Holocene humidity fluctuations in Sweden inferred from dendrochronology and peat stratigraphy

Tree-ring and peat stratigraphy data were examined back to 5000 BC in order to identify and compare humidity changes in Fennoscandia. The temporal variation in distribution of Scots pine ( Pinus sylvestris L.) was used as a measure of past lake-level fluctuations in central Sweden. The chronology, which spans 2893 BC–AD 1998 with minor gaps in AD 887–907 and 1633–1650 BC and with additional floating chronologies back to 4868 BC, was cross-dated and fixed to an absolute timescale using a chronology from Torneträsk, northern Sweden. The peat stratigraphy from the Stömyren peat bog, south-central Sweden, was transformed into humification indices to evaluate humidity changes during the past 8000 years. The peat chronology is established by four tephra datings and eight ¹⁴C datings. Synchronous periods of drier conditions, interpreted from regeneration and the mortality pattern of pine, tree-ring chronology and peat humification, were recognized at c. 4900–4800 BC, 2400–2200 BC, 2100–1800 BC, 1500–1100 BC, AD 50–200, AD 400–600 and AD 1350–1500. Possible wetter periods were encountered at 3600–3400 BC, 3200–2900 BC, 2200–2100 BC, 1700–1500 BC, 1100–900 BC, 100 BC-AD 50, AD 200–400, AD 750–900 and AD 1550–1700. The wet and dry periods revealed by the tree rings and peat stratigraphy data indicate considerable humidity changes in the Holocene.     

Performance analysis of different predictive models for crop classification across an aridic to ustic area of Indian states

The purpose of this study is to present comparative performance analysis of different machine learning algorithms for large area crop classification. Ten Indian districts with significant rabi crops viz. wheat, mustard, gram, red lentils (masoor) have been selected for the study. Most popular classical ensemble models – bagging/ARCing, random forest (RF), gradient boosting and Importance Sampled Learning Ensemble (ISLE) with traditional single model (decision tree) have been selected for comparative analysis. To incorporate dependency of large area crop in different variables viz. parent material and soil, phenology, texture, topography, soil moisture, vegetation, climate etc., 35 digital layers are prepared using different satellite data (ALOS DEM, Landsat-8, MODIS NDVI, RISAT-1, Sentinental-1A) and climatic data (precipitation, temperature). In rabi season, field survey about crop type is carried out to prepare training data. Performance is evaluated on the basis of marginal rates, F-measure and Jaccard’s coefficient of community, Classification Success Index and Agreement Coefficients. Score is calculated to rank the algorithm. RF is best performer followed by gradient boosting for crop classification. Other ensemble methods ARCing, bagging and ISLE are in decreasing order of performance. Traditional non-ensemble method decision tree scored higher than ISLE.     

Progress in Remediation of Groundwater at Petroleum Sites in California

Quantifying the overall progress in remediation of contaminated groundwater has been a significant challenge. We utilized the GeoTracker database to evaluate the progress in groundwater remediation from 2001 to 2011 at over 12,000 sites in California with contaminated groundwater. This paper presents an analysis of analytical results from over 2.1 million groundwater samples representing at least $100 million in laboratory analytical costs. Overall, the evaluation of monitoring data shows a large decrease in groundwater concentrations of gasoline constituents. For benzene, half of the sites showed a decrease in concentration of 85% or more. For methyl tert‐butyl ether (MTBE), this decrease was 96% and for TBE, 87%. At remediation sites in California, the median source attenuation rate was 0.18/year for benzene and 0.36/year for MTBE, corresponding to half‐lives of 3.9 and 1.9 years, respectively. Attenuation rates were positive (i.e., decreasing concentration) for benzene at 76% of sites and for MTBE at 85% of sites. An evaluation of sites with active remediation technologies suggests differences in technology effectiveness. The median attenuation rates for benzene and MTBE are higher at sites with soil vapor extraction or air sparging compared with sites without these technologies. In contrast, there was little difference in attenuation rates at sites with or without soil excavation, dual phase extraction, or in situ enhanced biodegradation. The evaluation of remediation technologies, however, did not evaluate whether specific systems were well designed or implemented and did not control for potential differences in other site factors, such as soil type.     

Sedimentation of particulate matter in the Dona Paula Bay, West Coast of India during November to May 1995–1997

Data on hydrography, nutrients, suspended particles, and sedimented particles were collected at weekly intervals from November to May during 1995 to 1997 at a station in the coastal waters of Dona Paula Bay, India. Suspended and sedimented particles were analyzed for total suspended matter (SPM), total sedimented particulate matter (TPM), particulate organic carbon (POC), particulate organic nitrogen (PON), chlorophylla (chla), and diatom abundance. Variations in hydrography and nutrients influenced the quantity and composition of sedimented particles. The TPM, POC, PON, and chla fluxes showed small-scale seasonal variations and were higher in the summer (February to May) than in the winter (November to January). Resuspension of carbon accounted for approximately 25% of the gross POC and was highest in April 1997 (45%). The mean net POC flux was 197±90 mg C m⁻² d⁻¹ and accounts for 4.6% of the TPM. The average C∶N (w∶w) ratio of the sedimented material was 13.2±6.6. The POC:chla ratio was relatively higher in the sedimented material as compared to the suspended material. The particulate carbon reaching the bottom sediment was 39% of the primary production. The low organic carbon concentration (approximately 0.1% of dry sediment) in the sediments implies that about 98% of the sedimented carbon was either consumed at the sedimentwater interface or resuspended/advected before it was finally buried into the sediments.     

Biopolymer-Based Nanocomposites for Removal of Cr(VI) from Aqueous Systems: A Review

Hexavalent chromium Cr(VI) has emerged as a contaminant of prime concern for the environmentalists because of its improper disposal by tannery, dye, and electroplating industries. Adsorption is the most exploited method for its removal from industrial wastewater because of its high removal efficiency even at low Cr(VI) concentration, minimal sludge, and ease of regeneration. In recent years, several adsorbents of biological origin such as plants, algae, fungi, and bacteria have been explored for Cr(VI) remediation. This review comprehends the recent studies involving usage of biopolymer-based nano-composites with respect to its adsorption mechanisms, adsorption capacities, isotherms, and kinetics. The conventional abiotic and biotic techniques for removal of Cr(VI) are also discussed with a comparative insight of their adsorption capacity and removal efficiency. Nano-biocomposites integrate the functional properties of both nanoparticles and biopolymers, which make them efficient biosorbents. Nano-biocomposites offer a large surface area, reduced particle loss, minimal particle agglomeration on the surface, and high stability. Common kinetic models among the nano-biocomposites,  and various equilibrium models are also analyzed to understand the mode of adsorption and associated factors. These materials are mostly found to follow monolayer adsorption with ion exchange, electrostatic interaction, and surface complexation as major players in the process.     

Field monitoring of suction in the vicinity of an urban tree: exploring termite infestation and the shading effects of tree canopy

Acta Geotechnica - The objective of this short communication is to explore spatial distribution of soil suction in the vicinity of an urban tree considering effects of termite infestation and also...     

Distribution of butyltins in the waters and sediments along the coast of India

Water and surface sediment samples were analyzed for butyltins (TBT, DBT, MBT) from various ports along the east and west coast of India. The total butyltin (TB) in water samples varied between ∼1.7 and 342 ng Sn l⁻¹, whereas for sediments it varied between below detection limit to 14861 ng Sn g⁻¹ dry weight of sediment. On an average Chennai port recorded the highest level of butyltins in the sediments while Paradip recorded the highest level of butylins in the waters. A fairly good relationship between the TB in the sediment and overlying water samples, as well as between organic carbon and TB, implicates the importance of adsorption/desorption process in controlling the levels of TBT in these port areas. In India the data on organotin pollution is very sparse; most of the port areas have been surveyed for butyltins for the first time during this study.     

Snow Cover Area Mapping Using Synthetic Aperture Radar in Manali Watershed of Beas River in the Northwest Himalayas

The current study has used Synthetic Aperture Radar (SAR) satellite data to estimate the Snow Cover Area (SCA) in Manali watershed of Beas River in Northwest Himalayas of Himachal Pradesh, India. SAR data used in this study is of Radarsat-2 (RS2) and Environmental Satellite (ENVISAT), Advanced Synthetic Aperture Radar (ASAR). The SAR preprocessing was done with SAR image processing tools for converting raw SAR images into calibrated geo-coded backscatter images. Maps for forest, built area, layover and shadow were created and used for masking snow cover in these areas. The backscattering ratio of wet snow to reference image threshold method with value range from ?2 to ?3 db was used to estimate wet SCA for study area. In this technique, if the threshold is too high (≥-2 db) wet SCA is overestimated and if it is too low (≤-3db), this method underestimates the SCA. The wet SCA is under/over estimated (+6 % to?8 % on average) in late spring season due to the inherent terrain and SAR imaging effects of layover/foreshortening and shadow and also due to the masking of forest areas. Overall, the SCA derived from SAR data matches well when compared with total SCA derived from cloud free optical remote sensing data products, especially during wet season.     

Deglaciation history of the southwestern Fennoscandian Ice Sheet between 15 and 13 14C ka BP

Analysis of 2D and 3D seismic records from the continental shelf off western Norway, in combination with chronological constraints from ¹⁴C dates, has led to a model for the glacial development in these shelf areas between c. 15 and 13 ¹⁴C ka BP. On the shallow Måløy Plateau adjacent to the Norwegian Channel, iceberg scours are preserved below a prominent moraine ridge, which by correlation to the Norwegian Channel indicate ice retreat at c. 15 ¹⁴C ka BP. Subsequently, the ice advanced across the scoured surface and deposited a till sheet before stabilizing to deposit a prominent moraine, termed the Bremanger Moraine. Based on location on the shelf, seismic stratigraphy, morphology and C dates the Bremanger Moraine is correlated with a significant moraine on the continental shelf off Trøndelag. We suggest that these features are products of a regional glacial event, the Bremanger Event, dated to <15–13.3 ¹⁴C ka BP. The Bremanger Event is probably a result of the deteriorating climatic conditions in the NE Atlantic during Heinrich event 1.     

Climate and environment on the Karelian Isthmus, northwestern Russia, 13000-9000 cal. yrs BP

Sediment sequences retrieved from Lake Medvedevskoye (60°13'N; 29°54'E) and Lake Pastorskoye (60°13'N; 30°02'E), Karelian Isthmus, northwestern Russia, were analysed for lithology, pollen and diatom stratigraphy, total organic carbon content and mineral magnetic parameters. Age control for both sequences was provided by AMS ¹⁴C measurements and the Vedde Ash tephra. The reconstructed climatic and environmental development shows the deglaciation of the sites and the establishment of sparse shrub and herb/grass vegetation before 12650 cal. yrs BP ('Allerød'; GI-1a). Steppe tundra and cold, dry conditions prevailed until about 11000 cal. yrs BP, i.e. throughout the 'Younger Dryas' (GS-1) and the earliest Holocene. The establishment of open Picea-Pinus-Betula forest around the lakes at about 11 000 cal. yrs BP coincides with the first distinct change towards gradually warmer and more humid climatic conditions. Boreal forest with Picea, Pinus, Betula, Alnus incana and Corylus was present at the lower altitude site between c. 10700 and 10200 cal. yrs BP, while open Betula-Pinus forest continued to dominate the vegetation around the higher altitude site. After a short, possibly colder, phase around 10200-10000 cal. yrs BP, which is expressed by a marked reduction in vegetation cover and decreased lake productivity, climatic conditions became significantly warmer and possibly more humid. Boreal forest with Pinus, Betula, Picea, Alnus incana, Corylus and Ulmus became widespread in the region after 10000 cal. yrs BP. The delayed environmental response of the lakes and their catchment to hemispheric warming at the Pleistocene/Holocene boundary may be explained by a sustained blocking of westerly air masses due to the presence of the Scandinavian ice sheet and associated strengthened easterlies and anticy-clonic circulation and/or extensive permafrost.