Low-temperature alteration of oceanic island basalts and their contribution to transition metal circulation of the ocean

The major elements, rare earth elements （REE） and trace elements of four basalt samples from central and western Pacific ferro- manganese crust provinces have been analyzed using chemical methods and ICP - MS, respectively. The results indicate that the samples have been extensively altered and that the contents of their major elements have changed significantly. However, the similarity of REE partition patterns and trace element contents of basalt samples to those of fresh oceanic island basalts （OIB） indicate that the basalt samples originated as OIB. Because of low-temperature alteration, the contents of A1203 , Fe203 , MnO, K20 and P205 increased, while MgO and FeO decreased. Active components, such as magnesium and iron, were leached from OIB resulting in the relative enrichment of SiO2. The leaching of active components can cause the relative enrichment of REE, while the precipitation of LREE-rich ferromanganese oxides in vesicles and fissures not only causes an increase of REE contents, but also induces ＂fractionation＂ of LREE and HREE. Based on the enrichment mechanism of REE contents, the theoretical quantities of precipitated ferromanganese oxides and the depleted quantities of active components are calculated ： the depleted quantities of active components for the unit mass of fresh basalts vary in the range of 0.15 ～ 0. 657, and the precipitated quantities of ferromanganese oxides for the unit mass of fresh basahs vary in the range of 0. 006 ～ 0. 042. Of the major elements, the two most depleted are iron, and magnesium, with 18.28% ～ 70.95% of iron and 44.50% ～ 93.94% of magnesium in the fresh basalts was leached out. Theoretical calculation and geochemistry results both indicate that low-temperature alteration of basalts can supply abundant amount of metals to seawater, and may play an important role in ocean metal circulation.     

稀土元素Ce对雨生红球藻生长及虾青素积累影响的研究

采用反相高效液相色谱分析法（RP-HPLC）研究了稀土元素铈（Ce^3＋）对雨生红球藻（Haematococcus pluvialis）生长及虾青素积累的影响。结果表明,低质量浓度的Ce^3＋对微藻生长和虾青素积累均具有明显的促进作用,当Ce^3＋的质量浓度为0．1mgm时,对藻生长的促进效果最佳,细胞密度较对照组提高34％;当Ce^3＋的质量浓度为1mg/L时,虾青素质量分数可达到细胞干质量的3．2％,较对照组提高167％。此外,高质量浓度Ce^3＋的对雨生红球藻有抑制作用,当Ce^3＋的质量浓度高于40mgm时,红球藻的生长完全被抑制,虾青素质量分数也明显降低。     

一种两步抗差估计的设计及其解算

抗差估计的关键是选择适当的权函数和合理的调制因子,针对这两个重要问题,在研究当前调制因子取值方法的基础之上,提出了可动性调制因子这一新概念,并基于可动性调制因子、IGG方案权函数,设计了两步抗差估计。两步抗差估计解决了抗差估计中传统的调制因子、方差因子、初值三者取值时存在的一系列问题,尤其当三者取值不能协调配制时出现的秩亏问题,从而使抗差估计方法更具有实际意义和广泛意义。     

主成分分析法在油荧光光谱波段选择中的应用

355nm激光器发射激光入射到海水表面,激发海表面溢油的荧光光谱,运用高光谱图像降维中应用广泛的分段主成分分析算法对油荧光光谱进行波段选择。该算法把每个分段被映射到主成分的信息量的大小作为是否被选择的标准,保证了选择波段的信息丰富;通过分段分析消除了传统主成分分析的全局性引起的波段忽略问题,获得较为满意的降维效果。     

Morphodynamics of an Artificial Cobble Beach in Tianquan Bay,Xiamen, China

By tracking and monitoring the profile configuration, topography, and hydrodynamic factors of an artificial cobble beach in Tianquan Bay, Xiamen, China over three consecutive years after its completion, we analyzed the evolution of its profile configuration and plane morphology, and its storm response characteristics. The evolution of the profile configuration of the artificial cobble beach in Tianquan Bay can be divided into four stages. The beach was unstable during the initial stage after the beach nourishment the profile configuration changed obviously, and an upper concave composite cobble beach formed gradually, which was characterized by a steep upper part and a gentle lower part. In the second stage, the cobble beach approached dynamic equilibrium with minor changes in the profile configuration. At the third stage the beach was in a high-energy state under the influence of Typhoon Meranti, and the response of the artificial cobble beach differed significantly from that of the low-tide terrace sandy beach. Within a short time, there was net onshore transport of cobbles in the cross-shore direction. The beach face was eroded, the beach berm was accumulated, and the slope of the beach was steepened considerably. In the alongshore direction, there was notable transport of cobbles on the beach from east to west along the shore, and the total volume of the beach decreased by 4.5×103 m~3, which accounted for 50% of the total amount of beach volume lost within three years. The fourth stage was the restoration stage after the typhoon, characterized by a little gentler profile slope and the increase in width and the decrease in height of beach berm. Because of the action of waves and the wave-driven longshore current caused by the specific terrain and landform conditions along the coast(e.g., coastal headlands, near-shore artificial structures, and reefs), the coastline of the artificial cobble beach gradually evolved from being essentially parallel to the artificial coast upon completion to a slightly curved parabolic shape, and three distinct erosion hotspots were formed on the west side of the cape and the artificial drainpipe, and the reefs. Generally, the adoption of cobbles for beach nourishment on this macro-tidal coast beach with severe erosion has yielded excellent stability and adaptability.     

贫困村空间分布及影响因素分析——以乌蒙山连片特困区为例

针对目前贫困分布研究以大尺度为主而缺乏对小尺度的关注和致贫因素分析忽略个体效应或背景效应的不足,基于空间贫困视角,以乌蒙山片区为研究区域、贫困村为研究对象,运用空间点模式分析方法探究贫困村空间分布特征,并设计多层线性回归模型从贫困村和县域两个层面综合定量剖析贫困影响因素。研究发现：① 贫困村的空间聚集特征较为明显,总体分布呈现大分散小集中、散点-极核-轴带-团块并存的空间格局。② 贫困村的贫困程度受多层因素的显著影响。其中,村级影响因素为：人口密度、通路率、劳动力比例、遭受自然灾害频次、安全饮用水比例;县级影响因素为：人均地方生产总值、高中阶段毛入学率、植被覆盖率。③ 农村贫困来源于贫困村与县域的双重作用。因此在精准扶贫工作中,政府及相关部门可针对不同尺度对象有针对性地施策,合理配置扶贫资金。     

基于F型mtDNA D-Loop的厚壳贻贝(Mytilus coruscus)群体遗传多样性研究

为研究东海区厚壳贻贝(Mytilus coruscus)遗传多样性,以厚壳贻贝F mtDNA D-loop为标记,对浙江省舟山嵊山岛、宁波渔山岛、温州南麂岛、福建省宁德湾和莆田南日岛五个海区的厚壳贻贝群体进行了遗传分析。结果表明,厚壳贻贝各群体的遗传多样性差异不明显,在5个群体中,宁德群体的遗传多样性相对最丰富;将5个群体作为一个整体时,呈现出较高的单倍型多样性和较低的核苷酸多样性。对厚壳贻贝5个群体间的遗传分化系数(Fst)和基因流(Nm)进行检测,结果显示群体间Fst值都很低,但Nm值都很高(Nm绝对值1),表明5个群体间存在丰富的基因交流。但宁德群体与浙江沿海的3个群体(嵊山、渔山、温州)的Fst值相对较高,且差异显著(P0.5),表明宁德群体与这3个群体间出现遗传分化。本研究旨在为海洋经济贝类资源的保护管理提供理论依据。     

基于分光光度法的多量程海水营养盐原位传感器检测系统设计

针对传统海水营养盐检测方法不能满足海水营养盐长期原位监测需求的问题,研制了一种基于分光光度法的多量程海水营养盐原位传感器检测系统,通过对系统的高度集成及对多量程检测、低功耗技术、漏液保护技术的应用,实现了对海水5项营养盐参数快速、宽范围、高精度的原位测量。经过实验室和青岛中苑码头现场测试,表明本营养盐传感器检测系统具有低功耗、高可靠性能,可满足对5项营养盐参数的快速精确测量要求,实现了对海水营养盐参数的原位监测,为相关部门及时了解海洋生态环境和水体富营养化程度提供了数据支持,具有重大现实意义。     

褐菖鲉仔、稚鱼消化系统发育的组织学观察

为探究卵胎生鱼类褐菖鲉(Sebastiscus marmoratus)的仔、稚鱼消化系统组织学特点, 采用常规组织切片技术, 并用HE染色和组织化学染色, 比较分析了产出后0~50d的褐菖鲉仔、稚鱼消化系统发育的组织学变化。结果显示: 褐菖鲉初产仔鱼已分化出口咽腔, 并具有初始的食道、胃、肠、肝脏和胰脏; 2日仔鱼肛门与外界相通, 食道扩大, 开始摄食, 进入混合性营养期; 3~4日仔鱼幽门盲囊出现, 食道内壁出现黏膜皱褶5~6个, 胃黏膜皱褶5个, 肝细胞团区域扩大; 5~6日仔鱼卵黄囊和油球耗尽, 进入外源性营养期, 食道黏膜上皮出现杯状细胞, 肠道弯曲, 可区分前中肠和后肠两部分; 10~14日仔鱼食道环肌层明显, 黏膜皱褶增加到7~12个, 胃壁四层结构基本形成, 肠道黏膜皱褶加深, 纹状缘清晰可见, 肝细胞分裂迅速, 数量显著增加, 体积增大, 出现肝血窦和胰岛; 28~30日稚鱼出现胃腺和胃小凹, 已具功能性胃, 标志着稚鱼期的开始, 此时胰岛细胞数量和酶原颗粒增多, 消化能力显著提高; 47~50日稚鱼已基本具有成鱼胃的特征, 肠道纹状缘发达, 肝细胞呈多边形, 细胞内含大量脂肪颗粒, 消化系统从结构和功能上已趋于完善。由此可见, 褐菖鲉仔鱼和稚鱼消化系统的发育具有卵胎生鱼类发育较早的特点, 与其消化功能的完善密切相关。     

赤道东印度洋和孟加拉湾障碍层厚度的季节内和准半年变化

利用2002—2015年ARGO网格化的温度、盐度数据, 结合卫星资料揭示了赤道东印度洋和孟加拉湾障碍层厚度的季节内和准半年变化特征, 探讨了其变化机制。结果表明, 障碍层厚度变化的两个高值区域出现在赤道东印度洋和孟加拉湾北部。在赤道区域, 障碍层同时受到等温层和混合层变化的影响, 5—7月和11—1月受西风驱动, Wyrtki急流携带阿拉伯海的高盐水与表层的淡水形成盐度层结, 同时西风驱动的下沉Kelvin波加深了等温层, 混合层与等温层分离, 障碍层形成。在湾内, 充沛的降雨和径流带来的大量淡水产生很强的盐度层结, 混合层全年都非常浅, 障碍层季节内变化和准半年变化主要受等温层深度变化的影响。上述两个区域障碍层变化存在关联, 季节内和准半年周期的赤道纬向风驱动的波动过程是它们存在联系的根本原因。赤道东印度洋地区的西风(东风)强迫出向东传的下沉(上升)的Kelvin波, 在苏门答腊岛西岸转变为沿岸Kelvin波向北传到孟加拉湾的东边界和北边界, 并且在缅甸的伊洛瓦底江三角洲顶部(95°E, 16°N)激发出向西的Rossby波, 造成湾内等温层深度的正(负)异常, 波动传播的速度决定了湾内的变化过程滞后于赤道区域1~2个月。