Effective anisotropic velocity model from surface monitoring of microseismic events

We develop a methodology to obtain a consistent velocity model from calibration shots or microseismicity observed on a buried array. Using a layered 1D isotropic model derived from checkshots as an initial velocity model, we invert P‐wave arrival times to obtain effective anisotropic parameters with a vertical axis of symmetry (VTI). The nonlinear inversion uses iteration between linearized inversion for anisotropic parameters and origin times or depths, which is specific to microseismic monitoring. We apply this technique to multiple microseismic events from several treatments within a buried array. The joint inversion of selected events shows a largely reduced RMS error indicating that we can obtain robust estimates of anisotropic parameters, however we do not show improved source locations. For joint inversion of multiple microseismic events we obtained Thomsen anisotropic parameters ε of 0.15 and δ of 0.05, which are consistent with values observed in active seismic surveys. These values allow us to locate microseismic events from multiple hydraulic fracture treatments separated across thousands of metres with a single velocity model. As a result, we invert the effective anisotropy for the buried array region and are able to provide a more consistent microseismicity mapping for past and future hydraulic fracture stimulations.     

Rotation period of Venus estimated from Venus Express VIRTIS images and Magellan altimetry

The 1.02 μm wavelength thermal emission of the nightside of Venus is strongly anti-correlated to the elevation of the surface. The VIRTIS instrument on Venus Express has mapped this emission and therefore gives evidence for the orientation of Venus between 2006 and 2008. The Magellan mission provided a global altimetry data set recorded between 1990 and 1992. Comparison of these two data sets reveals a deviation in longitude indicating that the rotation of the planet is not fully described by the orientation model recommended by the IAU. This deviation is sufficiently large to affect estimates of surface emissivity from infrared imaging. A revised period of rotation of Venus of 243.023 ± 0.002 d aligns the two data sets. This period of rotation agrees with pre-Magellan estimates but is significantly different from the commonly accepted value of 243.0185 ± 0.0001 d estimated from Magellan radar images. It is possible that this discrepancy stems from a length of day variation with the value of 243.023 ± 0.002 d representing the average of the rotation period over 16 years.     

Monitoring pesticides in the Great Barrier Reef

Pesticide runoff from agriculture poses a threat to water quality in the world heritage listed Great Barrier Reef (GBR) and sensitive monitoring tools are needed to detect these pollutants. This study investigated the utility of passive samplers in this role through deployment during a wet and dry season at river mouths, two near-shore regions and an offshore region. The nearshore marine environment was shown to be contaminated with pesticides in both the dry and wet seasons (average water concentrations of 1.3-3.8 ng L⁻¹ and 2.2-6.4 ng L⁻¹, respectively), while no pesticides were detected further offshore. Continuous monitoring of two rivers over 13 months showed waters flowing to the GBR were contaminated with herbicides (diuron, atrazine, hexazinone) year round, with highest average concentrations present during summer (350 ng L⁻¹). The use of passive samplers has enabled identification of insecticides in GBR waters which have not been reported in the literature previously.     

Long term monitoring of photosystem II herbicides--correlation with remotely sensed freshwater extent to monitor changes in the quality of water entering the Great Barrier Reef, Australia

Photosystem II (PSII) herbicides are used in large quantities on agricultural lands adjoining the Great Barrier Reef (GBR). Routine monitoring at 14 sites in inshore waters of the GBR using passive sampling techniques detected diuron (32-94% of sampling periods) at maximum concentrations of 1.7-430ng L(-1) in the relatively pristine Cape York Region to the Mackay Whitsunday Region, respectively. A PSII herbicide equivalent (PSII-HEq) index developed as an indicator for reporting was dominated by diuron (average contribution 89%) and typically increased during the wet season. The maximum PSII-HEq indicates the potential for photosynthetic inhibition of diatoms, seagrass and coral-symbionts. PSII herbicides were significantly positively correlated with remotely sensed coloured dissolved organic matter, a proxy for freshwater extent. Combining these methods provides for the first time the potential to cost-effectively monitor improvements in water quality entering the GBR with respect to exposure to PSII herbicides.     

Symbiont-specific responses in foraminifera to the herbicide diuron

The effects of the photosystem II (PSII) herbicide diuron was assessed on thirteen tropical foraminifera hosting diatom, dinoflagellate, red or green algae endosymbionts. Inhibition of photosynthesis (reduced ΔF/F(m)(')) by diuron depended on both symbiont type and test ultrastructure, with greatest sensitivity observed for diatom- and chlorophyte-hosting species (24h IC(25) 2.5-4μg L(-1)). Inhibition kinetics was slow (24-48h until maximum inhibition) in comparison with corals, suggesting structural differences may influence herbicide uptake and transport. Although foraminifera were generally less sensitive to direct effects of diuron (inhibition ΔF/F(m)(')) than other marine phototrophs, damage to PSII (reduction F(v)/F(m)) occurred at concentrations lower than observed for other organisms (24h IC(25) 3-12μg L(-1)). Damage to PSII was highly light dependent and occurred at very low light intensities indicating limited photoprotective capacity. The high diversity, widespread occurrence and relative sensitivity make foraminifera good bioindicator organisms to evaluate phytotoxic stress on coral reefs.     

Assessment of climate change impact on Eastern Washington agriculture

An assessment of the potential impact of climate change and the concurrent increase of atmospheric CO₂ concentration on eastern Washington State agriculture was conducted. Climate projections from four selected general circulation models (GCM) were chosen, and the assessment included the crops with larger economic value for the state (apples, potatoes, and wheat). To evaluate crop performance, a cropping system simulation model (CropSyst) was utilized using historical and future climate sequences. Crops were assumed to receive adequate water (irrigated crops), nutrients, and control of weeds, pests and diseases. Results project that the impact of climate change on eastern Washington agriculture will be generally mild in the short term (i.e., next two decades), but increasingly detrimental with time (potential yield losses reaching 25% for some crops by the end of the century). However, CO₂ elevation is expected to provide significant mitigation, and in fact result in yield gains for some crops. The combination of increased CO₂ and adaptive management may result in yield benefits for all crops. One limitation of the study is that water supply was assumed sufficient for irrigated crops, but other studies suggest that it may decrease in many locations due to climate change.     

Origins and antiquity of the island fox (Urocyon littoralis) on California's Channel Islands

The island fox (Urocyon littoralis) is one of few reportedly endemic terrestrial mammals on California's Channel Islands. Questions remain about how and when foxes first colonized the islands, with researchers speculating on a natural, human-assisted, or combined dispersal during the late Pleistocene and/or Holocene. A natural dispersal of foxes to the northern Channel Islands has been supported by reports of a few fox bones from late Pleistocene paleontological localities. Direct AMS ¹⁴C dating of these “fossil” fox bones produced dates ranging from ∼ 6400 to 200 cal yr BP, however, postdating human colonization of the islands by several millennia. Although one of these specimens is the earliest securely dated fox from the islands, these new data support the hypothesis that Native Americans introduced foxes to all the Channel Islands in the early to middle Holocene. However, a natural dispersal for the original island colonization cannot be ruled out until further paleontological, archaeological, and genetic studies (especially aDNA [ancient DNA]) are conducted.     

ETCHING AS A PROCESS OF LANDFORM DEVELOPMENT *

Bedrock forms of etch origin result from the interaction of groundwaters and bedrock at the weathering front at the base of the regolith. They are significant for general theories of landscape and landform genesis because they are azonal with respect both to climate and lithology. Two stages of etch form development are recognized: one involves weathering and the formation of a regolith; the second consists of stripping of the regolith and the exposure of the bedrock forms. Although etch forms have been recognized for some two centuries, the concept of etching as a process of landform development has been neglected, particularly in North America.     

An Archean oceanic felsic dyke swarm in a nascent arc: the Hunter Mine Group, Abitibi Greenstone Belt, Canada

The 2730-Ma-old Hunter Mine Group (HMG), a dominantly felsic subaqueous volcanic sequence, was formed during early arc construction in the Abitibi greenstone belt (Quebec, Canada). The western part of the HMG contains a felsic dyke swarm up to 1.5 km wide and traceable up-section for 2.5 km. Five distinct generations were identified: (1) aphanitic to feldspar-phyric dykes; (2) quartz-feldspar-phyric dykes with < 5% quartz phenocrysts; (3) quartz-feldspar-phyric dykes with 10–25% quartz phenocrysts; (4) dacitic feldspar-phyric dykes; and (5) mafic dykes. The felsic dykes collectively constitute more than 90% of the dyke swarm. Geochemically, they resemble modern calc-alkaline dacites and rhyolites. Their mantle-normalized incompatible trace-element patterns display a moderate enrichment of Th and light REE relative to HFSE and heavy REE as well as negative Nb, Ta, Eu and Ti anomalies. Most of the major- and trace-element abundance variations in these rocks can be explained by crystallization of feldspars. Geochemical data including depleted mantle-like _Nd values suggest that an older sialic substrate was not involved in their genesis. We infer that the felsic rocks were generated by melting of mafic oceanic crust. The swarm was emplaced during nascent oceanic island-arc development and was related to rifting of the arc. The conformably overlying MORB-like basalts and basaltic komatiites of the Stoughton-Roquemaure Group used the same conduits and further indicate splitting of the arc. HMG and associated parts of the Abitibi greenstone belts bear a strong resemblance to modern rifted intraoceanic arcs of the western Pacific.     

Reference Minerals for the Microanalysis of Light Elements

The quantitative determination of light element concentrations in geological specimens represents a major analytical challenge as the electron probe is generally not suited to this task. With the development of new in situ analytical techniques, and in particular the increasing use of secondary ion mass spectrometry, the routine determination of Li, Be and B contents has become a realistic goal. However, a major obstacle to the development of this research field is the critical dependence of SIMS on the availability of well characterized, homogeneous reference materials that are closely matched in matrix (composition and structure) to the sample being studied. Here we report the first results from a suite of large, gem crystals which cover a broad spectrum of minerals in which light elements are major constituents. We have characterized these materials using both in situ and wet chemical techniques. The samples described here are intended for distribution to geochemical laboratories active in the study of light elements. Further work is needed before reference values for these materials can be finalized, but the availability of this suite of materials represents a major step toward the routine analysis of the light element contents of geological specimens.