Marbles from Roman Hispania: stable isotope and cathodoluminescence characterization

Pure white marble has been considered a valuable ornamental and architectural material since ancient times. Many scientific techniques have been used to create an extensive data base of “finger-prints” characterizing white marbles from the major classical quarries. However, determining the provenance of white marbles is a difficult task due to their similarity in physical and chemical parameters. Three techniques (petrography, cathodoluminescence and stable C and O isotopes) have been used to characterize white marbles from the ancient quarries of the Iberian Peninsula. Maximum grain size, texture and isotopic composition can be used to identify the different quarries. Each area is generally represented by several cathodomicrofacies, but quantitative CL analysis is also helpful in distinguishing those quarries for which the data provided by other techniques are not sufficiently diagnostic. The database and the discriminating criteria presented in this study have been tentatively applied to some ancient sculptures from the National Museum of Roman Art in Merida (Spain).     

Evolution of Heterogeneous Mantle in the Acampamento Velho and Rodeio Velho Volcanic Events, Camaquã Basin, Southern Brazil

The Camaquã Basin, developed during the last phases of the Brazilian/Pan-African Orogeny and was filled with a thick volcano-sedimentary succesion, in which two volcanic events of alkaline affinity are represented by the Acampamento Velho Alloformation and the Rodeio Velho Member. The Acampamento Velho Alloformation records a bimodal event with a lower association of mafic flows and an upper association of felsic pyroclastic rocks and flows. It was formed during extension, after the subduction of the Adamastor oceanic plate beneath the Rio de La Plata continental plate at the end of the Neoproterozoic III. The second event, the Rodeio Velho Member, represented by mafic flows, intrusions and piroclasts, took place during overall extensional tectonism, probably in the middle Ordovician. Rb, Sr, Sm, and Nd isotopic measurements were carried out on samples from both units. Regardless the event they represent, all the samples display negative values for epsilon Nd, ranging from 2.97 to 10.31 for the Acampamento Velho Alloformation and from 8.39 to 13.92 for the Rodeio Velho Member. The initial ⁸⁷Sr/⁸⁶Sr ratios vary from 0.706 to 0.707 and from 0.704 to 0.707 for the Acampamento Velho Alloformation and Rodeio Velho Member, respectively. Mafic flow deposits in both units show a preferential enrichment in Ba relative to Th. Flow samples from the Rodeio Velho Member also display a distinctive enrichment in the Ba/Th ratio, without a change in the initial Sr, compared to the mafic flow deposits from the Acampamento Velho Alloformation, which show a slight enrichment in those ratios. As for the Acampamento Velho Alloformation, the mafic lavas could be a mixture of depleted mantle-derived basalts plus 20% to 30% of crustal contamination by sediment (probably Neoproterozoic arkosic quartzites). The formation of a magmatic chamber and the separation of the magma into two fractions gave rise initially to the mafic rocks at the base of the Acampamento Velho Alloformation The other magma fraction underwent a significant enrichment in crustal component before the felsic rocks of this Alloformation were formed. The flows from the Rodeio Velho Member originated in a distinct magma chamber, with EM I characteristics that was much more enriched in incompatible elements and depleted in radiogenic Sr.     

Arabia Terra,Mars: Tectonic and Palaeoclimatic Evolution of a Remarkable Sector of Martian Lithosphere

A regional geologic study of Arabia Terra, a densely cratered area of Mars northern hemisphere, has revealed the individuality of this province. This is best expressed by an equatorial belt with a crater age distinctly younger as compared to the northern part of Arabia Terra and to Noachis Terra to the south. We interpret this as an incipient back-arc system provoked by the subduction of Mars lowlands under Arabia Terra during Noachian times. The regional fracture patterns are also best explained in this manner, making it unnecessary to appeal to a rotational instability of the planet, which is not supported by the palaeoclimatic indicators in the area. This model could be the first regional-scale confirmation of Sleep's (1994) hypothesis of a limited plate consumption as an explanation of the martian dichotomy. This revised version was published online in July 2006 with corrections to the Cover Date.     

Estimating parameters of the channel width–flow discharge relation using rill and gully channel junction data

Eroding channels can usually be characterized by a power relationship between channel width (W) and channel discharge (Q). This paper examines the WQ relation using a recently developed channel junction approach to extend the validity of the WQ relation and to develop a procedure for estimating the WQ exponent and proportionality coefficient. Rill and gully channel data from the literature, and new data collected in different badland areas and in a few forest mountain streams, are analysed. Analysis shows that the WQ relation for channel width collected in badlands and forests agrees with trends observed for cropland. The exponent increases with increasing channel width in a continuous fashion rather than in a step‐like way and tends to a maximum whose value ranges between 0·5 and 0·6. The proportionality coefficient can be split into two terms, one expressing the case in which an eroding channel can broaden, the other reflecting the difficulties in removing the less erodible clods or rock fragments from the channel bed. Its splitting allows the development of a more correct form of the WQ relation in agreement with modern approaches of channel geometry: one part has the dimension of a discharge and makes the power base dimensionless, while the other brings the dimension of a length, needed for the channel width, into the WQ relation. The interpretation of the two constants is supported by data collected in rainfall‐runoff simulation experiments conducted in the field. Values characterizing the two constants in some environments are also given. Nevertheless the approach is not sufficiently parameterized yet to be of practical use (e.g. in models or for estimating peak discharge in areas where rill channels have formed). Copyright © 2009 John Wiley & Sons, Ltd.     

Defining manganese(II) removal processes in passive coal mine drainage treatment systems through laboratory incubation experiments

Oxic limestone beds are commonly used for the passive removal of Mn(II) from coal mine drainage (CMD). Aqueous Mn(II) is removed via oxidative precipitation of Mn(III/IV) oxides catalyzed by Mn(II)-oxidizing microbes and Mn oxide (MnO_x) surfaces. The relative importance of these two processes for Mn removal was examined in laboratory experiments conducted with sediments and CMD collected from eight Mn(II)-removal beds in Pennsylvania and Tennessee, USA. Sterile and non-sterile sediments were incubated in the presence/absence of air and presence/absence of fungicides to operationally define the relative contributions of Mn removal processes. Relatively fast rates of Mn removal were measured in four of the eight sediments where 63–99% of Mn removal was due to biological oxidation. In contrast, in the four sediments with slow rates of Mn(II) removal, 25–63% was due to biological oxidation. Laboratory rates of Mn(II) removal were correlated (R² = 0.62) to bacterial biomass concentration (measured by phospholipid fatty acids (PLFA)). Furthermore, laboratory rates of Mn(II) removal were correlated (R² = 0.87) to field-scale performance of the Mn(II)-removal beds. A practical recommendation from this study is to include MnO_x-coated limestone (and associated biomass) from an operating bed as “seed” material when constructing new Mn(II)-removal beds.     

Spatial variability of soil quality in the surroundings of a saline lake environment

The spatial variability of the quality of the soil on the shores of a lagoon affected by hydromorphy and/or salinity can be identified (Laguna de Villacañas, Castilla La Mancha) by the use of multitemporal Landsat images in order to analyse these changes. For this purpose, TM and ETM images along with field observations and certain edaphic laboratory parameters are used. In order to identify saline-hydromorphic soils, the spatial variability of chemical and physical properties of a transect, which includes from Solonchaks to Regosols and Cambisols, have been correlated with the Normalised Difference Vegetation Index (NDVI). This index, chosen for specific dates, has proven to be very useful in detecting halophytic vegetation and relating it to the variability of the quality of these soils.     

Linking Palaeozoic palaeogeography of the Betic Cordillera to the Variscan Iberian Massif: new insight through the first conodonts of the Nevado-Filábride Complex

International Journal of Earth Sciences - Graphite-rich metamorphic limestones included within low-grade black schists of the lowest Nevado-Filábride tectonic unit in the Sierra de Baza...     

Bootstrap approaches for spatial data

Generation of replicates of the available data enables the researchers to solve different statistical problems, such as the estimation of standard errors, the inference of parameters or even the approximation of distribution functions. With this aim, Bootstrap approaches are suggested in the current work, specifically designed for their application to spatial data, as they take into account the dependence structure of the underlying random process. The key idea is to construct nonparametric distribution estimators, adapted to the spatial setting, which are distribution functions themselves, associated to discrete or continuous random variables. Then, the Bootstrap samples are obtained by drawing at random from the estimated distribution. Consistency of the suggested approaches will be proved by assuming stationarity from the random process or by relaxing the latter hypothesis to admit a deterministic trend. Numerical studies for simulated data and a real data set, obtained from environmental monitoring, are included to illustrate the application of the proposed Bootstrap methods.