Aftershocks of the San Marcos earthquake of April 25, 1989 (M S =6.9) and some implications for the Acapulco-San Marcos,Mexico, seismic potential

Aftershock activity following the April 25, 1989 (M _S =6.9) earthquake near San Marcos, Guerrero, Mexico, was monitored by a temporary network installed twelve hours after the mainshock and remaining in operation for one week. Of the 350 events recorded by this temporary array, 103 were selected for further analysis in order to determine spatial characteristics of the aftershock activity. An aftershock area of approximately 780 km² is delimited by the best quality locations. The area of highest aftershock density lies inside an area delimited by the aftershocks of the latest large event in the region in 1957 (M _S =7.5) and it partially overlaps the zone of maximum intensity of the earlier 1907 (M _S =7.7) shock. Aftershocks also appear to cluster close to the mainshock hypocenter. This clustering agrees with the zone of maximum slip during the mainshock, as previously determined from strong motion records. A low angle Benioff zone is defined by the aftershock hypocenters with a slight tendency for the slab to follow a subhorizontal trajectory after a 110 km distance from the trench axis, a feature which has been observed in the neighboring Guerrero Gap. A composite focal mechanism for events close to the mainshock which also coincides with the zone of largest aftershock density, indicates a thrust fault similar to the mainshock fault plane solution.The San Marcos event took place in an area which could be considered as a mature seismic gap. Due to the manner in which strain release has been observed to previously occur, the occurrence of a major event, overlapping both the neighboring Guerrero Gap and the San Marcos Gap segments of the Mexican thrust, cannot be overlooked.     

Temporal fluctuations of water repellency in forest soils of Galicia,NW Spain. Do soil samples dried at laboratory reflect the potential soil water repellency?

Water repellency is a widespread property of Pinus pinaster and Eucalyptus globulus forest soils in NW Spain and is particularly severe during the summer dry conditions. The aim of this work was to compare actual water repellency at field‐moist samples with potential water repellency after drying at 25 and 105 °C in samples collected at different times of year under four forest soils. Also, we investigated whether drying at 25 or 105 °C led to repellency values comparable to the highest levels reached under field conditions in the summer with a view to developing an appropriate sampling protocol towards estimating the maximum possible water repellency of a given soil as a key to establishing its environmental effects. The actual and potential water repellency was determined by using the water drop penetration time (WDPT) and molarity of an ethanol drop (MED) tests. Clear seasonal patterns of water repellency were observed from the results for the four forest soils, peaking in the dry period and disappearing after prolonged wet periods. Water repellency lasts longer in sandy loam soils than in more finely textured soils, and also under eucalyptus than under pine forests. Drying soil samples at 25 or 105 °C increased water repellency, as measured with the WDPT method, in the four soils, but especially in the non‐repellent samples collected during the wet period. The increase was more marked in the sandy loam soils than in the more finely textured soils, and also after drying at 105 °C than at 25 °C. MED measurements exposed a common trait in the four soils; thus, the water repellency values obtained under field conditions in summer invariably exceeded those obtained after drying at 25 or 105 °C. In addition, the repellency values for dried samples collected in the wet period were never comparable to the maximum levels observed under field conditions in the summer. Copyright © 2011 John Wiley & Sons, Ltd.     

Hydrogeochemical and isotopic characterizations of an aquifer in the semi-arid region of the Mexican Highlands

This work addresses hydrogeochemical processes in shallow aquifers, represented by the Quaternary alluvial deposits, from a part of the semi-arid Mexican Highlands through the evaluations of physicochemical parameters as well as the δ¹⁸O and δ²H compositions of groundwater. Mifflin diagram separates the Na-bicarbonate, sulphate and mixed groundwater into one group showing interactions with volcanic lithology in the recharge zones and another group interacting with the evaporite rich sedimentary formation. In the Gibbs diagram, the samples with Cl^?/(Cl^? + HCO₃^?) < 0.4 showed higher influence of ion exchange and the samples with Cl^?/(Cl^? + HCO₃^?) > 0.4 showed higher effects of evaporation. All of them were oversaturated with carbonate minerals (i.e., calcite and dolomite) and unsaturated with evaporites (i.e., gypsum and halite). Evaporation (earlier stage) occurred before the water-rock interactions (later stage). Evolution occurs through three different routes such as up to 7.5‰ enrichment in δ¹⁸O caused by the infiltration with a certain delay and subsequently, the water-rock interaction became dominant. Ternary mixing models revealed dominant influence of local recharge (C₁) on the water system, contributing 70.4%. Water-rock interaction (C₃) with 18% and evaporation (C₂) with 11.6% had comparatively less influences. The presence of nitrate (2–60 mg/L) in the groundwater indicated variable degrees of anthropogenic pollution.     

The Risk Atlas of Mexico City,Mexico: a tool for decision-making and disaster prevention

Natural Hazards - We present a Risk Atlas of Mexico City based on a Geographical Information System (RA-GIS). We identified the prevalent social risk to the more relevant hazards in Mexico City...     

Insights into cation exchange selectivity of a natural clinoptilolite by means of dielectric relaxation spectroscopy

Purified natural clinoptilolite from the Tasajeras deposit, Cuba, and some of its metal exchanged forms are studied, at the dehydrated state, by means of dielectric relaxation spectroscopy (DRS) using two different modus operandi: complex impedance spectroscopy and dielectric dynamic thermal analysis. Data analysis yields the determination of the extra-framework cation (EFC) population into the various possible crystallographic sites of the zeolitic framework as well as of the activation energy characterizing the localized hopping mechanism of EFC. First, it is shown that the DRS responses obtained here match well with the previous reported data, which were previously localized EFCs in positions close to M1 and M2 sites when the clinoptilolite is modified to almost homoionic form. From this outcome, it can be concluded that all EFCs are in the same crystallographic situation regarding solvation or, in other terms, that no steric effect can be taken into account to explain cationic selectivity. Second, based on the assumption that the activation energy for EFC hopping is directly connected to the EFC/framework interaction and on simple thermodynamics consideration, we show this interaction does not govern the EFC exchange reaction. So, it is emphasized that EFC/H₂O interaction is the key factor for cation exchange selectivity.     

Risk of metal mobility in soils from a Pb/Zn depleted mine (Lugo,Spain)

The risk of Pb, Zn and Cd mobility is evaluated in soils from a depleted mine at Rubiais (Lugo, Spain). This area is under special protection because of its outstanding natural value. Soils from nine different areas were selected: at the mining zone (R1, R2, R3), at minespoils (R4, R5, R6) and soils developed on the settling pond (R7, R8, R9). A control soil (RC) was sampled outside the mine. The objectives are (i) to study the characteristics of soils with high influence on metal retention, (ii) to determine the content of Pb, Zn and Cd comparing it with the generic reference levels, and (iii) to evaluate the distribution and the interactions between the metals and the soil geochemical phases by means of sequential chemical extraction, X-ray diffraction, field emission scanning electron microscopy/energy-dispersive X-ray spectroscopy (FE-SEM/EDS) and time of flight secondary ion mass spectrometry (TOF–SIMS). The concentration of Pb, Zn and Cd ranges 850–6,761, 1,754–32,287 and 1.8–43.7 mg kg^?1, respectively, and the highest proportion is in the residual fraction. The Mn oxides highly influence the retention of Cd while Pb retention is mainly influenced by Fe oxides. Zn is uniformly distributed amongst the residual fraction and the Fe and Mn oxides. TOF–SIMS and SEM/EDS techniques confirm the fractionation results, showing how Pb and Zn are as sulphide and associated with Fe and Mn oxides. Nevertheless, care should be taken since oxides and sulphides could suffer sulphide oxidation processes or alteration of the oxides causing leaching and the contamination of the protected ecosystem.     

Changes in groundwater chemistry due to metallurgical activities in an alluvial aquifer in the Moa area (Cuba)

The aim of this work is to evaluate the changes in groundwater chemistry in an alluvial aquifer in the Moa area. Surface and ground water, metallurgical waste and various geological material samples were collected in order to evaluate groundwater composition. The results show that the alluvial aquifer is polluted with SO₄^2-, Mg²⁺and heavy metals. According to its major components in the alluvial aquifer, two types of groundwater are identified: magnesi-bicarbonated and sulphate-magnesic. Maximum SO₄^2– and Mg²⁺ contents are more than 1000 mg/L, and are four times higher than the acceptable levels for human consumption of water. The high values of Cr(VI), Ni(II), Mn(II) Fe_(total), SO₄^2– and Mg²⁺ in alluvial aquifers are due to polluted recharge from metallurgical waste from the tailing dam. This recharge is favoured by the preferential flow due to desiccation cracks in metallurgical waste. Geochemical modelling showed that potentially toxic heavy metals might exist largely in the forms of MSO₄^2– and M²⁺ in pore water of SAL metallurgical waste. All samples were supersaturated in goethite and hematite. Results from batch testing indicate that the heavy metals have two origins: natural, due to the existing ultramaphic rocks and laterites, and anthropogenic, by metallurgical waste rich in sulphate and (oxy)hydroxide minerals. These results highlight the need to locate and evaluate a new water source to supply the population of the city of Moa.     

Changes in Climate and Crop Production During the 20th Century in Argentina

This work was focused on the assessment of changes occurring in crop production and climate during the 20th century in Argentina. The study was carried out for nine sites located in the Pampas region that are representative of contrasting environments. We have considered the four main crops cultivated in this area (wheat, maize, sunflower and soybean). Historical climatic data and crop production related variables (yield, planted area, harvested area) were analyzed and, by means of crop simulation models, we quantified the impact of climate on crop yields. Changes occurring in climate during the three last decades of the 20th century were characterized by important increases in precipitation especially between October and March, decreases in maximum temperature and solar radiation in particular during spring and summer and increases in minimum temperature during almost all of the year. These changes contributed to increases in yields, especially in summer crops and in the semiarid zone, mostly due to increases in precipitation, although changes in temperature and radiation also affected crop yields but to a lesser extent. Comparing the period 1950–1970 with 1971–1999, yields increases attributable to changes in climate were 38% in soybean, 18% in maize, 13% in wheat, and 12% in sunflower while mean observed yield increases were 110% for maize, 56% for wheat and 102% for sunflower.     

Radiating Fluid Spheres in the Effective Variables Approximation

We study the evolution of spherically symmetric radiating fluid distributions using the effective variables method, implemented ab initio in Schwarzschild coordinates. To illustrate the procedure and to establish some comparison with the original method, we integrate numerically the set of equations at the surface for two different models. The first model is derived from the Schwarzschild interior solution. The second model is inspired in the Tolman VI solution.     

Variation of Proton Flux Profiles with the Observer’s Latitude in Simulated Gradual SEP Events

We studied the variation of the shape of the proton intensity–time profiles in simulated gradual Solar Energetic Particle (SEP) events with the relative observer’s position in space with respect to the main direction of propagation of an interplanetary (IP) shock. Using a three-dimensional (3D) magnetohydrodynamic (MHD) code to simulate such a shock, we determined the evolution of the downstream-to-upstream ratios of the plasma variables at its front. Under the assumption of an existing relation between the normalized ratio in speed across the shock front and the injection rate of shock-accelerated particles, we modelled the transport of the particles and obtained the proton flux profiles to be measured by a grid of 18 virtual observers located at 0.4 and 1.0 AU, with different latitudes and longitudes with respect to the shock nose. The differences among flux profiles are the result of the way each observer establishes a magnetic connection with the shock front, and we found that changes in the observer’s latitude may result in intensity changes of up to one order of magnitude at the two radial distances considered here. The peak intensity variation with the radial distance for the pair of observers located at the same angular position was also derived. This is the first time that the latitudinal dependence of the peak intensity with the observer’s heliocentric radial distance has been quantified within the framework of gradual SEP event simulations.