Stable isotope evidence for multiple fluid regimes during carbonate cementation of the Upper Tertiary Hazeva Formation, Dead Sea Graben, southern Israel

Stable carbon- and oxygen-isotope compositions of calcite and dolomite cements have been used to understand porewater evolution in the Upper Tertiary Hazeva Formation within the Dead Sea Graben, southern Israel. Sandstone samples were obtained from four boreholes in three tectonic blocks of the graben over depths of 253–6448 m, a variation that largely reflects differential subsidence of individual fault-bounded blocks. Early carbonate cements dominate diagenesis. Calcite occurs at <1600 m, but was replaced by dolomite at greater depths. Dolomite at 1600–2700 m is Fe-poor (<0.8 mol% FeCO₃), and at 4700–6200 m, Fe-rich (0.5–7.2 mol% FeCO₃). Magnesite, anhydrite and halite are the final diagenetic phases. Calcite has positively correlated δ¹⁸O (+21‰ to +25‰) and δ¹³C (−6‰ to −2‰) values that generally decrease with depth. Dolomite has a wider variation in δ¹⁸O (+18‰ to +30‰) and δ¹³C (−8‰ to −1‰) values, which also generally are lower with increasing depth. However, the δ¹³C and δ¹⁸O values of dolomite from the uppermost 400 m of the Hazeva Formation in the Sedom Deep-1 borehole are anomalous in spanning the entire range of stable carbon and oxygen isotopic compositions over this relatively small interval.The decreasing dolomite δ¹³C values likely indicate an increased contribution of carbon from organic sources with increasing depth. Except for the uppermost 400 m, Hazeva Formation dolomite in the Sedom Deep-1 borehole has stable carbon-isotope compositions that imply initial dolomitization at much shallower levels, prior to the preferential subsidence of this tectonic block. The oxygen isotopic compositions of the calcite cement are best explained by equilibration at present burial temperatures (≤55 °C) with porewater of meteoric origin. Its δ¹⁸O values increased from −5‰ at the shallowest depths to 0‰ at 1600 m. The dolomite oxygen isotopic compositions also reflect equilibration at present burial temperatures with porewaters ranging from 0‰ at 1600 m to +7‰ at 3600 m (100 °C). In the deepest fault block (Sedom Deep-1 borehole), however, increasingly Fe-rich dolomite has (re)equilibrated with porewater whose δ¹⁸O values decreased from +9‰ at 4750 m (120 °C) to +1‰ to +2‰ by 6200 m (150 °C).Much of the dolomite likely formed at relatively shallow depths from saline brines derived from precursors to the Dead Sea. These infiltrated the Hazeva Formation, mixing with and largely displacing meteoric water, and dolomitizing calcite. Rock–water ratios tended to be high during these processes. However, the upper 400 m of the Hazeva Formation in the deepest fault block were likely deposited during its rapid tectonic subsidence, and largely escaped the initial style of dolomitization pervasive elsewhere in the study area. These sediments were also capped by evaporites. This relatively thin interval likely became a preferential conduit for brines that escaped underlying and overlying strata, including the Fe-rich, lower ¹⁸O fluids (evolved seawater?) present in the deepest part of the graben. These rocks present the most promising target for the passage and accumulation of hydrocarbons in the study area.     

Petrology of the uppermost upper mantle deduced from spinel-lherzolite and harzburgite nodules at Calton Hill,Derbyshire

A suite of protogranular- to porphyroclastic-textured spinel lherzolites and harzburgites from the Lower Carboniferous ankaramite vent at Calton Hill has been investigated for trends of modal variation and mineral composition and for variation in calculated bulk composition. The results indicate that the nodules are accidental xenoliths derived from a source at approximately 45 km depth and at 950 °C, i.e. within the mantle but above the Low Velocity Zone. The lherzolites and harzburgites have a complex petrogenetic history involving initital formation as residues from partial melting of peridotite; it is proposed that the residues were then admixed with veins of pyroxenite, followed by a complex series of metamorphic cycles of mineral reaction and exsolution, deformation, recrystallization and annealing and finally by rupture and incorporation in the ankaramite. During ascent to the surface chrome diopside in some nodules has undergone partial, incongruent melting to form a less sodic pyroxene and a soda-rich basalt melt.     

An Origin for Harrisitic and Granular Olivine in the Rum Layered Suite, NW Scotland: a Crystal Size Distribution Study

Dendritic crystal morphologies occur in a number of igneousrocks and are thought to originate from the rapid growth ofcrystals, yet many examples of dendritic morphologies are foundin plutonic igneous rocks where cooling rates should be low.Results from crystal size distribution (CSD) measurements onharrisitic olivines from Rum, Scotland, combined with estimatedolivine growth rates, suggest that the characteristic skeletalhopper and branching olivines of harrisitic cumulates that areup to centimetres long, may have exceptionally short crystalgrowth times (several hours to several hundreds of days). This,together with very low calculated nucleation densities for harrisiticolivine, supports the interpretation of harrisite being a disequilibriumtexture, developed in response to supersaturation of the magmain olivine. We propose that this supersaturation arose throughundercooling of thin picrite sheets emplaced along the Rum magmachamber floor, beneath cooler resident magma. It is envisagedthat the picrite sheets were largely free of suspended olivinecrystals. Coupled with the olivine-enriched composition of themelt and the increasing cooling rate, this allowed homogeneousnucleation of olivine to set in at deeper undercooling and greaterolivine supersaturation than if there had been plentiful suspendedolivines to act as heterogeneous nuclei. The enhanced supersaturationcaused rapid growth of olivine once nucleation began, with skeletaland dendritic shapes. It is suggested that the observed, interlayeredsequences of harrisite and cumulus peridotite found throughoutthe Rum Layered Suite are a result of multiple episodes of harrisitecrystallization resulting from picrite emplacement that alternatedwith periods of crystal growth and accumulation in the mainbody of magma at lesser degrees of undercooling. KEY WORDS: crystal size distribution; harrisite; crystal growth rates; Rum Layered Suite     

Archaean quartz arenites in the Canadian Shield: examples from the Superior and Churchill Provinces

Units of remarkably pure Archaean quartz arenite occur in the northwestern part of the Superior Province and in the northern terrane of the Western Churchill Province (Rae Province) of the Canadian Shield. In the Superior Province, silica-cemented quartz arenites of Archaean age are well preserved in several greenstone belts. The example from the Keeyask Lake sedimentary assemblage displays tabular–planar and trough cross-beds, ripple marks, reactivation surfaces and pebble lag deposits. In spite of penetrative deformation and greenschist-grade metamorphism, primary textures are extremely well preserved, showing framework grains to be very well rounded and sorted. The succession of Keeyask Lake quartz-arenite beds is overlain by siltstones containing small-scale stratiform, domal and columnar stromatolites. A shallow-marine environment of deposition is inferred. Detrital heavy minerals include pyrite, magnetite, zircon, tourmaline, apatite, sphene and topaz. In the northern part of the Western Churchill Province (Rae Province), Archaean quartz arenites occur in northeasterly trending belts where intense structural deformation has in most places obscured or obliterated primary textures and structures. This has led to speculation that some of these units are metachert or recrystallized vein quartz, but local preservation of primary textures and structures provides clear evidence of epiclastic origin. In the example described herein, quartz arenites of the Woodburn Lake Group display sparse occurrences of trough and tabular–planar cross-beds, channels, ripple marks and pebble lag deposits. Probable environments of deposition for these quartz arenites include fluvial systems and shallow-marine shelf settings. The occurrence of unequivocal quartz-arenite clasts in beds of intercalated conglomerate provides direct evidence of at least two episodes of accumulation of almost pure quartz sand. Thin sections and polished slabs reveal frameworks of clastic quartz grains with little to no matrix (now mainly muscovite), and rare detrital grains of accessory heavy minerals, predominantly zircon and opaque iron oxides. Pyrite and other sulphides have been introduced along fractures, but some intergranular sulphide grains may be of detrital origin. The principal source for the quartz arenites in both areas must have been quartz-rich granitoid rocks. Conditions of intense chemical weathering are indicated. The widespread occurrence of extremely mature quartz arenites throughout Archaean terranes of the Canadian Shield, and in other shields of the world, are suggestive of crustal stability during early Earth history. The association of quartz arenites and ultramafic rocks, uncharacteristic of younger terranes, is now recognized in many Archaean greenstone belts of the Canadian Shield.     

Sediment distribution and evolution of tidal deltas along a tide-dominated shoreline, Wachapreague, Virginia

Borings from the barrier island/lagoon system of the Eastern Shore of Virginia penetrated an unconformity which separates Pleistocene barrier island and offshore marine sediments from the overlying Holocene tidal delta and barrier island sediments. Offshore marine sediments and deposits within the flood-tidal delta (marsh, tidal flat-bay, inlet-mouth bar complex) are recognized on the basis of sediment color, composition, grain-size changes in the vertical sequence, presence of organic matter, and faunal suite. Subsurface data, historical records, and morphology of lateral accretion on barrier islands suggest that major inlets in the vicinity of Wachapreague have been relatively stable throughout Holocene time; they appear to be located where Pleistocene stream valleys previously existed. Holocene barrier islands apparently developed on drainage divide areas following post-Wisconsin transgression of the sea.

The initial phase of tidal delta development was characterized by vertically accreting, fan-shaped, inlet-mouth bars; tidal channels stabilized after bar crests had shoaled sufficiently for marsh to form. With landward progradation across the lagoon, sand-rich deposits graded laterally away from the inlets and vertically into clayey sand and silty clay of the tidal flat-bay and marsh environments.

Ebb inlet-mouth bars developed asymmetrically southward in response to littoral drift. Flood tidal deltas also built preferentially toward the south as indicated by: (1) sand distribution of the inlet-mouth bar complex; and (2) greater development of marsh south of the inlets.