Composition and petrology of HED polymict breccias: The regolith of (4) Vesta

We have done petrologic and compositional studies on a suite of polymict eucrites and howardites to better understand regolith processes on their parent asteroid, which we accept is (4) Vesta. Taking into account noble gas results from companion studies, we interpret five howardites to represent breccias assembled from the true regolith: Elephant Moraine (EET) 87513, Grosvenor Mountains (GRO) 95535, GRO 95602, Lewis Cliff (LEW) 85313, and Meteorite Hills (MET) 00423. We suggest that EET 87503 is paired with EET 87513, and thus is also regolithic. Pecora Escarpment (PCA) 02066 is dominated by melt‐matrix clasts, which may have been formed from true regolith by impact melting. These meteorites display a range in eucrite:diogenite mixing ratio from 55:45 to 76:24. There is no correlation between degree of regolith character and Ni content. The Ni contents of howardite, eucrite, and diogenites (HEDs) are mostly controlled by the distribution of coarse chondritic clasts and metal grains, which in some cases resulted from individual, low‐velocity accretion events, rather than extensive regolith gardening. Trace element compositions indicate that the mafic component of HED polymict breccias is mostly basalt similar to main‐group eucrites; Stannern‐trend basaltic debris is less common. Pyroxene compositions show that some trace element‐rich howardites contain abundant debris from evolved basalts, and that cumulate gabbro debris is present in some breccias. The scale of heterogeneity varies considerably; regolithic howardite EET 87513 is more homogeneous than fragmental howardite Queen Alexandra Range (QUE) 97001. Individual samples of a given howardite can have different compositions even at roughly 5 g masses, indicating that obtaining representative meteorite compositions requires multiple or large samples.     

Phytoplankton diversity and chlorophyll-A in a polluted estuary

The quantity of phytoplankton in Newark Bay, New Jersey as indicated by chlorophyll-a content of the water, is low in the winter and early spring, and fluctuates greatly during the spring and summer. Chlorophyll-a concentrations are generally less than 20 μg/l until April. Between April and August, three phytoplankton blooms were indicated by chlorophyll-a concentrations as high as 81.4 μg/l. Net phytoplankton diversity values indicated generally eutrophic conditions; however, there was no significant correlation between diversity and chlorophyll-a concentrations. A role of nannoplankton in blooms is indicated.     

Petroleum hydrocarbon contamination of ground water in Tiverton,Rhode Island,USA

Ground water samples from several private wells serving individual homes in Tiverton, Rhode Island were analyzed for petroleum contamination over a 19-month period. The hydrocarbon concentrations initially ranged from 68 to 2350 ppb and then gradually decreased to lower values, ranging from 6 to 1650 ppb, at the end of the study. Samples from the well with the highest hydrocarbon concentration (2350 to 1650 ppb) were investigated in some detail because this was considered a possible source of the petroleum contamination in the area. These studies indicated that most of the hydrocarbons were in the dissolved phase (<1.0 μm) of the ground water and that it contained large amounts of naphthalene, methyl and dimethyl naphthalenes, and ethyl naphthalenes. In addition, the qualitative distribution of hydrocarbons changed as the concentration decreased over the course of the investigation. There appeared to be preferential loss of the more volatile and easily degraded components relative to the higher molecular weight and more refractory hydrocarbons. Some of the wells at this location are contaminated with at least two different petroleum products, i.e. gasoline and fuel oil. The exact nature and source of the contaminant is not known; it may be spilled or leaking petroleum products, or other materials containing petroleum hydrocarbons (e.g. commercial or industrial cleaning solutions). Based on differences in the qualitative distribution of components, some of the wells contain hydrocarbons that have been environmentally altered or that originate from a source other than the most contaminated well     

Organic matter on clay minerals and marine sediments — effect on adsorption of dissolved copper,phosphate, and lipids from saline solutions

Adsorption of dissolved copper and phosphate by natural and peroxide-treated marine sediments was compared. A three-fold increase in copper adsorption and a six-fold increase in phosphate adsorption was caused by the peroxide treatment. Indigenous organic matter evidently interferes with adsorption.Clay minerals coated with heptadecanoic acid adsorbed somewhat less copper, phosphate, and hexadecane than uncoated clays, but slightly more nonadecanoic acid and anthracene.     

The North Cape oil spill: hydrocarbons in Rhode Island coastal waters and Point Judith Pond.

On 19 January 1996, the North Cape oil barge ran aground near Moonstone Beach, RI, and spilled over 2700 metric tons of No. 2 fuel oil during a severe winter storm. High winds and rough seas drove the oil into the water column, and the oil spread throughout Block Island Sound and into several coastal salt ponds. Over 50 water samples were collected from Point Judith Pond (PJP) and the southern coast of Rhode Island for four months after the spill and analyzed for polycyclic aromatic hydrocarbons (PAHs) and total petroleum hydrocarbons (TPHs). These analyses revealed that at least 60 km2 of coastal waters were impacted from the spill. Maximum concentrations of sigmaPAHs and TPHs were 115 and 3940 microg l(-1), respectively. The percentage of sigmaPAHs relative to the TPHs for all samples varied from 0.2 to 43%, showing that there was no clear relationship between sigmaPAHs and TPHs for the whole dataset and likely resulting from spatial and temporal partitioning over the course of the spill. However, within the dataset, there were stronger correlations for distinct samples collected at similar locations and times. In PJP, water column concentrations of individual PAHs decreased at rates of 0.08-0.24 day(-1) and lower-molecular weight PAHs were removed faster than higher-molecular weight PAHs.     

The formation and evolution of an isolated submarine valley in the North Channel,Irish Sea: an investigation of Beaufort's Dyke

Beaufort's Dyke is a submarine depression located in the North Channel of the Irish Sea. With a maximum depth of 312 m, the dyke is one of the deepest areas within the European continental shelf. Integration and interpretation of 450 km of sparker seismic data and full‐coverage bathymetric data derived from multi‐beam echo sounder surveys allow for the investigation of the formation processes of Beaufort's Dyke and the evolution of geomorphological features within it. The dyke, formed by composite subglacial processes dominated by subglacial meltwater discharge, is interpreted as a tunnel valley. The regional isolation of Beaufort's Dyke may be explained by the bounding of the North Channel by the bedrock masses of Ireland and Scotland, coupled with the exploitation of structural weakness along a fault plane and presence of halite in the eroded substrate enhancing the erosive potential of the overlying glacier. Beaufort's Dyke has probably been maintained as an open feature by strong rectilinear tidal currents. The morphology of lunate sediment waves and a large parabolic bedform towards the south of the dyke contradict the observed dominant S–N mean hydrodynamic flow recorded within the North Channel, suggesting an alternative hydrodynamic regime either within the dyke or during bedform creation. Copyright © 2011 John Wiley & Sons, Ltd.     

TOPCAT‐NP: a minimum information requirement model for simulation of flow and nutrient transport from agricultural systems

Future catchment planning requires a good understanding of the impacts of land use and management, especially with regard to nutrient pollution. A range of readily usable tools, including models, can play a critical role in underpinning robust decision‐making. Modelling tools must articulate our process understanding, make links to a range of catchment characteristics and scales and have the capability to reflect future land‐use management changes. Hence, the model application can play an important part in giving confidence to policy makers that positive outcomes will arise from any proposed land‐use changes. Here, a minimum information requirement (MIR) modelling approach is presented that creates simple, parsimonious models based on more complex physically based models, which makes the model more appropriate to catchment‐scale applications. This paper shows three separate MIR models that represent flow, nitrate losses and phosphorus losses. These models are integrated into a single catchment model (TOPCAT‐NP), which has the advantage that certain model components (such as soil type and flow paths) are shared by all three MIR models. The integrated model can simulate a number of land‐use activities that relate to typical land‐use management practices. The modelling process also gives insight into the seasonal and event nature of nutrient losses exhibited at a range of catchment scales. Three case studies are presented to reflect the range of applicability of the model. The three studies show how different runoff and nutrient loss regimes in different soil/geological and global locations can be simulated using the same model. The first case study models intense agricultural land uses in Denmark (Gjern, 114 km²), the second is an intense agricultural area dominated by high superphosphate applications in Australia (Ellen Brook, 66 km²) and the third is a small research‐scale catchment in the UK (Bollington Hall, 2 km²). Copyright © 2007 John Wiley & Sons, Ltd.     

Regional aerosol optical depth characteristics from satellite observations: ACE‐1, TARFOX and ACE‐2 results

Analysis of the aerosol properties during 3 recent international field campaigns (ACE‐1, TARFOX and ACE‐2) are described using satellite retrievals from NOAA AVHRR data. Validation of the satellite retrieval procedure is performed with airborne, shipboard, and land‐based sunphotometry during ACE‐2. The intercomparison between satellite and surface optical depths has a correlation coefficient of 0.93 for 630 nm wavelength and 0.92 for 860 nm wavelength. The standard error of estimate is 0.025 for 630 nm wavelength and 0.023 for 860 nm wavelength. Regional aerosol properties are examined in composite analysis of aerosol optical properties from the ACE‐1, TARFOX and ACE‐2 regions. ACE‐1 and ACE‐2 regions have strong modes in the distribution of optical depth around 0.1, but the ACE‐2 tails toward higher values yielding an average of 0.16 consistent with pollution and dust aerosol intrusions. The TARFOX region has a noticeable mode of 0.2, but has significant spread of aerosol optical depth values consistent with the varied continental aerosol constituents off the eastern North American Coast.