. Models from previous studies, which were mainly derived from short-period PcP observations and which are characterized by discrete layers above the CMB, are almost all inconsistent with the long-period data. The data also discriminate against low nonzero S velocities below the CMB. Simple first-order-discontinuity models of the CMB, for instance according to the Jeffreys-Bullen earth model or according to recent models based mainly on free oscillations, explain the data reasonably well.Model improvements are attempted by varying the P-velocity gradient above the CMB. The best amplitude fit is obtained for a rather strong decrease in P velocity with depth in this zone which, however, gives no acceptable traveltime fit for PcP. The scatter in body-wave amplitudes is considerable even for long-period waves and may prevent the correct assessment of that part of the amplitude variation of a phase with distance that is due to the variation of velocities and densities with depth alone.     

The magnetotelluric dispersion relations over 2-D structures

The causal properties of the magnetotelluric response, first derived by Weidelt, and Fischer & Schnegg in the 1-D limit, are confirmed numerically in the 2-D limit for the particular structure consisting of two uniform quarter spaces. This finding is of interest from several points of view: (1) the dispersion relations in their 1-D form seem to retain their validity for all 2-D tensor elements, irrespective of any rotation of the coordinate system chosen at the surface; in particular, (2) they appear equally valid for the E- and B-polarization configurations. (3) Whereas the question recently debated in the literature (whether the Earth can always be considered as a linear, passive and causal system) is perhaps not yet entirely resolved, the present empirical demonstration suggests that it may in general be safe to apply the 1-D dispersion relations to structures with 2-D character.     

Point-block covariance: A general solution for the two-dimensional stationary random functions

The application of the theory of random functions to problems of ore evaluation may involve computations of the covariance between the mean value of a given block and the functional value at a given point. However, an analytical solution for such a covariance does not exist for nonspherical blocks and for commonly applied models of covariance functions. Further, because this covariance is a function of the spatial arrangements of the block and the point, it has to be evaluated numerically each time for given point—block arrangements. This paper presents a readily available general solution to this problem in the form of a series of graduated curves which, together with some geometric manipulations, may be used to compute the covariance between a pointand a two-dimensional block for all possible point—block arrangements. The availability of the graph thus eliminates the necessity of using the time-absorbing programs on computers for such computations. Finally, many of the approximations that are made in order to avoid cumbersome covariance evaluations are no longer necessary due to the ease of such computations with the help of the graph provided.     

Evolution and observational signature of diffused antiworld

The existence of macroscopic regions with antibaryon excess in the baryon asymmetric Universe with general baryon excess is the possible consequence of practically all models of baryosynthesis. Diffusion of matter and antimatter to the border of antimatter domains defines the minimal scale of the antimatter domains surviving to the present time. A model of diffused antiworld is considered, in which the density within the surviving antimatter domains is too low to form gravitationally bound objects. The possibility to test this model by measurements of cosmic gamma ray fluxes is discussed. The expected gamma ray flux is found to be acceptable for modern cosmic gamma ray detectors and for those planned for the near future.     

Modeling of type III bursts dynamic spectra

The one-dimensional process of spatially limited electron stream propagation in the solar corona is simulated. It is shown that the beam instability development results either in strong relaxation in velocity space and inhibition of spatial diffusion (high-stream density) or in velocity space relaxation decrease and simultaneous growth of spatial stream length (low-stream density). Assuming a profile of background plasma density to be exponential, dynamic spectra of type III bursts are modeled, which shows that the emission source velocity is constant, and a duration of the burst emission at a given frequency reduces for high-stream densities.     

Carbonate equilibria in hydrothermal systems: First ionization of carbonic acid in NaCl media to 300°C

The ionization quotients of aqueous carbon dioxide (carbonic acid) have been precisely determined in NaCl media to 5 m and from 50° to 300°C using potentiometric apparatus previously developed at Oak Ridge National Laboratory. The pressure coefficient was also determined to 250°C in the same media. These results have been combined with selected information in the literature and modeled in two ways to arrive at the best fits and to derive the thermodynamic parameters for the ionization reaction, including the equilibrium constant, activity coefficient quotients, and pressure coefficients. The variation with temperature of the two fundamental quantities $\text{Δ}\text{V}\text{?}{}^{\mathrm{o}}$ and $\text{Δ}\text{C}\text{?}{}^{\mathrm{o}}{}_{\mathrm{p}}$ were examined along the saturation vapor pressure curve and at constant density. The results demonstrated again that for reactions with minimal electrostriction changes the magnitudes and variations of $\text{Δ}\text{C}\text{?}{}^{\mathrm{o}}{}_{\mathrm{p}}$ and $\text{Δ}\text{V}\text{?}{}^{\mathrm{o}}$ with temperature are small and, in addition, $\text{Δ}\text{C}\text{?}{}_{\mathrm{p}}$ and $\text{Δ}\text{V}\text{?}$ are approximately independent of salt concentration.The results have also been applied to an examination of the solubility of calcite as a function of pH (in a given NaCl medium) for the neutral to acidic region both for systems with fixed CO₂ pressure and systems where the calcium ion concentration equals the concentration of carbon. The pH of saturated solutions of calcite with P_CO2 of 12 bars increases from 5.1 to 5.5 between 100° and 300°C.     

Integration of reflection seismic and sediment grain-size data from Lake Khubsugul (Northern Mongolia): a reply to Prokopenko and Kendall

Prokopenko and Kendall (J Paleolimnol doi:, 2008) criticise the work presented in Fedotov et al. (J Paleolimnol 39:335–348, 2008), and instead propose an alternative interpretation for the grain-size evolution recorded in the KDP-01 core, retrieved from the central part of Lake Khubsugul. Their interpretation is based (i) on a seismic-stratigraphic re-interpretation of sparker seismic profile khub012 (which they copied from Fedotov et al. (EOS Trans 87:246–250, 2006)), (ii) on the presupposition that changes in lake level are the dominant control on facies distribution in Lake Khubsugul, and (iii) on the invalidation of our age-depth model. In this reply to their comment, we demonstrate that they interpreted seismic artefacts and geometries caused by changes in profile orientation as true stratigraphic features and that the lake-level reconstruction they derive from this interpretation is therefore incorrect. We also demonstrate that their grain-size predictions, which they consider to be predominantly driven by changes in lake level, are inconsistent with the measured sulphate concentration, which is a demonstrated proxy of lake level in Lake Khubsugul, and with the measured grain-size record. Finally, we point out that even if there would be a problem with the age-depth model, this problem would not affect the part of the sedimentary sequence discussed in Fedotov et al. (J Paleolimnol 39:335–348, 2008).     

ON THE GENERATION OF P AND S WAVE ENERGY IN CRYSTALLINE ROCKS*

A seismic source consisting of a 700 kg weight that could be dropped vertically or projected down a ramp inclined at 45° to the vertical was tested as a source of P, SV and SH waves within a crystalline rock body at Chalk River, Ontario. The seismic energy was recorded by arrays of both horizontal and vertical-component geophones at distances between 30 and 600 m from the source, which was operated over glacial overburden varying in thickness from less than a meter to a few tens of meters. Seismic energy was more efficiently generated when the overburden thickness was at least several meters. The signals identified visually as S are generally true S, though some may be the converted wave PS. The SV amplitudes are generally larger than those of P, regardless of the type of shot, while the signal frequencies are roughly 60 Hz and 90 Hz, respectively. The horizontal-component seismograms for the inclined shots showed no evidence of SH polarization, and the SH amplitudes were only rarely enhanced relative to P and SV amplitudes on changing from vertical to inclined shots. These unexpected results are attributed to the combined effect of the high velocity and density contrasts and the irregularity of the boundary between the glacial overburden and the rock body.     

Ecological-geochemical assessment of the state of the Volga source of water supply to Moscow

Long-term observational data (1992?C2009) on heavy metal (Cu, Zn, Pb, Cr, Ni, V, Mo, Co, Fe, and Mn) content of different links in the Ivankovo Reservoir ecosystem are used to consider the regularities in the distribution and behavior of heavy metals in the system anthropogenic pollution sources-reservoir and its drainage area, thus enabling the assessment of the pollution level of the Volga Source of water supply to Moscow.