Entstehung und Alter der Oberharzer Gänge

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Protokoll der wissenschaftlichen Sitzung am 4. und 5. Januar 1937

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Tektonische Beziehungen zwischen Harzrand und Harzvorland

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Über Flysch und Molasse im Allgäu

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Deep Space 1 at comet 19P/Borrelly: Magnetic field and plasma observations

On September 22, 2001 the Deep Space 1 spacecraft performed a flyby at comet 19P/Borrelly at a solar distance of 1.36 AU leading the Earth by 74^° in longitude. The spacecraft-comet distance at closest approach was 2171 km. The bow shock had a magnetic compression ratio of 2.5 at a distance of 147 100 km from the nucleus. Deep Space 1 first entered the sheath region essentially from the north polar region. Fluctuations from the cometary ion pickup were present throughout the sheath region and even well upstream of the shock, as expected. The magnetic field pileup region had a peak field strength of 83 nT and was shown to be consistent with a pressure equal to the solar wind ram pressure. The peak field location was offset from the time of closest approach. It is uncertain whether this is a spatial or temporal variation. Draping of magnetic fields around the nucleus was sought, but evidence for this was not apparent in the data. A possible explanation is that the interplanetary solar wind was composed of turbulent short-scale fields, and thus the fields were not symmetric about the point of closest approach. During the flyby phase there were in general few intervals of ACE data where there were large scale Parker spiral fields. With the addition of plasma data, the shock properties are investigated. The characteristics of magnetic draping, pileup and fluctuations are explored. These comet 19P/Borrelly results are contrasted with other cometary flyby results.     

First attempts towards an integrative concept for the ecological assessment of groundwater ecosystems

Healthy aquifers deliver important ecosystem services, e.g. the purification of infiltrating water and the storage of high-quality water over decades in significant quantities. The functioning of terrestrial and surface aquatic ecosystems directly depends on groundwater and vice versa. Nowadays, legislation has started to consider groundwater not only as a resource but as a living ecosystem. The assessment of ecosystems requires consideration of ecological criteria, which, so far, are not available for groundwater systems. In the framework of a project supported by the German Federal Environment Agency (UBA), a first concept for the ecological assessment of groundwater ecosystems is developed. Steps to be taken are introduced, with a strong focus on microbes as potential bioindicators. These include (1) the typology of groundwater ecosystems, (2) the derivation of natural background values, (3) the identification of potential bioindicators, and (4) the development of an assessment model. First successes and difficulties associated with these challenges, e.g. the lack of simple correlations between abiotic and biotic variables, are discussed on the basis of a data set from a local and regional aquifer in NE Germany. The need for collaboration between ecologists, hydrogeologists and geochemists, as well as the application of modern approaches such as multivariate statistics, is emphasized.     

Recent evolution of Lake Arreo,northern Spain: influences of land use change and climate

We present a high-resolution, multiproxy reconstruction of the depositional history of Lake Arreo, northern Spain, for the last 60 years. We conducted sedimentological, geochemical and diatom analyses in short cores and made a detailed comparison with regional instrumental climate data (1952–2007), limnological monitoring of the lake (1992–2008) and recent land use changes that affect the lake catchment. Chronology is based on “floating” discontinuous varve counts and ¹³⁷Cs and ¹⁴C dates. Four periods were identified in the Lake Arreo recent history: (1) prior to 1963, varved facies intercalated with fine turbidite deposits, and diatom assemblages dominated by Cyclotella taxa indicate predominantly meromictic conditions, (2) from 1964 to 1978, permanent anoxia persisted in bottom waters, as shown by similar facies and diatom assemblages as before, though detrital layers were coarser, (3) from 1979 to 1994, sediment delivery to the lake increased and laminated, clastic facies were deposited, and (4) from 1995 to 2008, dominance of massive facies and an increase in Fragilaria tenera and Achnanthes minutissima reflect relatively lower lake levels, less frequent bottom anoxia with more frequent water column mixing, similar to modern conditions. The period 1952–1979 was a time of meromixis and varved facies deposition, and was characterized by higher rainfall and less intense agricultural pressure in the watershed. There were two short humid periods (1992–1993 and 1996–1998) when monitoring data show more anoxic weeks per year and relatively higher lake levels. Increased cultivation of small landholdings in 1963, and particularly after 1979, caused a large increase in sediment delivery to the lake. The inferred lake evolution is in agreement with monitoring data that suggest a transition from dominantly meromictic conditions prior to 1993–1994 to a predominantly monomictic pattern of circulation since then, particularly after 2000. The synergistic effects of intensive water extraction for irrigation and lower rainfall since 1979, and particularly since 1994, brought the long period of meromictic conditions in Lake Arreo to an end. Water balance and sediment delivery to the lake are dominant factors that control the limnological and mixing conditions in Lake Arreo and they must be considered in management and restoration plans.     

Ambient pressure thermal desorption spectroscopy (AP-TDS) of NiO/SiO2 catalysts

The Sabatier reaction is a key process in the “power-to-gas” application which is considered to contribute to future chemical energy storage systems. In this contribution we focus on the catalytic active sites of a NiO catalyst supported on SiO₂ (NiO/SiO₂) which is commonly used in the Sabatier reaction. A novel technique for the characterization of the active sites is presented and discussed using thermal desorption spectroscopy at ambient pressure. This analytical tool is operated under reaction conditions and allows element specific measurements during the catalytic process of CO₂ reforming towards methane. Beside the desorption experiments, XPS and XAS measurements of pristine and catalytically used samples are performed to determine the influence of the Sabatier reaction conditions on the surface structure of the catalyst.