Characterization of dissolved organic matter fluorescence in the South Atlantic Bight with use of PARAFAC model: Interannual variability

Systematic water sampling for characterization of chromophoric dissolved organic matter (CDOM) in the coastal South Atlantic Bight, was conducted as part of the long term Coastal Ocean Research and Monitoring Program (CORMP). Water samples were collected during a 3.5 year period, from October 2001 until March 2005, in the vicinity of the Cape Fear River (CFR) outlet and in adjacent Onslow Bay (OB). During this study there were two divergent hydrological and meteorological conditions in the CFR drainage area: a severe drought in 2002, followed by the very wet year of 2003. CDOM was characterized optically by the absorption coefficient at 350 nm, the spectral slope coefficient (S), and by Excitation Emission Matrix (EEM) fluorescence. Parallel Factor Analysis (PARAFAC) was used to assess CDOM composition from EEM spectra and six components were identified: three terrestrial humic-like components, one marine humic-like component and two protein-like components. Terrestrial humic-like components contributed most to dissolved organic matter (DOM) fluorescence in the low salinity plume of the CFR. The contribution of terrestrial humic-like components to DOM fluorescence in OB was much smaller than in the CFR plume area. Protein-like components contributed significantly to DOM fluorescence in the coastal ocean of OB and they dominated DOM fluorescence in the Gulf Stream waters. Hydrological conditions during the observation period significantly impacted both concentration and composition of CDOM found in the estuary and coastal ocean. In the CFR plume, there was an order of magnitude difference in CDOM absorption and fluorescence intensity between samples collected during the drought compared to the wet period. During the drought, CDOM in the CFR plume was composed of equal proportions of terrestrial humic-like components (ca. 60% of the total fluorescence intensity) with a significant contribution of proteinaceous substances (ca. 20% of the total fluorescence). During high river flow, CDOM was composed mostly of humic substances (nearly 75% of total fluorescence) with minor contributions by proteinaceous substances. The impact of changes in fresh water discharge patterns on CDOM concentration and composition was also observed in OB, though to a lesser degree.     

Paleolithic hunting in a southern Moravian landscape: The case of Milovice IV,Czech Republic

The Dolní Věstonice–Pavlov–Milovice area (Czech Republic) on the slopes of the Pavlov Hills provides an opportunity for correlating the geomorphology of the Dyje River valley with Gravettian settlement patterns. Although the sites vary in size and complexity, they create a regular chain of strategic locations at elevations between 200 m and 240 m asl. In 2009, a road collapsed into deserted cellars inside the village of Milovice and revealed a complex of archaeological layers deep within loess, at an elevation of only 175 m asl. This paper presents an analysis of this atypical archaeological site location and compares the results with the other sites. We argue that this location allowed direct contact with mammoth herds concentrated on the floodplain, while the aquatic environment offered possibilities for gathering plants and fishing. This site represents a new aspect of organized settlement, hunting strategies, and short‐distance human movements during the Gravettian within this area. © 2011 Wiley Periodicals, Inc.     

A 2300-year record of environmental change from SW Anatolia, Lake Burdur, Turkey

This work deals with changes recorded by lacustrine sediments from SW Anatolia in Turkey in the context of increasing stress on the Mediterranean environment in relation to human-climate-environmental interactions. Paleolimnological investigations were carried out on Lake Burdur (Lake District geographical subregion of Turkey), which has been subject to rapid changes in its hydrological system that caused a ~10-m water-level drop in the last 30 years. Study of a 5-m-long sediment core, taken from the recently dried out part of the lake, shows significant variation in granulometry, clay mineralogy, nitrogen and organic carbon content and its isotopic composition (?¹³C_org) throughout the sedimentary sequence, which represents the last 2,300 years. Chronology is based on radiocarbon dates obtained from plant fragments. The results provide a record of environmental changes, including biological productivity and erosion intensity, in relation to changes in water level and humidity of the area. The lowest previous water level, which is the same as observed today, occurred at approximately 300 BC, after which time a water-level increase led to a maximum stage between AD 200 and 1200. From AD 1200 to the present, the climate became drier accompanied by an overall lowering of water level, with periods of water-level fluctuations superimposed. The lake never dried out as is observed today at the coring site. The present drop in the lake water level is attributed to human activity rather than to climate change. This record of climate and environmental change in the Lake Burdur area appears to be stratigraphically complete. This study provides rare data for the late Holocene in Anatolia as well as information about rapid climate changes during specific periods. The influence of both the Northern hemisphere atmospheric circulation and Indian monsoon on the east Mediterranean remains unclear. Nevertheless, the North Sea—Caspian atmospheric teleconnection could be an important factor that explains local differences in climatic evolution of Anatolia during the period considered.     

Internal catchment process simulation in a snow‐dominated basin: performance evaluation with spatiotemporally variable runoff generation and groundwater dynamics

Hydrologic models have increasingly been used in forest hydrology to overcome the limitations of paired watershed experiments, where vegetative recovery and natural variability obscure the inferences and conclusions that can be drawn from such studies. Models are also plagued by uncertainty, however, and parameter equifinality is a common concern. Physically‐based, spatially‐distributed hydrologic models must therefore be tested with high‐quality experimental data describing a multitude of concurrent internal catchment processes under a range of hydrologic regimes. This study takes a novel approach by not only examining the ability of a pre‐calibrated model to realistically simulate watershed outlet flows over a four year period, but a multitude of spatially‐extensive, internal catchment process observations not previously evaluated, including: continuous groundwater dynamics, instantaneous stream and road network flows, and accumulation and melt period spatial snow distributions. Many hydrologic model evaluations are only on the comparison of predicted and observed discharge at a catchment outlet and remain in the ‘infant stage’ in terms of model testing. This study, on the other hand, tests the internal spatial predictions of a distributed model with a range of field observations over a wide range of hydroclimatic conditions. Nash‐Sutcliffe model efficiency was improved over prior evaluations due to continuing efforts in improving the quality of meteorological data collection. Road and stream network flows were generally well simulated for a range of hydrologic conditions, and snowpack spatial distributions were well simulated for one of two years examined. The spatial variability of groundwater dynamics was effectively simulated, except at locations where strong stream–groundwater interactions exist. Model simulations overall were quite successful in realistically simulating the spatiotemporal variability of internal catchment processes in the watershed, but the premature onset of simulated snowmelt for one of the simulation years has prompted further work in model development. Copyright © 2011 John Wiley & Sons, Ltd.     

Evidence for extreme fractionation of peralkaline silicic magmas, the Boseti volcanic complex, Main Ethiopian Rift

Matrix glass and melt inclusions in phenocrysts from pantellerite lavas of the Boseti volcanic complex, Ethiopia, record extreme fractionation of peralkaline silicic magma, with Al₂O₃ contents as low as 2.3?wt.%, FeO* contents up to 17?wt.% and SiO₂ contents ~65?wt.%. The new data, and published data for natural and experimental glasses, suggest that the effective minimum composition for peralkaline silicic magmas has ~5?wt.% Al₂O₃, 13?wt.% FeO* and 66?±?2?wt.% SiO₂. The dominant fractionating assemblage is alkali feldspar?+?fayalite?+?hedenbergite?+?oxides?±?quartz. Feldspar – melt relationships indicate that the feldspar is close to the minimum on the albite-orthoclase solid solution loop through the entire crystallization history. There is petrographic, mineralogical and geochemical evidence that magma mixing may have been a common process in the Boseti rhyolites.     

Interannual Variation in Photosynthetically Significant Optical Properties and Water Quality in a Coastal Blackwater River Plume

Surface water optical characteristics, nutrients, and planktonic chlorophyll a concentrations were analyzed in the Cape Fear River (CFR) plume over a 2-year period. CFR discharge during the dry year (109 ± 105 m³s⁻¹) was only 25% of the wet year discharge (429 ± 337 m³s⁻¹). Partitioning the contributions of phytoplankton pigments, non-pigmented particles, and colored dissolved organic matter (CDOM) to the absorption of photosynthetically active radiation (PAR) indicated that CDOM was the dominant contributor to PAR absorption. Particulate absorption was relatively greater during the dry year. Pigment absorption was minor and varied little among stations or between years. Chlorophyll a concentrations were reduced at the most plume-influenced stations during the wet year, despite lower turbidity and higher nitrate concentrations. Ammonium and orthophosphate concentrations were not different between years. CDOM absorption [a _CDOM (412)] ranged from 0.05 to 8.25 m⁻¹ with highest values occurring near the CFR mouth. Our results suggest that for coastal ecosystems with significant blackwater river inputs, CDOM may exert a major limiting influence over near-shore primary production.