Influence of hydrogeochemical processes on temporal changes in groundwater quality in a part of Nalgonda district, Andhra Pradesh, India

Geochemical processes that take place in the aquifer have played a major role in spatial and temporal variations of groundwater quality. This study was carried out with an objective of identifying the hydrogeochemical processes that controls the groundwater quality in a weathered hard rock aquifer in a part of Nalgonda district, Andhra Pradesh, India. Groundwater samples were collected from 45 wells once every 2 months from March 2008 to September 2009. Chemical parameters of groundwater such as groundwater level, EC and pH were measured insitu. The major ion concentrations such as Ca²⁺, Mg²⁺, Na⁺, K⁺, Cl⁻, and SO₄ ²⁻ were analyzed using ion chromatograph. CO₃ ⁻ and HCO₃ ⁻ concentration was determined by acid–base titration. The abundance of major cation concentration in groundwater is as Na⁺ > Ca²⁺ > Mg²⁺ > K⁺ while that of anions is HCO₃ ⁻ > SO₄ ²⁻ > Cl⁻ > CO₃ ⁻. Ca–HCO₃, Na–Cl, Ca–Na–HCO₃ and Ca–Mg–Cl are the dominant groundwater types in this area. Relation between temporal variation in groundwater level and saturation index of minerals reveals the evaporation process. The ion-exchange process controls the concentration of ions such as calcium, magnesium and sodium. The ionic ratio of Ca/Mg explains the contribution of calcite and dolomite to groundwater. In general, the geochemical processes and temporal variation of groundwater in this area are influenced by evaporation processes, ion exchange and dissolution of minerals.     

Effect of co-operative fuzzy c-means clustering on estimates of three parameters AVA inversion

We determine the degree of variation of model fitness, to a true model based on amplitude variation with angle (AVA) methodology for a synthetic gas hydrate model, using co-operative fuzzy c-means clustering, constrained to a rock physics model. When a homogeneous starting model is used, with only traditional least squares optimization scheme for inversion, the variance of the parameters is found to be comparatively high. In this co-operative methodology, the output from the least squares inversion is fed as an input to the fuzzy scheme. Tests with co-operative inversion using fuzzy c-means with damped least squares technique and constraints derived from empirical relationship based on rock properties model show improved stability, model fitness and variance for all the three parameters in comparison with the standard inversion alone.     

Possible solar control on primary production along the Indian west coast on decadal to centennial timescale

Using multiple geochemical proxies including specific biomarkers (dinosterol, phytol, stigmasterol and β‐sitosterol) measured in a high‐sedimentation rate core collected from the inner shelf (depth ～45 m) off Goa (India), we reconstruct surface productivity, which is mainly controlled by the monsoon upwelling in this region, during the last ca. 700 a. Surface productivity appears to have varied in tandem with the Konkan–Goa rainfall and sunspot activity during the instrumental period (last 250 a). The productivity proxies also covary with the total solar irradiance reconstructed for the period beyond the instrumental era, within the considerable uncertainty of the age model. This suggests that solar forcing may control coastal upwelling intensity and biological productivity in the eastern Arabian Sea on decadal to centennial timescales. During the late Anthropocene (last ca. 50 a), steep increases in all four biomarkers indicate greatly enhanced productivity in response to high solar irradiance as well as anthropogenic inputs of nutrients. Copyright © 2008 John Wiley & Sons, Ltd.     

Propagation Characteristics and Generation Mechanism of ELF/VLF Hiss Observed at Low-latitude Ground Station (L = 1.17)

Extremely low frequency (ELF)/Very low frequency (VLF) hiss is whistler mode wave that interacts with energetic electrons in the magnetosphere. The characteristics features of ELF/VLF hiss observed at low latitude ground station Jammu (Geomag. lat. 22°16′ N, L=1.17) are reported. It is observed that most of hiss events first propagate in ducted mode along higher L-values (L = 4–5), after reaching lower edge of ionosphere excite the Earth-ionosphere waveguide and propagate towards equator to be received at low-latitude station Jammu. To understand the generation mechanism of ELF/VLF hiss, incoherent Cerenkov radiated power from the low-latitude and mid-latitude plasmasphere are evaluated. Considering this estimated power as an input for wave amplification through wave–particle interaction, the growth rate and amplification factor is evaluated which is too small to explain the observed wave intensity. It is suggested that some non-linear mechanism is responsible for the generation of ELF/VLF hiss.     

Four-dimensional structure and sub-seasonal regulation of the Indian summer monsoon multi-decadal mode

A better understanding of the drivers and teleconnection mechanisms responsible for the multi decadal mode (MDM) of variability of the Indian summer monsoon rainfall (ISMR) with major socio-economic impacts in the region through clustering of large-scale floods or droughts is key to improving the poor simulation of ISMR MDM by most climate models. Here, using the longest instrumental record of ISMR available (1813–2006) and longest atmospheric and oceanic re-analyses, the global four dimensional (space–time) structures of atmospheric and oceanic fields of the multi-decadal mode of ISMR and sub-seasonal evolution of the teleconnection mechanism are brought out, essential for understanding underlying drivers but lacking so far. The relationships between the spatial structure of winds, Sea Surface Temperature (SST) and thermocline depth with the ISMR MDM indicate that the tropical ocean over the Indo-Pacific domain is passive responding primarily to the surface winds associated with the mode. A close association between the Atlantic Meridional Overturning Circulation (AMOC), north Atlantic (NA) SST, NA sea surface salinity (SSS) and the ISMR MDM indicate a slow oceanic pathway linking NA SST and the ISMR. In addition to strong correlation (~ 0.9) between global spatial patterns of JJAS SST associated with the MDMs of ISMR, NA SST and AMOC, strong temporal coherence (correlations ~ 0.9) between them is suggestive of regulation of the ISMR MDM (T ~ 65-years) by the NA SST associated with the Atlantic Multidecadal Oscillation (AMO) through a ‘fast’ atmospheric bridge. On a seasonal time scale, the atmospheric bridge manifests in the form of a stationary Rossby wave train generated by an anticyclonic (cyclonic) barotropic vorticity located above positive (negative) SST anomaly over NA in two phases of the AMO. That the AMO SST is the driver of the ISMR MDM is further supported when we unravel the sub-seasonal face of the teleconnection between the two. We show that phase locking of active (break) spells with annual cycle during positive (negative) phases of the ISMR MDM are forced by a similar phase locking of barotropic anticyclonic (cyclonic) vorticity over the NA SST with the annual cycle through the generation of a quasi-stationary Rossby wave train with an anticyclonic (cyclonic) vorticity at upper level over the Indian region with the NA columnar vorticity leading Indian monsoon rainfall by about a week. Our findings provide a basis for enhanced predictability of tropical climate through slow modulation by extra-tropical SST.

     

Assessment of seawater mixing in a coastal aquifer by high resolution electrical resistivity tomography

Seawater intrusion is a major problem in urbanized coastal regions of India which is due to over exploitation of groundwater for various purposes. This study was carried out with the objective of assessing the zone of mixing between seawater and groundwater in the coastal aquifer in south of Chennai, Tamil Nadu, India using high resolution electrical resistivity tomography. High resolution electrical resistivity tomography was carried out in five profiles perpendicular to the sea using IRIS make SYSCAL Pro-96 system with 2.5 m or 5 m inter-electrode separation. The maximum length of the profile was 170 m which resulted in a depth of investigation of 28.7 m. The apparent resistivity measured in this area varies from 0.3 ohm-m to 30,000 ohm-m. The apparent resistivity of saturated zone decreases towards the sea, indicating the influence of seawater. This was also confirmed by measuring the electrical conductivity of groundwater, which gradually increases from 156 μS/cm to 3430 μS/cm towards the sea. Further, the concentration profiles of electrical conductivity, sodium, chloride and chloride / bicarbonate ratio are compared with the high resolution electrical resistivity tomography profile. The distance of influence of seawater is comparatively high in northern part than in southern part of the area. The high resolution electrical resistivity tomography was effectively used to determine the effect of seawater mixing with groundwater.     

Biological stabilization of mine dumps: shear strength and numerical simulation approach with special reference to Sisam tree

The stability of mine waste dump is very important for an economic and safety point of view. The biological method is the most popular and eco-friendly approach to stabilize the mine waste dump in the long term. Trees outclass grasses and shrubs for long term stability as the roots of trees are stronger and penetrate deeper. Their roots bind the dump material and form a composite material having high shear strength. The mechanics of stabilization by tress have yet not been fully understood. Moreover, one always refers to biological stabilization of slope qualitatively rather than quantitatively. A numerical simulation tool has been used in the present paper to assess the increased factor of safety of a vegetated dump slope. The Sisam tree was chosen for the present study as it is commonly available in northern India, needs little care and has high economic value. The increased shear strength of the dump mass having tree roots was calculated by shear box test. The tree roots occupy large space, hence, a large size shear box (1.5 m × 1.5 m × 0.75 m) has specifically been designed and fabricated for determining the shear strength of dump root matrix. A small size shear box (0.30 m × 0.30 m × 0.15 m) has also been designed and fabricated to determine the increased shear strength due to small trees. It was observed that the Sisam tree of even moderate size binds the upper layers of mine dump and improve the factor of safety substantially. It was also observed that the stability of dump slope improves with time (i.e. size of tree).     

Gas-hydrate stability thickness map along the Indian continental margin

The gas-hydrate stability thickness (GHST) map along the Indian continental margin is prepared from available bathymetry, sea-bottom temperature and geothermal gradient data. The bottom-simulating reflector (BSR) often marks the base of gas-hydrate stability zone. The prior information about the stability thickness in a particular area will help in identifying BSR on seismic data. The map is also useful to the exploration scientists to set a depth window within which proxies for gas-hydrate can be looked into. A GHST map was initially prepared in 1998 based on the-then available data. A lot of new data has been generated by various organizations under the Indian National Gas Hydrate Programs for the advancement of exploration and exploitation activities. By incorporating the new data from the published and available documents, we have modified the GHST map along the Indian margin. Besides filling the data gap, the new map shows the gas-hydrate stability zone in the Andaman offshore. In addition, we show maps of sea-bottom temperature, sediment thickness, geothermal gradient and heat flow to provide a bird’s eye view of these parameters along the continental margin of India.     

Interplanetary turbulences causing unusual anisotropic wave trains in cosmic rays

The various observed harmonics of the cosmic ray variation may be understood on a unified basis if the free space cosmic ray anisotropy is non-sinusoidal in form. The major objective of this paper is to study the first three harmonics of high amplitude wave trains of cosmic ray intensity over the period 1991–1994 for Deep River Neutron Monitoring Station. The main characteristic of these events is that the high amplitude wave trains shows a maximum intensity of diurnal component in a direction earlier than 1800 Hr/co-rotational direction. It is noticed that these events are not caused either by the high-speed solar wind streams or by the sources on the Sun responsible for producing these streams such as polar coronal holes. The direction of semi-diurnal anisotropy shows negative correlation with Bz. The occurrence of high amplitude events is dominant for the positive polarity of Bz component of IMF. The diurnal amplitude of these events shows a negative and the time of maximum shows a weak correlation with disturbance storm time index Dst. The direction of tri-diurnal anisotropy of these events is found to significantly correlate with geomagnetic activity index Ap.