Emanuel Kayser

Ohne Zusammenfassung     

The generalized Laplace condition

The Laplace condition relates conventionally disturbances of longitude-latitude and azimuth-horizon distance assuming parallelism of terrestrial and reference axes. Here the Laplace condition is generalized for non-parallel axes which coincide only after a three dimensional rotation.     

The Need for Ultraviolet to Understand the Chemical Evolution of the Universe and Cosmology.

We identify an important set of key areas where an advanced observational Ultraviolet capability would have major impact on studies of cosmology and Galaxy formation in the young Universe. Most of these are associated with the Universe at z < 3–4. We address the issues associated with Dark matter evidence in the local Universe and the impact of the Warm-Hot Intergalactic Medium WHIM on the local Baryon count. The motivations to make ultraviolet (UV) studies of supernovae (SNe) are reviewed and discussed in the light of the results obtained so far by means of IUE and HST observations. It appears that UV studies of SNe can, and do lead to fundamental results not only for our understanding of the SN phenomenon, such as the kinematics and the metallicity of the ejecta, but also for exciting new findings in Cosmology, such as the tantalizing evidence for “dark energy” that seems to pervade the Universe and to dominate its energetics. The need for additional and more detailed UV observations is also considered and discussed.Finally we show the enormous importance of the UV for abundance evolution in the Intergalactic Medium (IGM), and the importance of the He II studies to identify re-ionization epochs, which can only be done in the UV.     

Progress in application of cathodoluminescence (CL) in sedimentary petrology

Summary ¶Significant progress has been made in cathodoluminescence (CL) studies in the last three decades due to the application of enhanced methods such as high-resolution spectroscopy. The luminescence of all detrital and diagenetic minerals such as quartz, feldspar, phyllosilicates, carbonates, apatites, zircons etc. can now be quantitatively characterized by spectroscopy. For siliciclastic sediments, the potential for provenance studies has been explored because varying conditions at the time of formation (e.g. of quartz and zircons) might be encoded within the CL and therefore provide fingerprints for particular grain populations. Different cement generations allow a cement stratigraphy to be established and the deconvolution of the diagenetic history of carbonate and clastic sediments. CL investigations of carbonate, apatite and – with some limitations – siliceous biogenic skeletons provide evidence of growth zonation (ontogenetic cyclicities and changes in spatial distribution) and diagenesis (intra-skeleton cementation and recrystallization).However, further research using CL is required to fully understand detrital components, primary and secondary mineralization in sedimentary deposits and biogenic materials. We present here an, admittedly incomplete, overview of these developments.Received March 6, 2002; revised version accepted January 30, 2003 Published online June 12, 2003     

Der nordalpine Flysch zwischen der Ostschweiz und Salzburg

Ohne Zusammenfassung     

Harzrand und Subherzyn

Ohne ZusammenfassungVorläufiger Bericht! Eine ausführlichere Veröffentlichung der Untersuchungen erfolgt an anderer Stelle.     

Composite magnetic anisotropy fabrics: experiments, numerical models and implications for the quantification of rock fabrics

Magnetic fabrics from rocks with multiple mineral-preferred orientations may have anisotropy ellipsoids whose shape and orientation arise from the addition of two or more component fabrics. Our numerical models and experiments demonstrate that such composite magnetic fabrics do not directly reflect the shapes and/or orientations of the individual mineral fabrics and we provide criteria for the recognition and interpretation of composite fabrics in natural rocks. These criteria include:

1. (1) the orientation of the maximum susceptibility axis is located at the intersection of two planar fabrics, and

2. (2) the shape of the susceptibility ellipsoid changes from oblate to prolate and the degree of anisotropy decreases, as the relative intensity of two planar component fabrics becomes equal and as the angle between the planar fabrics increases.

Composite magnetic fabrics are observed in the shales and slates of the Martinsburg Formation, Lehigh Gap, Pennsylvania. Modeling of the AMS (anisotropy of magnetic susceptibility) and ARMA (anhysteretic remanent magnetization anisotropy) behavior constrains the relative degree of anisotropy of the bedding-parallel and cleavage-parallel fabrics. In particular, ARMA model results allow a good estimate of magnetite fabric strength.

We conclude that, in the presence of composite magnetic fabrics, quantitative measures of finite strain in deformed rocks are limited by the ability to accurately determine the degree of anisotropy and relative susceptibility of each component fabric. Such determinations require knowledge of the mineral(s) that are responsible for the measured magnetic fabric and their behavior during deformation.     

Quaternary sediment dynamics in the Belgica mound province,Porcupine Seabight: ice-rafting events and contour current processes

The Belgica cold-water coral banks on the eastern slope of the Porcupine Seabight are closely associated with bottom currents. In order to better understand the local temporal and spatial characteristics, as well as the palaeoclimatologic influences, a 26 m long core, taken on a small contourite drift, was studied. This sediment record of approximately 100 ka BP reveals new insights into the regional glacial and sedimentary processes, which are intrinsically linked to several geological, climatological, biological and hydrodynamic variables. The glacial sequences in the core contain six ice-rafting events (IRE). They are comparable with the North Atlantic Heinrich Events, although their characteristics show dominant influences from the proximal British–Irish Ice Sheet (BIIS). These IRE have a low magnetic susceptibility and are deposited during two or three ice-rafting pulses. The record of ice-rafting suggests a millennial-scaled BIIS destabilisation and confirms the start of a final retreat about 25 ka ago. Additionally, the glacial sequence corresponds to a muddy contourite, influenced by bottom-current strength variations during interstadials, possibly triggered by sporadic reintroductions of Mediterranean Outflow Water in a glacial North Atlantic Ocean. The interglacial sequence features an 11-m thick deep-water massive sand unit, probably deposited under a high-energy bottom-current regime.     

Isotope fractionation by chemical diffusion between molten basalt and rhyolite

Experimental diffusion couples were used to study chemical diffusion between molten rhyolite and basalt with special emphasis on the associated fractionation of calcium and lithium isotopes. Diffusion couples were made by juxtaposing firmly packed powders of a natural basalt (SUNY MORB) and a natural rhyolite (Lake County Obsidian) and then annealing them in a piston cylinder apparatus for times ranging from 0.1 to 15.7 h, temperatures of 1350-1450°C, and pressures of 1.2-1.3 GPa. Profiles of the major elements and many trace elements were measured on the recovered quenched glasses. The diffusivities of all elements except lithium were found to be remarkably similar, while the diffusivity of lithium was two to three orders of magnitude larger than that of any of the other elements measured. Chemical diffusion of calcium from molten basalt into rhyolite was driven by a concentration ratio of ∼18 and produced a fractionation of ⁴⁴Ca from ⁴⁰Ca of about 6 ‰. Because of the relatively low concentration of lithium in the natural starting materials a small amount of spodumene (LiAlSi₂O₆) was added to the basalt in order to increase the concentration difference between basalt and rhyolite, which was expected to increase the magnitude of diffusive isotopic fractionation of lithium. The concentration ratio between Li-doped basalt and natural rhyolite was ∼15 and the resulting diffusion of lithium into the rhyolite fractionated ⁷Li from ⁶Li by about 40‰. We anticipate that several other major rock-forming elements such as magnesium, iron and potassium will also exhibit similarly larger isotopic fractionation whenever they diffuse between natural melts with sufficiently large differences in the abundance of these elements.