渭北黄土台塬全新世地层高分辨率研究

在野外观测研究的基础上 ,对陕西扶风新店村全新世黄土剖面作了详细的地层划分。通过磁化率、粒度、TOC、全铁和碳酸盐含量测定分析 ,进一步揭示渭北黄土台塬全新世季风气候变化的规律。同时 ,阐明了“全新世大暖期”的气候有明显的波动变化 ,尤其是在 6 0 0 0— 5 0 0 0 a B.P.发生了一个干旱气候事件 ,形成黄土堆积 ,使得全新世古土壤分裂成为两层 ,表现为多周期土壤。从 3 10 0 a B.P.开始至今气候变得干旱 ,风尘堆积旺盛 ,形成了现代黄土和表土层     

Adsorption of phenanthrene on Al (oxy)hydroxides formed under the influence of tannic acid

Although there has been substantial research done on adsorption of metals/metalloids by Al (oxy)hydroxides, little is known regarding the adsorption of polyaromatic hydrocarbons (PAHs) on Al (oxy)hydroxides, especially those formed in the presence of organic acid. This paper investigated the adsorption of phenanthrene on Al (oxy)hydroxides formed with initial tannate/Al molar ratios (MRs) 0, 0.001, 0.01, and 0.1 (referred to MR0, MR0.001, MR0.01, and MR0.1, respectively) through batch adsorption experiments and FTIR study. The results showed that Al (oxy)hydroxides were important sorbents for phenanthrene. The adsorption kinetic data were fitted well with the pseudo-second-order equation. According to a modified Freundlich model, the adsorption capacities of Al (oxy)hydroxides followed a descending order of MR0.1 > MR0 ≥ MR0.01 > MR0.001, which was inconsistent with the organic carbon content in the Al (oxy)hydroxides. Adsorption capacity correlated with the specific surface area, micropore area, and micropore diameter of Al (oxy)hydroxides, yet the relationships were not statistically significant (P > 0.05). FTIR results showed that physical interaction was essential in phenanthrene adsorption onto the Al (oxy)hydroxides, which could be explained by an entropy-driven process. Surface hydrophobicity of Al (oxy)hydroxides played a key role in phenanthrene adsorption. Additional π–π electron donor–acceptor interaction of phenanthrene (acting as electron donor) with aromatic ring of tannic acid (electron acceptor) could be also important in phenanthrene adsorption by high MR Al (oxy)hydroxides, yet it needs further study. The findings obtained in the present study are of fundamental significance in understanding the mechanism of immobilization of PAHs in low organic matter but oxide-rich soils.     

不同酸液条件下叙利亚灰岩溶蚀能力的实验研究

文章根据SY/T 6526-2002《盐酸与碳酸盐岩动态反应速率测定方法》,利用高温高压酸岩反应仪进行了普通盐酸、有机盐酸、胶凝酸、乳化酸和地面交联酸与叙利亚灰岩粉末在两个目的层温度95 ℃和150 ℃下2.0 h的溶蚀实验。结果显示,五种酸液2.0 h的酸溶解率都在90%以上,普通盐酸、有机盐酸的溶蚀能力高于胶凝酸、乳化酸和地面交联酸三种缓速酸;95 ℃下乳化酸和地面交联酸溶解慢、溶解率低,而150 ℃下是地面交联酸和胶凝酸;适当条件下,“多相隔离”对H+抑制作用要比高粘度溶液强,而且随着酸液内部高分子之间链接复杂程度的提高,H+被束缚的程度也增大;温度提高增大了酸溶解率,对乳化酸、地面交联酸和胶凝酸影响比较显著,对普通盐酸和有机盐酸不明显。      

大别山超高压变质岩的变形特征及其地质意义

大别山超高压变质岩至少经过５期变形。第１期产生于榴辉岩相变质前；第２期大致与榴辉岩相变质作用同步．岩石产生紧密同斜褶皱及榴辉岩相糜棱岩；第３期产生于超高压变质岩向中地壳折返的过程中，以榴辉岩的布丁化及基质的透入性剪切为特征；第４期主要形成剪切条带及伸展沿劈理．是大别山碰撞后差异隆升，岩层向南滑脱的结果；最后一期为脆性变形，岩层沿北东向断层产生左行平移。通过超高压变质岩的变形分析，可以了解超高压变质岩形成和折返的构造运动过程。     

高精度温度采集系统设计

针对高精度温度采集的需求,设计了一个以低功耗单片机MSP430F149作为核心处理器,以PT100铂电阻为传感器的温度采集系统。为了提高系统的复用性,采用精密电阻法,从硬件设计上消除了恒流源电流漂移以及A/D转换电路参考电压精度对温度测量数据的影响。重点描述了系统设计方案,详细说明了恒流源选择的原则、电流偏差的消除以及AD7792转换器的操作步骤。实验结果表明,温度测量精度优于0.1 ℃。对比试验表明,系统稳定性良好,已应用于业务产品中。     

扬子板块北缘下志留统龙马溪组重晶石结核特征及其成因机制分析

在扬子板块北缘城口明中剖面及巫溪徐家坝剖面下志留统龙马溪组底部的硅质岩、泥岩中发现椭球状重晶石结核。其矿物组成主要为重晶石颗粒与作为"基质"的黄铁矿、粘土矿物和石英。通过重晶石岩石学、矿物学及锶同位素分析表明,重晶石结核形成于早期成岩阶段松软沉积物的孔隙水中。上升洋流带来丰富的营养及富钡物质,表层海水的高初始生产力促使生物繁盛,海水中的钡通过生物作用富集形成生物钡,生物钡(bio-barite)在埋藏过程中的硫酸盐耗竭区(sulfate depleted zones)通过硫酸盐细菌作用(BSR)溶解被激活提供了钡的来源。围岩岩性(黑色泥岩和硅质泥岩)表明重晶石结核形成于缺氧的环境中。上述研究对深入理解早志留世时期扬子板块北缘古海洋环境有一定的启示作用。     

Delineating the Source of Lead in the Urban Atmospheric Dust Based on Stable Isotopic Ratio: A Case Study from Panzhihua City of Southwest China

正Objective Atmospheric lead pollution is a global problem. Mining, coal mining, iron and steel smelting, and chemical and coal-fired power plants are major industries in Panzhihua City of southwest China. Many toxic and harmful heavy metals, including Pb, are emitted in production activities. Pb seriously affects human health and natural ecosystems. Thus, Pb source tracing is important for Pb pollution     

浙江省雷击跳闸数据与闪电定位数据统计分析

利用浙江省电力部门雷击跳闸数据、浙江省气象局闪电定位数据,统计分析了2007—2011年电力雷击跳闸事故与地闪数据之间的时空分布特点、雷击跳闸事故与地闪参数及距离之间的关系。结果表明:电力雷击跳闸事故与地闪数据的日分布和月分布均为单峰结构,相关系数分别为0.9905和0.9881;空间分布虽有一定对应,但并非显著相关;导致110kV、220kV及500kV输电线路雷击跳闸的地闪强度主要集中在90kA以下,并且500kV输电线路雷击跳闸对应的电流强度相对较小;地闪与雷击跳闸事故杆塔距离、地闪与雷击跳闸杆塔对应输电线路的距离均主要集中在2km以下。     

重庆城区浓雾的基本特征

统计分析沙坪坝1951～2002年间发生的浓雾事件，结合2001年12月重庆市雾的外场试验资料，探索重庆市主城区浓雾的基本特征。重庆主城区浓雾随年代演变有减缓趋势；主城区浓雾是自然雾与烟尘等的混合物，河谷及城市效应使雾更浓；城市中出现浓雾的大气边界层特征是在近地面层有逆温及增湿降温现象；高浓度气溶胶的净辐射效应阻碍白天混合层发展，使大气边界层趋于稳定，它是重庆连续几天有雾的原因之一；浓雾具有一定的湿沉降作用，能有限地清洁空气；有浓雾的天气条件下，建议降低污染物的排放总量，以避免严重大气污染事件发生。