Surface and deep water response to rapid climate changes at the Western Iberian Margin

Rapid climate changes at the onset of the last deglaciation and during Heinrich Event H4 were studied in detail at IMAGES cores MD95-2039 and MD95-2040 from the Western Iberian margin. A major reorganisation of surface water hydrography, benthic foraminiferal community structure, and deepwater isotopic composition commenced already 540 years before the Last Isotopic Maximum (LIM) at 17.43 cal. ka and within 670 years affected all environments. Changes were initiated by meltwater spill in the Nordic Seas and northern North Atlantic that commenced 100 years before concomitant changes were felt off western Iberia. Benthic foraminiferal associations record the drawdown of deepwater oxygenation during meltwater and subsequent Heinrich Events H1 and H4 with a bloom of dysoxic species. At a water depth of 3380 m, benthic oxygen isotopes depict the influence of brines from sea ice formation during ice-rafting pulses and meltwater spill. The brines conceivably were a source of ventilation and provided oxygen to the deeper water masses. Some if not most of the lower deep water came from the South Atlantic. Benthic foraminiferal assemblages display a multi-centennial, approximately 300-year periodicity of oxygen supply at 2470-m water depth. This pattern suggests a probable influence of atmospheric oscillations on the thermohaline convection with frequencies similar to Holocene climate variations. For Heinrich Events H1 and H4, response times of surface water properties off western Iberia to meltwater injection to the Nordic Seas were extremely short, in the range of a few decades only. The ensuing reduction of deepwater ventilation commenced within 500–600 years after the first onset of meltwater spill. These fast temporal responses lend credence to numerical simulations that indicate ocean–climate responses on similar and even faster time scales.     

Recombination of electrons with H3+ and H5+ ions

The dissociative recombination coefficients α for capture of electrons by H₃⁺ and H₅⁺ ions have been determined as a function of electron temperature T_e using a microwave afterglow-mass spectrometer apparatus. At ion and neutral temperatures T_u+ = T_n = 240 K, the coefficient α (H₃⁺) is found to vary slowly with T_e at first, decreasing from 1.6 × 10^?7 cm³/s at T_e = 240 K to 1.2 × 10^?7 cm³/s at T_e = 500 K, thereafter falling as T_e^?1 over the range 500 K ? T_e, ? 3000 K. These results, which have a ± 20% uncertainty, agree satisfactorily over the common energy range (0.03–0.36 eV) with the recombination cross sections determined in merged beam measurements by Auerbach et al. At T₊ = T_n = 128 K, the coefficient α(H₅⁺) is found to be (1.8 ± 0.3) × 10^?6 [T_e(K)/300]^?0.69 cm³/s over the range 128 K ? T_e ? 3000 K, with a more rapid decrease, as T_e^?1, between 3000 K and 5500 K. The implications of these results for modelling planetary atmospheres and interstellar clouds are briefly touched on.     

Recent trends of urban development and town planning in Spain

With the socio-economic change from rural to industrial, Spain has experienced an enormous urbanisation boom during the last 20 years. This has produced a concentration of high-rise apartment blocks not only in the big cities but also in medium-sized towns and even within the medieval town centres. More astonishing, compared with Central Europe, seems however, the spatial distribution of the social classes which, with a centre-periphery gradient, still corresponds to the model of the pre-industrial town. The paper investigates the impact of town planning, house building policy, and behavioural aspects on these structural patterns.     

Lithium, boron and chlorine as tracers for metasomatism in high-pressure metamorphic rocks: a case study from Syros (Greece)

High-pressure metamorphic (HPM) rocks (derived from igneous protoliths) and their metasomatised rinds from the island of Syros (Greece) were analysed for their B and Cl whole-rock abundances and their H₂O content by prompt-gamma neutron-activation analysis (PGNAA) and for their Li and Be whole-rock abundances by ICP-OES. In the HPM rocks, B?/Be and Cl?/Be ratios correlate with H₂O contents and appear to be controlled by extraction of B and Cl during dehydration and prograde metamorphism. In contrast, samples of the metasomatised rinds show no such correlation. B?/Be ratios in the rinds are solely governed by the presence or absence of tourmaline, and Cl?/Be ratios vary significantly, possibly related to fluid inclusions. Li/Be ratios do not correlate with H₂O contents in the HPM rocks, which may in part be explained by a conservative behaviour of Li during dehydration. However, Li abundances exceed the vast majority of published values for Li abundances in fresh, altered, or differentiated oceanic igneous rocks and presumably result from metasomatic enrichment of Li. High Li concentrations and highly elevated Li/Be ratios in most metasomatised samples demonstrate an enrichment of Li in the Syros HP mélange during fluid infiltration. This study suggests that B and Cl abundances of HPM meta-igneous rocks can be used to trace prograde dehydration, while Li concentrations seem to be more sensitive for retrograde metasomatic processes in such lithologies.     

Are C1 chondrites chemically fractionated? a trace element study

Six C1 chondrite samples and a C2 xenolith from the Plainview H5 chondrite were analyzed by radiochemical neutron activation for the elements Ag, Au, Bi, Br, Cd, Ce, Cs, Eu, Ge, In, Ir, Lu, Nd, Ni, Os, Pd, Pt, Rb, Re, Sb, Se, Sn, Tb, Te, Tl, Yb, and Zn. The data were combined with 9 earlier analyses from this laboratory and examined for evidence of chemical fractionation in C1 chondrites.A number of elements (Br, Rb, Cs, Au, Re, Os, Ni, Pd, Sb, Bi, In, Te) show small but correlated variations. Those of the first 8 probably reflect hydrothermal alteration in the meteorite parent body, whereas those of Sb, Bi, In, and Te may at least in part involve nebular processes. Br and Au show systematic abundance differences from meteorite to meteorite, which suggests hydrothermal transport on a kilometer scale. The remaining elements vary from sample to sample, suggesting transport on a centimeter scale.There is no conclusive evidence for nebular fractionation affecting C1 's. Though C1 chondrites have lower $\text{Zr}\text{Hf}$ and $\text{Ir}\text{Re}$ ratios than do other chondrite classes, these ratios vary in other classes, suggesting that those classes rather than C1's are fractionated. Three fractionation-prone REE—Ce, Eu, and Yb have essentially the same relative abundances in C1's and all other chondrite classes, and hence apparently are not fractionated in C1's. We did not confirm the large Tb and Yb variations in C1's reported by other workers.We present revised mean C1 abundances for 35 elements, based on the new data and a critical selection of literature data. Changes are generally less than 10%, except for Br, Rb, Ag, Sb, Te, Au, and the REE.The Plainview C2 xenolith has normal trace element abundances, except for 3 elements falling appreciably above the C2 range: Rb, Cs, and Bi. Hydrothermal alteration may be the reason for all 3, though nebular fractionation remains a possibility for Bi.     

Alpine overdeepenings and paleo-ice flow changes: an integrated geophysical-sedimentological case study from Tyrol (Austria)

We present a study of the inneralpine basin of Hopfgarten focused on the analysis of basin fill in order to reveal its formation in relation to paleo-ice flow and tectonics. The study is based on geological mapping as well as seismic (reflection and refraction) and geoelectrical surveys. The oldest sequence in the basin, identified by seismic stratigraphy at 400 m below surface, consists of coarse grained sediments of supposedly Oligocene to Miocene age, which subsided along faults linked to the Inn fault. Three superimposed sequences, each displaying baselaps in contact with a subglacially formed unconformity and sigmoid foresets, show pleniglacial conditions followed by a glaciolacustrine environment. The uppermost of these three sequences lies on top of last glacial maximum till (LGM; Würmian Pleniglacial; MIS 2) and represents Termination I. The middle sequence is classified as Termination II following the Rissian Pleniglacial (MIS 6). The oldest glacial sequence cannot be constrained chronostratigraphically but might correlate with Termination V following the major glaciation of MIS 12. Limited glacial erosion during the LGM occurred only during the ice build-up phase. Further overdeepening was impeded due to topographic barrier and mutual blockades of glaciers within this highly dissected landscape. The occurrence and relative timing of the impediment was controlled by the onset of transfluences and thus by the altitude of coles. The higher amount of overdeepening during older glacial periods is explained by longer phases of free ice advance in the ice build up phase due to higher transfluences routes at that time. Thus, the preservation of older Pleistocene sequences within the basin may be the result of the lowering of watersheds from one glaciation to the next. Our model of an inverse relationship between glacial shaping of the surface and the subsurface may apply to similar Alpine landscapes as well.     

Nitrogen isotopes in the recent solar wind from the analysis of Genesis targets: Evidence for large scale isotope heterogeneity in the early solar system

We have analyzed nitrogen, neon and argon abundances and isotopic ratios in target material exposed in space for 27 months to solar wind (SW) irradiation during the Genesis mission. SW ions were extracted by sequential UV (193 nm) laser ablation of gold-plated material, purified separately in a dedicated line, and analyzed by gas source static mass spectrometry. We analyzed gold-covered stainless steel pieces from the Concentrator, a device that concentrated SW ions by a factor of up to 50. Despite extensive terrestrial N contamination, we could identify a non-terrestrial, ¹⁵N-depleted nitrogen end-member that points to a 40% depletion of ¹⁵N in solar-wind N relative to inner planets and meteorites, and define a composition for the present-day Sun (¹⁵N/¹⁴N = [2.26 ± 0.67] × 10⁻³, 2σ), which is indistinguishable from that of Jupiter’s atmosphere. These results indicate that the isotopic composition of nitrogen in the outer convective zone of the Sun has not changed through time, and is representative of the protosolar nebula. Large ¹⁵N enrichments due to e.g., irradiation, low temperature isotopic exchange, or contributions from ¹⁵N-rich presolar components, are therefore required to account for inner planet values.     

Low-grade metamorphic rocks from the Pulur complex,NE Turkey: implications for the pre-Liassic evolution of the Eastern Pontides

In the Pulur complex (Sakarya Zone, Eastern Pontides, Turkey) a low-grade tectonometamorphic unit (Doankavak) is exposed in three tectonic windows beneath a complex medium-pressure high-temperature metamorphic unit of late Carboniferous age. The thrust plane between both units is transgressively covered by Liassic conglomerates. The Doankavak unit comprises a sequence of metabasites with MORB-type chemical compositions and phyllites, with subordinate calcareous phyllites, marbles, quarzofeldspathic schists and metacherts. This sequence is interpreted as a former accretionary complex related to the consumption of the Palaeotethys. Mineral parageneses in the metabasites allow for the distinction of two domains with slightly different peak metamorphic conditions, i.e. 375–425 °C/0.5–0.8 GPa (greenschist facies) and 400–470 °C/0.6–1.1 GPa (albite-epidote amphibolite facies). The age of metamorphism is constrained at ~ 260 Ma (early Late Permian) by two Rb-Sr mineral-whole rock ages (hornblende, phengite) and one ⁴⁰Ar/³⁹Ar single step total fusion age (phengite). In conjunction with previous data on other accretionary complexes in the Sakarya zone in Northern Turkey, the data presented in this study suggest a continuous subduction of the Palaeotethys at least from Early/Late Permian to Late Triassic and a discontinuous preservation of accretion complexes in both space and time.     

Thermal modeling of Carboniferous to Triassic sediments of the Karawanken Range (Southern Alps) as a tool for paleogeographic reconstructions in the Alpine–Dinaridic–Pannonian realm

Vitrinite reflectance was measured in Late Carboniferous to Triassic shales, siltstones and marls of the Karawanken Range. Thermal models of the central South-Karawanken Range were calibrated on the basis of these data. They suggest an eroded overburden of more than 3,200 m of Jurassic to Cretaceous sediments and a heat flow in the range of 42 to 60 mW m^?2 during the time of maximum subsidence. Because the reconstructed thermal history of the South-Karawanken Range is very similar to the thermal history of the Generoso basin (western Southern Alps), these data provide strong evidence for a deep basinal position of the Southern Karawanken Range during Jurassic to Cretaceous times. A vitrinite reflectance anomaly at the northern margin of the South-Karawanken Range is explained by advective heat transport during the Oligocene. The heat source for the anomalies at the western margin of the Seeberg Rise and in the area between the Periadriatic Lineament and the Donat Fault Zone is unknown. Vitrinite reflectance in Late Triassic sediments indicates the South-Karawanken Range and the South-Zala Unit of the Pannonian basement as exotic blocks in the Sava Composite Unit. This is explained by Miocene displacement of structural units, which were derived from different paleogeographical segments of the Permo-Mesozoic western Tethyan margin.     

Superdense CO2 inclusions in Cretaceous quartz–stibnite veins hosted in low-grade Variscan basement of the Western Carpathians, Slovakia

CO₂ inclusions with density up to 1,197 kg m⁻³ occur in quartz–stibnite veins hosted in the low-grade Palaeozoic basement of the Gemericum tectonic unit in the Western Carpathians. Raman microanalysis corroborated CO₂ as dominant gas species accompanied by small amounts of nitrogen (<7.3 mol%) and methane (<2.5 mol%). The superdense CO₂ phase exsolved from an aqueous bulk fluid at temperatures of 183–237°C and pressures between 1.6 and 3.5 kbar, possibly up to 4.5 kbar. Low thermal gradients (∼12–13°C km⁻¹) and the CO₂–CH₄–N₂ fluid composition rule out a genetic link with the subjacent Permian granites and indicate an external, either metamorphogenic (oxidation of siderite, dedolomitization) or lower crustal/mantle, source of the ore-forming fluids.According to microprobe U–Pb–Th dating of monazite, the stibnite-bearing veins formed during early Cretaceous thrusting of the Gemeric basement over the adjacent Veporic unit. The 15- to 18-km depth of burial estimated from the fluid inclusion trapping PT parameters indicates a 8- to 11-km-thick Upper Palaeozoic–Jurassic accretionary complex overlying the Gemeric basement and its Permo-Triassic autochthonous cover.