Local Fractional Frequency Shifts Used as Tracers of Magnetic Activity

Using data from SOI-MDI (Haber et al., 2000), we compute the local frequencies of high-degree p modes and f modes. The frequencies are obtained through ring-diagram mode fitting. The Dense-Pack data set consists of a mosaic of 189 overlapping tiles, each tracked separately at the surface rotation rate over 1664-min time intervals during the Dynamics Programs. Each tile is 16° square and the tile centers are separated by 7.5° in latitude and longitude. For each sampling day and for each tile, we have computed the frequency shift measured relative to the temporal and spatial average of the entire set of frequencies. The motion of active regions as they rotate across the solar disk is vividly traced by these measurements. Active regions appear as locations of large positive frequency shifts. If the shifts are averaged over the solar disk and are scaled down to the appropriate wave number regime, the magnitude and frequency dependence of the shifts are consistent with the measured changes in global oscillation frequencies that occur over the solar cycle. As with the frequency shifts of low-degree global oscillations, the frequency dependence of the shifts indicates that the physical phenomena inducing the shifts is confined to the surface layers of the Sun.     

Correcting the errors from variable sea salt retention and water of hydration in loss on ignition analysis: Implications for studies of estuarine and coastal waters

The standard technique of determining the concentrations of total suspended solids (TSSs), particulate inorganic matter (PIM), and particulate organic matter (POM) by filtration with glass fiber filters is subject to an error or bias from sea salt plus water of hydration retention, when applied to saline waters. The sea salt plus water of hydration retention by the filters occurs even after washing the filter with 300 ml of deionized water, a greater volume than any wash recommended in the literature. We determined that the mass retention on a glass fiber filter, at a given salinity, is essentially constant, no matter the volume of seawater passed through the filter. We also determined that the sea salt plus water of hydration retention on glass fiber filters is directly proportional to the salinity of the seawater filtered. Sea salt plus water of hydration retention causes an overestimate of TSS; sea salt retention causes an overestimate of PIM; volatilization of water of hydration causes an overestimate of POM. Thus a correction curve is required for sea salt and water of hydration errors in the determination of TSS and PIM. Corrected POM comes from the difference between the two. Also, filter blanks (procedural control filters), run with deionized (DI) water rather than the seawater sample, are required to correct for possible filter mass loss during the analysis. We demonstrate correction curves for sea salt plus water of hydration retention for Whatman GF/F filters, 47 mm diameter, utilizing the methods of the APHA Manual, Standard Methods for the Examination of Water and Wastewater. Application of other glass fiber filter types or an analytical technique differing significantly from that employed here requires a different correction curve for retention of sea salt and water of hydration. These methods can be used to reanalyze older data on PIM, POM, and TSS.We apply these corrections to PIM and POM data from the northern Gulf of Mexico and examine the interactions of these filter corrections with corrections for structural water volatilization from suspended clay minerals in the determinations of PIM and POM. We analyze published data on PIM and POM determinations and their application to remote sensing. We conclude that sea salt and water of hydration retention on filters has an adverse effect on remote-sensing algorithms inverting radiance reflectance to estimate concentrations of suspended matter.     

A Lagrangian Stochastic Model for Heavy Particle Dispersion in the Atmospheric Marine Boundary Layer

The dispersion of heavy particles and pollutants is often simulated with Lagrangian stochastic (LS) models. Although these models have been employed successfully over land, the free surface at the air-sea interface complicates the implementation of traditional LS models. We present an adaptation of traditional LS models to the atmospheric marine boundary layer (MBL), where the bottom boundary is represented by a realistic wavy surface that moves and deforms. In addition, the correlation function for the turbulent flow following a particle is extended to the anisotropic, unsteady case. Our new model reproduces behaviour for Lagrangian turbulence in a stratified air flow that departs only slightly from the expected behaviour in isotropic turbulence. When solving for the trajectory of a heavy particle in the air flow, the modelled turbulent forcing on the particle also behaves remarkably well. For example, the spectrum of the turbulence at the particle location follows that of a massless particle for time scales approximately larger than the Stokes’ particle response time. We anticipate that this model will prove especially useful in the context of sea-spray dispersion and its associated momentum, sensible and latent heat, and gas fluxes between spray droplets and the atmosphere.     

Retrieving daily global solar radiation from routine climate variables

Solar radiation is an important variable for studies related to solar energy applications, meteorology, climatology, hydrology, and agricultural meteorology. However, solar radiation is not routinely measured at meteorological stations; therefore, it is often required to estimate it using other techniques such as retrieving from satellite data or estimating using other geophysical variables. Over the years, many models have been developed to estimate solar radiation from other geophysical variables such as temperature, rainfall, and sunshine duration. The aim of this study was to evaluate six of these models using data measured at four independent worldwide networks. The dataset included 13 stations from Australia, 25 stations from Germany, 12 stations from Saudi Arabia, and 48 stations from the USA. The models require either sunshine duration hours (Ångstrom) or daily range of air temperature (Bristow and Campbell, Donatelli and Bellocchi, Donatelli and Campbell, Hargreaves, and Hargreaves and Samani) as input. According to the statistical parameters, Ångstrom and Bristow and Campbell indicated a better performance than the other models. The bias and root mean square error for the Ångstrom model were less than 0.25 MJ m² day^?1 and 2.25 MJ m² day^?1, respectively, and the correlation coefficient was always greater than 95 %. Statistical analysis using Student’s t test indicated that the residuals for Ångstrom, Bristow and Campbell, Hargreaves, and Hargreaves and Samani are not statistically significant at the 5 % level. In other words, the estimated values by these models are statistically consistent with the measured data. Overall, given the simplicity and performance, the Ångstrom model is the best choice for estimating solar radiation when sunshine duration measurements are available; otherwise, Bristow and Campbell can be used to estimate solar radiation using daily range of air temperature.     

Determination of a precise rotation period for the Deep Space 1 target, Comet 19P/Borrelly

The rotation period derived by Mueller and Samarasinha (Mueller, B.E.A., Samarasinha, N.H. [2002]. Earth Moon Planets 90, 463-471) of the Deep Space 1 (DS1) mission target, Comet 19P/Borrelly, using ground-based data from July 28 to August 1, 2000, is improved by two orders of magnitude. This precision is reached in a multistep process.Combining all available ground-based data in 2000 decreases the error by an order of magnitude. Next, assuming that the rotation period did not change between 2000 and 2001, constraints from the HST 2001 data (Weaver, H.A., Stern, S.A., Parker, J.Wm. [2003]. Astron. J. 126, 444-451) yield three possible rotation periods: P = 1.088 ± 0.003 days, P = 1.108 ± 0.002 days, and P = 1.135 ± 0.003 days, which are consistent with our initial derivation of P = 1.08 ± 0.04 days (Mueller, B.E.A., Samarasinha, N.H. [2002]. Earth Moon Planets 90, 463-471).These three periods are further refined and the error bars further improved by another order of magnitude by linking the combined ground-based data from 2000 to the nuclear orientation of Borrelly at the DS1 encounter in 2001 (see Table 2). Due to aliasing, there are seven possible rotation periods around P = 1.088 days, five possible periods around P = 1.108 days, and six possible periods around P = 1.135 days, with precisions of the order of 0.0002 days (≈17 s).     

Nonlinear Formulation of the Bulk Surface Stress over Breaking Waves: Feedback Mechanisms from Air-flow Separation

Historically, our understanding of the air-sea surface stress has been derived from engineering studies of turbulent flows over flat solid surfaces, and more recently, over rigid complex geometries. Over the ocean however, the presence of a free, deformable, moving surface gives rise to a more complicated drag formulation. In fact, within the constant-stress turbulent atmospheric boundary layer over the ocean, the total air-sea stress not only includes the traditional turbulent and viscous components but also incorporates surface-wave effects such as wave growth or decay, air-flow separation, and surface separation in the form of sea-spray droplets. Because each individual stress component depends on and alters the sea state, a simple linear addition of all stress components is too simplistic. In this paper we present a model of the air-sea surface stress that incorporates air-flow separation and its effects on the other stress components, such as a reduction of the surface viscous stress in the separated region as suggested by recent measurements. Naturally, the inclusion of these effects leads to a non-linear stress formulation. This model, which uses a variable normalized dissipation rate of breaking waves and normalized length of the separation bubble, reproduces the observed features of the drag coefficient from low to high wind speeds despite extrapolating empirical wave spectra and breaking wave statistics beyond known limits. The model shows the saturation of the drag coefficient at high wind speeds for both field and laboratory fetches, suggesting that air-flow separation over ocean waves and its accompanying effects may play a significant role in the physics of the air-sea stress, at least at high wind speeds.     

Variability and change in the Canadian cryosphere

During the International Polar Year (IPY), comprehensive observational research programs were undertaken to increase our understanding of the Canadian polar cryosphere response to a changing climate. Cryospheric components considered were snow, permafrost, sea ice, freshwater ice, glaciers and ice shelves. Enhancement of conventional observing systems and retrieval algorithms for satellite measurements facilitated development of a snapshot of current cryospheric conditions, providing a baseline against which future change can be assessed. Key findings include: 1. surface air temperatures across the Canadian Arctic exhibit a warming trend in all seasons over the past 40?years. A consistent pan-cryospheric response to these warming temperatures is evident through the analysis of multi-decadal datasets; 2. in recent years (including the IPY period) a higher rate of change was observed compared to previous decades including warming permafrost, reduction in snow cover extent and duration, reduction in summer sea ice extent, increased mass loss from glaciers, and thinning and break-up of the remaining Canadian ice shelves. These changes illustrate both a reduction in the spatial extent and mass of the cryosphere and an increase in the temporal persistence of melt related parameters. The observed changes in the cryosphere have important implications for human activity including the close ties of northerners to the land, access to northern regions for natural resource development, and the integrity of northern infrastructure.     

Influences of sudden changes in discharge and physical stream characteristics on transient storage and nitrate uptake in an urban stream

Changes in the physical structure of urban streams can occur abruptly due to flashy high‐flow events and subsequently alter stream processes, including transient storage and nitrate uptake. We examined temporal variability in transient storage and nitrate uptake by exploring the effects of altered physical characteristics resulting from a single high‐flow event in three reaches of Spring Creek, an urban stream in Fort Collins, Colorado, USA. Study reaches of varying geomorphic and hydraulic characteristics were chosen to represent distinct geomorphic settings in terms of substrate size, sinuosity, bed slope, and degree of rehabilitation and structural controls. We performed detailed physical characterizations and multiple nutrient injections of Br^? and NO₃^? to estimate transient storage and nitrate uptake in each reach. A comparison of pre‐flood and post‐flood data indicates that transient storage and nitrate uptake are highly context specific and mediated by interactions between geomorphic setting and flood discharge. In the two reaches that showed significant post‐flood increases in transient storage (250% to 350% increases in F_med²⁰⁰), the pool‐riffle reach exhibited a significant increase in uptake velocity, while the channelized reach did not. In contrast, transient storage decreased post‐flood in the third reach containing hydraulic structures. These complex responses likely reflect reach‐specific differences in hyporheic versus in‐channel storage. This study shows that repeat injections are necessary to describe nutrient dynamics because transient storage and nitrate uptake can be highly variable over time (showing changes on the order of 100%) due to variation in discharge and geomorphically influential flow events. Copyright © 2014 John Wiley & Sons, Ltd.     

Identification of the natural product 2,3,4,5-tetrabromo-1-methylpyrrole in Pacific biota, passive samplers and seagrass from Queensland, Australia

Halogenated natural products (HNPs) are frequently detected in marine organisms. High HNP concentrations have previously been found in marine mammals from the Great Barrier Reef, Australia, including in the blubber of herbivorous dugongs (Dugong dugon). To identify the source of HNPs we initially focused on the analysis of Australian seagrass (Halophila ovalis) which serves as the principal food source for dugongs. GC/MS analysis of the seagrass indicated the presence of several organobromine compounds. One compound was identified as 2,3,4,5-tetrabromo-1-methylpyrrole (TBMP) by synthesis. Subsequent analysis of semipermeable membrane devices demonstrated that the photo-sensitive TBMP is widespread in the Great Barrier Reef (Queensland, Australia). The detection of larger TBMP concentrations in fish fillets from Chile and traces in mussels from New Zealand indicated that this potential HNP may be distributed throughout the Southern Pacific Ocean.     

A cleaner river: long term use of semipermeable membrane devices demonstrate that concentrations of selected organochlorines and PAHs in the Brisbane River estuary, Queensland have reduced substantially over the past decade

We first used semipermeable membrane devices as samplers to evaluate concentrations of organochlorines and PAHs in the Brisbane River in 1998. Here we revisit this work and repeat the study a decade later in the same season (summer), also taking account of results from a similar study involving PAHs in the summer of 2001-2002. The accumulation of organochlorines and most PAHs in the samplers in the recent assessment was substantially less than in the 1998 deployment, suggesting that the ambient concentrations of these chemicals have decreased considerably over the last decade. In all cases there was high reproducibility of the mass of chemicals accumulated in the sampler. We used performance reference compounds in the later deployment, and assuming that the kinetics were similar in both deployment periods, we estimate that the concentration of dieldrin, the organochlorine found at highest concentrations, decreased from approximately 3.9 ng/L to about 1.4 ng/L. The decrease of most other analytes of interest including DDE and DDD was greater, potentially indicating that dieldrin is still entering the Brisbane River through run-off from urban areas where it was used widely for treatment of termites until 1995. DDT use in Australia ceased in the mid 1980s.