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11.
Thomas Backhaus Rolf Altenburger sa Arrhenius Hans Blanck Michael Faust Antonio Finizio Paola Gramatica Matthias Grote Marion Junghans Wiebke Meyer Manuela Pavan Tobias Porsbring Martin Scholze Roberto Todeschini Marco Vighi Helge Walter L. Horst Grimme 《Continental Shelf Research》2003,23(17-19):1757
Freshwater and marine ecosystems are exposed to various multi-component mixtures of pollutants. Nevertheless, most ecotoxicological research and chemicals regulation focus on hazard and exposure assessment of individual substances only, the problem of chemical mixtures in the environment is ignored to a large extent. In contrast, the assessment of combination effects has a long tradition in pharmacology, where mixtures of chemicals are specifically designed to develop new products, e.g. human and veterinary drugs or agricultural and non-agricultural pesticides. In this area, two concepts are frequently used and are thought to describe fundamental relationships between single substance and mixture effects: Independent Action (Response Addition) and Concentration Addition. The question, to what extent these concepts may also be applied in an ecotoxicological and regulatory context may be considered a research topic of major importance, as the concepts would allow to make use of already existing single substance toxicity data for the predictive assessment of mixture toxicities. Two critical knowledge gaps are identified: (a) There is a lack of environmental realism, as a huge part of our current knowledge about the applicability of the concepts is restricted to artificial situations with respect to mixture composition or biological effect assessment. (b) The knowledge on what exactly is needed for using the concepts as tools for the predictive mixture toxicity assessment is insufficient. Both gaps seriously hamper the necessary, scientifically sound consideration of mixture toxicities in a regulatory context.In this paper, the two concepts will be briefly introduced, the necessity of considering the toxicities of chemical mixtures in the environment will be demonstrated and the applicability of Independent Action and Concentration Addition as tools for the prediction and assessment of mixture toxicities will be discussed. An overview of the specific aims and approaches of the BEAM project to fill in the identified knowledge gaps is given and first results are outlined. 相似文献
12.
H. C. Soffel S. Schmidt M. Davoudzadeh C. Rolf 《International Journal of Earth Sciences》1996,85(2):293-302
New pole positions for Triassic and Cretaceous times have been obtained from volcanic and sedimentary sequences in Central Iran. These new results confirm the general trend of the Apparent Polar Wander Path (APWP) of the Central-East-Iran microplate (CEIM) from the Triassic through the Tertiary as published by Soffel and Förster (1983, 1984). Two new palaeopoles for the Triassic of the CEIM have been obtained; limestones and tuffs from the Nakhlak region yield a mean direction of 094.0°/25.0°, N=12, k=4.1,α 95=24.7°, after bedding correction, corresponding to a palaeopole position of 310.8°E; 3.9°S, and volcanic rocks from the Sirjan regions yield a mean direction of 114.5°/35.1°, N=44, k=45.9,α 95=3.2° after bedding correction and a palaeopole position of 295.8°E; 10.3°N. Combining these with the two previously published results yields a new palaeopole position of 317.5°E; 12.7°N, for the Triassic of the CEIM, thus confirming that large counterclockwise rotations of the CEIM have occurred since the Triassic time. New results have also been obtained from Cretaceous limestones from the Saghand region of the CEIM. The mean direction of 340.7°/26.3°, N=33, k=44.3,α 95=3.8°, and the corresponding palaeopole position of 283.1°E; 64.4°N, is in agreement with previously determined Cretaceous palaeopole positions of the CEIM. Furthermore, results have also been obtained from Triassic dolomite, limestone, sandstone and siltstone from the Natanz region, which is located to the west of the CEIM. A total of 161 specimens from 44 cores taken at five sites gave a mean direction of the five sites at 033.3°/25.1°, N=5, k=69.0,α 95=9.3° and a palaeopole position of 167.2°E; 53.7°N. They pass the positive fold test of McElhinny (1964) on the level of 99% confidence. This pole position is in fairly good agreement with the mean Triassic pole position of the Turan Plate (149°E; 49°N). It indicates that the area of Natanz has not undergone the large counterclockwise rotation relative to the Turan plate since the Triassic, which has been shown for the CEIM. A Triassic palaeogeographic reconstruction of Iran, Arabia (Gondwana) and the Turan Plate (Eurasia) is also presented. 相似文献
13.
Role of the subducted slab,mantle wedge and continental crust in the generation of adakites from the Andean Austral Volcanic Zone 总被引:78,自引:2,他引:78
All six Holocene volcanic centers of the Andean Austral Volcanic Zone (AVZ; 49–54°S) have erupted exclusively adakitic andesites
and dacites characterized by low Yb and Y concentrations and high Sr/Y ratios, suggesting a source with residual garnet, amphibole
and pyroxene, but little or no olivine and plagioclase. Melting of mafic lower crust may be the source for adakites in some
arcs, but such a source is inconsistent with the high Mg# of AVZ adakites. Also, the AVZ occurs in a region of relatively
thin crust (<35 km) within which plagioclase rather than garnet is stable. The source for AVZ adakites is more likely to be
subducted oceanic basalt, recrystallized to garnet-amphibolite or eclogite. Geothermal models indicate that partial melting
of the subducted oceanic crust is probable below the Austral Andes due to the slow subduction rate (2 cm/year) and the young
age (<24 Ma) of the subducted oceanic lithosphere. Geochemical models for AVZ adakites are also consistent with a large material
contribution from subducted oceanic crust (35–90% slab-derived mass), including sediment (up to 4% sediment-derived mass,
representing approximately 15% of all sediment subducted). Variable isotopic and trace-element ratios observed for AVZ adakites,
which span the range reported for adakites world-wide, require multistage models involving melting of different proportions
of subducted basalt and sediment, as well as an important material contribution from both the overlying mantle wedge (10–50%
mass contribution) and continental crust (0–30% mass contribution). Andesites from Cook Island volcano, located in the southernmost
AVZ (54°S) where subduction is more oblique, have MORB-like Sr, Nd, Pb and O isotopic composition and trace-element ratios.
These can be modeled by small degrees (2–4%) of partial melting of eclogitic MORB, yielding a tonalitic parent (intermediate
SiO2, CaO/Na2O>1), followed by limited interaction of this melt with the overlying mantle (≥90% MORB melt, ≤10% mantle), but only very
little (≤1%) or no participation of either subducted sediment or crust. In contrast, models for the magmatic evolution of
Burney (52°S), Reclus (51°S) and northernmost AVZ (49–50°S) andesites and dacites require melting of a mixture of MORB and
subducted sediment, followed by interaction of this melt not only with the overlying mantle, but the crust as well. Crustal
assimilation and fractional crystallization (AFC) processes and the mass contribution from the crust become more significant
northwards in the AVZ as the angle of convergence becomes more orthogonal.
Received: 1 March 1995 / Accepted: 13 September 1995 相似文献
14.
15.
Arne P. Willner Stuart N. Thomson Johannes Glodny Hans‐Joachim Massonne Rolf L. Romer Cees R. van Staal Alexandre Zagorevski 《地学学报》2019,31(1):1-10
Following Appalachian orogenesis, metamorphic rocks in central Newfoundland were exhumed and reburied under Tournaisian strata. New zircon fission‐track (ZFT) ages of metamorphic rocks below the Tournaisian unconformity yield post‐depositionally reset ages of 212–235 Ma indicating regional fluid‐absent reheating to at least ≥220°C. Post‐Tournaisian sedimentary thicknesses in surrounding basins show that burial alone cannot explain such temperatures, thus requiring that palaeo‐geothermal gradients increased to ≥30–40°C/km before final late Triassic accelerated cooling. We attribute these elevated palaeo‐geothermal gradients to localized thermal blanketing by insulating sediments overlying radiogenic high‐heat‐producing granitoids. Late Triassic rifting and magmatism before break up of Pangaea likely also contributed to elevated heat flow, as well as uplift, triggering late Triassic accelerated cooling and exhumation. Thermochronological ages of 240–200 Ma are seen throughout Atlantic Canada, and record rifting and basaltic magmatism on the conjugate margins of the Central Atlantic Ocean preceding the onset of oceanic spreading at ~190 Ma. 相似文献
16.
Tomaso R. R. Bontognali Judith A. McKenzie Rolf J. Warthmann Crisogono Vasconcelos 《地学学报》2014,26(1):72-77
Some species of sulphate‐reducing bacteria (SRB) are known to mediate the formation of dolomite and Mg‐calcite. However, their exact role in the mineralization process remains elusive. Here, we present the result of a laboratory experiment that was designed to test whether formation of carbonate minerals by SRB can occur in the absence of living cells, through passive mineralization of their exopolymeric substances (EPS). SRB capable of mediating dolomite were cultivated in the laboratory, allowing them to secrete EPS. Microbial activity within the cultures was subsequently inhibited with antibiotics. Only after this step, Ca2+ and Mg2+ were added to the solution and carbonate minerals could form. Mg‐calcite and disordered Ca‐dolomite precipitated in association with EPS. The mol.% of Mg2+ in the crystals increased with longer incubation times. This result demonstrates that organic compounds produced by SRB can mediate the formation of Ca‐Mg carbonates in the absence of an active metabolism. 相似文献
17.
The Late Cretaceous Klepa basalts in Macedonia (FYROM)—Constraints on the final stage of Tethys closure in the Balkans 下载免费PDF全文
Dejan Prelević Simon Wehrheim Magnus Reutter Rolf L. Romer Blažo Boev Milica Božović Paul van den Bogaard Vladica Cvetković Stefan M. Schmid 《地学学报》2017,29(3):145-153
The waning stage(s) of the Tethyan ocean(s) in the Balkans are not well understood. Controversy centres on the origin and life‐span of the Cretaceous Sava Zone, which is allegedly a remnant of the last oceanic domain in the Balkan Peninsula, defining the youngest suture between Eurasia‐ and Adria‐derived plates. In order to investigate to what extent Late‐Cretaceous volcanism within the Sava Zone is consistent with this model we present new age data together with trace‐element and Sr–Nd–Pb isotope data for the Klepa basaltic lavas from the central Balkan Peninsula. Our new geochemical data show marked differences between the Cretaceous Klepa basalts (Sava Zone) and the rocks of other volcanic sequences from the Jurassic ophiolites of the Balkans. The Klepa basalts mostly have Sr–Nd–Pb isotopic and trace‐element signatures that resemble enriched within‐plate basalts substantially different from Jurassic ophiolite basalts with MORB, BAB and IAV affinities. Trace‐element modelling of the Klepa rocks indicates 2%–20% polybaric melting of a relatively homogeneously metasomatised mantle source that ranges in composition from garnet lherzolite to ilmenite+apatite bearing spinel–amphibole lherzolite. Thus, the residual mineralogy is characteristic of a continental rather than oceanic lithospheric mantle source, suggesting an intracontinental within‐plate origin for the Klepa basalts. Two alternative geodynamic models are internally consistent with our new findings: (1) if the Sava Zone represents remnants of the youngest Neotethyan Ocean, magmatism along this zone would be situated within the forearc region and triggered by ridge subduction; (2) if the Sava Zone delimits a diffuse tectonic boundary between Adria and Europe which had already collided in the Late Jurassic, the Klepa basalts together with a number of other magmatic centres represent volcanism related to transtensional tectonics. 相似文献
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20.
Phase center modeling for LEO GPS receiver antennas and its impact on precise orbit determination 总被引:12,自引:5,他引:7
Adrian Jäggi R. Dach O. Montenbruck U. Hugentobler H. Bock G. Beutler 《Journal of Geodesy》2009,83(12):1145-1162
Most satellites in a low-Earth orbit (LEO) with demanding requirements on precise orbit determination (POD) are equipped with
on-board receivers to collect the observations from Global Navigation Satellite systems (GNSS), such as the Global Positioning
System (GPS). Limiting factors for LEO POD are nowadays mainly encountered with the modeling of the carrier phase observations,
where a precise knowledge of the phase center location of the GNSS antennas is a prerequisite for high-precision orbit analyses.
Since 5 November 2006 (GPS week 1400), absolute instead of relative values for the phase center location of GNSS receiver
and transmitter antennas are adopted in the processing standards of the International GNSS Service (IGS). The absolute phase
center modeling is based on robot calibrations for a number of terrestrial receiver antennas, whereas compatible antenna models
were subsequently derived for the remaining terrestrial receiver antennas by conversion (from relative corrections), and for
the GNSS transmitter antennas by estimation. However, consistent receiver antenna models for space missions such as GRACE
and TerraSAR-X, which are equipped with non-geodetic receiver antennas, are only available since a short time from robot calibrations.
We use GPS data of the aforementioned LEOs of the year 2007 together with the absolute antenna modeling to assess the presently
achieved accuracy from state-of-the-art reduced-dynamic LEO POD strategies for absolute and relative navigation. Near-field
multipath and cross-talk with active GPS occultation antennas turn out to be important and significant sources for systematic
carrier phase measurement errors that are encountered in the actual spacecraft environments. We assess different methodologies
for the in-flight determination of empirical phase pattern corrections for LEO receiver antennas and discuss their impact
on POD. By means of independent K-band measurements, we show that zero-difference GRACE orbits can be significantly improved
from about 10 to 6 mm K-band standard deviation when taking empirical phase corrections into account, and assess the impact
of the corrections on precise baseline estimates and further applications such as gravity field recovery from kinematic LEO
positions. 相似文献