An electrochemical study of pyrite oxidation in the presence of carbon coatings in cyanide medium

The anodic and cathodic behaviour of pyrite with clay and different carbon coatings of activated carbon, graphite and carbonaceous matter in cyanide medium was investigated using the potentiodynamic method. The presence of clay coating did not change the polarisation curve appearance for either the anodic oxidation of pyrite or the cathodic reduction of oxygen or the potential of the current plateau, but only decreased the plateau current especially at a higher coating thickness. The presence of the carbon coatings marginally shifted the rest potential for pyrite to a more anodic position and slightly changed the polarisation curve appearance for pyrite oxidation. The current density for pyrite oxidation largely increased in the presence of the carbon coatings, the potential at the plateau shifted to more cathodic positions, and the plateau width became smaller. These effects became more noticeable at a higher coating thickness. The activated carbon, graphite and carbonaceous matter coatings performed similarly in affecting pyrite oxidation at a similar thickness. The carbon coatings significantly increased the limiting current densities for oxygen reduction on pyrite, and the limiting current plateau became steeper at a higher coating thickness. The carbon coatings increased the limiting current density for oxygen reduction to a similar extent at a low coating thickness, but increased to varied extents at a higher coating thickness. The carbon coatings also greatly increased the cathodic current density for gold reduction on pyrite. The enhancement of pyrite oxidation and oxygen or gold reduction on pyrite by the carbon coatings was likely attributed to the electrochemical interaction between pyrite and the carbon materials with electron-rich surfaces and high conductivity. The presence of the carbon coatings significantly increased the oxidation of pyrite in aerated cyanide solutions and the preg-robbing of pyrite especially at a higher coating thickness.     

Dissolved trace elements in river water: spatial distribution and the influencing factor, a study for the Pearl River Delta Economic Zone, China

Twenty-nine water samples were collected from different river channels of the Pearl River Delta Economic Zone, China. An inductively coupled plasma-mass spectromonitor (ICP-MS) was used to measure concentrations of the trace elements in these samples. The results suggest that the average concentrations of rare earth elements in river water show an increasing trend from the West River, the North River, the rivers of the Pearl River Delta, and the Shenzhen River to the East River. Relatively high concentrations of heavy metals appear in the East River, the rivers of the Pearl River Delta and the Shenzhen River, while the West River and the North River have relatively low heavy metal concentrations. Trace element concentrations in samples collected near urban or industrial areas are much higher than those of samples collected from distant areas, away from urban and industrial areas. After natural conditions, human activities have significant influence on the trace element concentrations in river water. This trace element concentration’s spatial distribution in the river water from the Pearl River Delta Economic Zone is actually an integrated effect of natural conditions and human activity.     

加强工程施工项目管理措施与建议

结合项目施工管理的经验,从建立项目管理班子、项目评估和合同评审签订、人力资源的优化配置、强化劳务管理、责任成本管理、建立激励约束机制六个方面来探讨加强工程项目管理办法,并同时提出了加强工程项目管理的具体措施与建议.     

中国西北部盆地岩石热导率和生热率特征

本文根据大量实测数据,首次系统地报道了中国西北地区塔里木盆地、准噶尔盆地和柴达木盆地内的岩石热导率、岩石放射性生热率数据及其分布特征.对600多个岩石热导率和100多个实测岩石生热率的统计分析表明,沉积盆地中岩石的热物理性质与其岩性、埋藏深度和地层时代密切相关.随深度和地层时代的加大,岩石热导率增大;塔里木盆地的岩石热导率的总体平均值最大,而柴达木盆地的最小.岩石生热率在上地壳的分布是随深度的增加而减小的,但在沉积盆地的深度范围内几乎不变,其分布是均匀的,仅不同岩性的生热率差别较大.估算的岩石放射性生热产生的热量可以占到盆地地表热流的25%～45%.因此,岩石热物理性质的参数不仅与盆地的地温分布和大地热流特征密切相关,还可以为该地区盆地热历史恢复及深部地球物理的研究提供有效的参数和边界条件.     

工业革命以来青藏高原与南极冰芯高分辨率甲烷记录对比研究

自工业革命以来全球大气CH4含量呈快速的增长趋势, 但达索普冰芯记录所显示的北半球中低纬度地区大气CH4增长的启动时间要晚于极地冰芯记录近100 a. 由于受北半球人类活动CH4排放、CH4在大气中的寿命及大气中CH4的传输等过程的影响, 最近150 a以来, 中低纬度大气CH4与南极大气CH4含量在不同的时段表现出不同的净积累量和增长速率, 且20世纪两次世界大战期间达索普冰芯记录明确显示出人类活动排放的减缓使大气CH4呈负增长. 对比研究认为, 到20世纪中叶人类活动的甲烷排放已达到极高值, 中低纬度大气中CH4增长率及年积累逐步趋于平稳且略有降低. 可以认定, 工业革命以来中低纬度地区大气CH4与南极大气CH4含量的变化在不同的时段在受控于人类活动影响的同时, CH4在大气中的行为和传输过程以及东亚中低纬度季风气候的影响决定了两地之间大气CH4含量变化存在显著的差异.     

冰芯记录中末次间冰期-冰期旋回气候突变事件的研究进展

冰芯记录中的气候变化是古气候研究中的重要组成部分. 极地、中低纬度和热带地区的冰芯记录表明, 在冰期间冰期旋回大尺度气候变化背景下, 全球经历了一系列数百年至千年时间尺度的快速气候突变事件, 诸如末次间冰期的干冷事件、末次冰期的DansgaardOeschger事件、 Heinrich事件和Younger Dryas事件等, 虽然这些穿插在冰阶中的暖湿气候事件、间冰阶中的干冷气候事件的成因、机制和影响范围还存在明显的不确定性. 主要介绍不同区域冰芯记录中末次间冰期冰期旋回这些气候突变事件发生的时间、过程和机制等的研究进展.     

青藏高原各拉丹冬地区冰川变化的遥感监测

以位于青藏高原长江源头的各拉丹冬地区冰川为例, 利用2000年的TM数字遥感影像资料、 1969年的航空相片遥感资料、地形图及数字地形模型, 通过遥感图像处理和分析提取研究区小冰期最盛期(LIA)、 1969年和2000年的冰川范围, 并在地理信息系统技术支持下分析该地区冰川的进退情况. 研究结果表明, 该地区1969年冰川面积比小冰期最盛期的冰川面积减少了5.2%, 2000年的冰川面积比1969年的冰川面积减少了1.7%. 从1969年到2000年最大冰川退缩速度为-41.5 m*a-1, 最大冰川前进速度为+21.9 m*a-1. 本区的冰川基本处于稳定状态, 冰川退缩的速度不是太大, 并有前进的冰川存在.     

国际冰芯与气候环境研究新进展--关于国际"冰芯与气候"会议

2001年8月19～23日, 在格陵兰举行了规模空前的"冰芯与气候"国际盛会, 会议展示了冰芯与气候环境研究的最新进展. 文中介绍这次会议并概括了近年来的主要研究进展. 与南北极地区的冰芯研究相比, 中低纬度地区冰芯研究是近年来国际冰芯研究中发展最快的. 在这一研究中, 中国科学家做出了重要贡献并得到了国际同行的高度评价.