Pt/十六烷基三甲基溴化铵纳米聚集体修饰玻碳电极促进析氢(英文)

A novel, cost-effective, and simple electrocatalyst based on a Pt-modified glassy carbon electrode(GCE), using cetyltrimethylammonium bromide(CTAB) as a cationic surfactant, is reported. Amphiphilic CTAB molecules were adsorbed on GCE by immersion in a CTAB solution. The positively charged hydrophilic layer, which consisted of small aggregates of average size less than 100 nm,was used for accumulation and complexation of [PtCl2. anions by immersing the electrode in Ksolution. The modified electrode was characterized using scanning electron microscopy,energy-dispersive X-ray spectroscopy, impedance spectroscopy, and electrochemical methods. The electrocatalytic activity of the Pt particles in the hydrogen evolution reaction(HER) was investigated.The results show that the CTAB surfactant enhances the electrocatalytic activity of the Pt particles in the HER in acidic solution.     

On the development of ship anti-roll tanks

This paper reviews the development of ship anti-roll tanks from the 1880s to the present day including their modelling and control strategies. Mention is also made of other ship roll stabilization systems and the application of the technology to stabilization of other structures. The potential for the use of roll stabilization tanks on modern, high speed multi-hull craft which also have a low speed operational requirement is also discussed.     

Online GPS processing services: an initial study

There are a number of online Global Positioning System (GPS) processing services that provide GPS processing results to the user free of charge and with unlimited access. These services provide solutions for a user-submitted Receiver Independent Exchange Format (RINEX) file based on differential methods using reference stations or precise point positioning using precise GPS orbit and clock data. Different data sets varying in time and location were submitted to the online services and their results compared. Although the quality of results depends on many factors, in most cases the users can expect reliable online processing results for a 10-h data set made by a geodetic dual frequency receiver anywhere in the world.     

Watershed modeling of rainfall excess transformation into runoff

In this paper an attempt is made to present a distributed physiographic conceptual model that uses the principles of flow continuity and momentum. For this purpose, the watershed under study is divided into subwatersheds keeping in view the drainage patterns and characteristics. Then the main tributaries are identified and their drainage areas are delineated to form tributary subwatersheds. The main channel subwatersheds have taken care of the remaining area in the vicinity of the main channel. The kinematic wave theory is applied for the overland runoff computations from these subwatersheds. Further, the overland flows are superimposed onto the main channel. The dynamic wave theory is used to route the flows through the main channel to compute the watershed responses at the outlet. The proposed model is tested onto a natural watershed. The computations were performed for few storm events. Comparison of the significant parameters of the computed and the observed hydrographs shows that the maximum relative error in prediction is 5.8%. Thus, the results are satisfactory. Better results can be obtained when measured rainfall-excess data are available or a more realistic loss index is adopted for rainfall-excess separation.     

Nouvelles données structurales et datations 40K–40Ar sur les roches métamorphiques de la région de Neyriz (zone de Sanandaj–Sirjan,Iran méridional). Leur intérêt dans le cadre du domaine néo-téthysien du Moyen-Orient

The metamorphic rocks of the Neyriz area (Sanandaj–Sirjan zone) represent a Palaeozoic sequence, the upper part of which being palaeontologically dated from the Carboniferous and the Permian. Field structural analysis of the whole sequence, detailed in laboratory by microstructural one and ⁴⁰K–⁴⁰Ar dating carried on separated minerals, lead to establish that the whole sequence, from gneisses to Permian rocks, has suffered a unique synmetamorphic deformation, of variable intensity, marked by a foliation. Isotopic ages measured on extracted amphiboles and micas, clustered in four groups between 300 and 60 Ma, show the successive stages of their slow exhumation, which ended by the end of the Cretaceous. To cite this article: R. Sheikholeslami et al., C. R. Geoscience 335 (2003).     

Application of Geographic Information Systems to Analyses and Modeling of Hydrocarbons Anomaly in Yakla,North Tarim Basin,Xinjiang,China

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Precision rectification of high resolution satellite imagery without ephemeris data

The huge capability of high resolution satellite imageries (HRSI), that includes spatial, spectral, temporal and radiometric resolutions as well as stereoscopic vision introduces them as a powerful new source for the Photogrammetry, Remote Sensing and GIS communities. High resolution data increases the need for higher accuracy of data modeling. The satellite orbit, position, attitude angles and interior orientation parameters have to be adjusted in the geometrical model to achieve optimal accuracy with the use of a minimum number of Ground Control Points (GCPs). But most high resolution satellite vendors do not intend to publish their sensor models and ephemeris data. There is consequently a need for a range of alternative, practical approaches for extracting accurate 2D and 3D terrain information from HRSI. The flexibility and good accuracy of the alternative models demonstrated with KFA-1000 and the well-known SPOT level 1A images. A block of eight KFA-1000 space photos in two strips with 60% longitudinal overlap and 15% lateral sidelap and SPOT image with rational function, DLT, 2D projective, polynomials, affine, conformal, multiquadric and finite element methods were used in the test. The test areas cover parts of South and West of Iran. Considering the quality of GCPs, the best result was found with the DLT method with a RMSE of 8.44 m for the KFA-1000 space photos.     

Environmental characterization of a karst polje: an example from Izeh polje,southwest Iran

Groundwater contamination is a well-known phenomenon, which occurs on local and regional scales in Izeh polje. The aims of this paper are investigation of the impact of human activities on the polje ecosystem, determination of the vulnerability of ground water, and to solve environmental problems. Nitrate contamination of groundwater in the Izeh polje was predicted using a solute transport model. The nitrate concentration in groundwater in most parts of Izeh polje is greater than maximum concentration permissible for drinking water, i.e., 45 mg/l. The main source of nitrate in the eastern underground areas of Izeh city is the domestic sewage. Bacterial pollution of shallow ground water in Izeh polje is severe and widespread. About 45% of ground water samples in May and September 2001 have positive MPN coliforms. Infiltration of polluted surface waters and decrease of water table depth, have lead to bacterial pollution of 80% of ground water samples in January 2002. The northeast, south and southwest areas of Izeh polje have higher pollution potential rather than its middle parts. The aquifer vulnerability indices in the middle, eastern, and northern parts of the polje are moderately lower as a result of decreased sediment size of the aquifer. The pollution in the polje depends on the amount and presence of pollutants. If they do exist, the possibility of pollution is considerable due to the coarseness of materials and shallow depth of groundwater table.     

Evaluation of total load sediment transport formulas using ANN

The calculated results from various sediment transport formulas often differ from each other and from measured data. Some parameters in the sediment transport formulas are more effective than others to estimate total sediment load. In this study, an Artificial Neural Network （ANN） model is trained using four dominant parameters of sediment transport formulas. ANN models are able to reveal hidden laws of natural phenomena such as sediment transport process. The results of ANN and some total bed material load sediment transport formulas have been compared to indicate the importance of variables which can be used in developing sediment transport formulas. To train ANN, average flow velocity, water surface slopes, average flow depth, and median particle diameter are used as dominant parameters to estimate total bed material load. Two hundreds and fifty samples are used to train the ANN model. Twenty-four sets of field data not used in the training nor calibration of ANN are used to compare or verify the accuracy of ANN and some well-known total bed material load formulas. The test results show that the ANN model developed in this study using minimum number of dominant factors is a reliable and uncomplicated method to predict total sediment transport rate or total bed material load transport rate. Results show that the accuracy of formulas in descending order are those by Yang （1973）, Laursen （1958）, Engelund and Hansen （1972）, Ackers and White （1973）, and Toffaleti （1969）. These results are similar to those made by ASCE （1982） based on laboratory and field data not used in this paper. Study results also show that the formulas based on physical laws of sediment transport, like those formulas that were developed based on power concept, are more accurate than other formulas for estimating total bed material sediment load in rivers.