Primary production in a turbid estuary, the Ems-Dollard: field and model studies

The Ems-Dollard Estuary has a steep axial gradient in turbidity which strongly regulates primary production of phytoplankton and microphytobenthos. A combination of the turbidity and nutrient gradients causes a high pelagic primary production in the outer, seaward part of the estuary, and a high benthic production on high-level mudflats (with long effective photoperiods) in the inner part. Model simulations were used to study phytoplankton succession and the factors influencing this succession. Light limitation was evaluated in a sensitivity run which used a lower compensation light intensity.     

The Cloud Ice Mountain Experiment (CIME) 1998: experiment overview and modelling of the microphysical processes during the seeding by isentropic gas expansion

The second field campaign of the Cloud Ice Mountain Experiment (CIME) project took place in February 1998 on the mountain Puy de Dôme in the centre of France. The content of residual aerosol particles, of H₂O₂ and NH₃ in cloud droplets was evaluated by evaporating the drops larger than 5 μm in a Counterflow Virtual Impactor (CVI) and by measuring the residual particle concentration and the released gas content. The same trace species were studied behind a round jet impactor for the complementary interstitial aerosol particles smaller than 5 μm diameter. In a second step of experiments, the ambient supercooled cloud was converted to a mixed phase cloud by seeding the cloud with ice particles by the gas release from pressurised gas bottles. A comparison between the physical and chemical characteristics of liquid drops and ice particles allows a study of the fate of the trace constituents during the presence of ice crystals in the cloud.In the present paper, an overview is given of the CIME 98 experiment and the instrumentation deployed. The meteorological situation during the experiment was analysed with the help of a cloud scale model. The microphysics processes and the behaviour of the scavenged aerosol particles before and during seeding are analysed with the detailed microphysical model ExMix. The simulation results agreed well with the observations and confirmed the assumption that the Bergeron–Findeisen process was dominating during seeding and was influencing the partitioning of aerosol particles between drops and ice crystals. The results of the CIME 98 experiment give an insight on microphysical changes, redistribution of aerosol particles and cloud chemistry during the Bergeron–Findeisen process when acting also in natural clouds.     

The dynamics of phytoplankton, bacteria and heterotrophic flagellates at two Banks near Magdeburg in the River Elbe (Germany)

The main objectives of this study were to describe the seasonal standing stock dynamics of phytoplankton, bacterioplankton and heterotrophic flagellates in the highly eutrophic River Elbe (Germany), and to compare the seasonal patterns observed with other streams. Emphasis was placed on examining and assessing abiotic and biotic controlling factors influencing the structure and dynamics of the riverine plankton. All the physico-chemical and biological parameters determined were within the range or somewhat higher (in the case of phytoplankton abundance and biomass) than reported for other large streams. The underwater light conditions resulting from atypically short phytoplankton growth periods of about 6 months per year and the low phytoplankton carbon to chl a ratio of 23 were identified as a major limiting factor for phytoplankton development in the River Elbe. The seasonal distribution pattern of bacterioplankton indicated probable tight trophodynamical coupling both with phytoplankton and with heterotrophic flagellates, whereas heterotrophic flagellates showed a more trophic link with bacterial densities. Although approximately constant DOC and DON levels throughout the year sustained bacterial growth rates, during the phytoplankton growing season an increase of bacterial standing stocks was observed. Although the left-bank sampling site of the Elbe is strongly influenced by the tributaries Mulde and Saale containing higher concentrations of chloride, nitrogen nutrients, heavy metals and organic pollutants, no clear differences were observed between the two sides of the river concerning the biological parameters measured. Possible reasons and the slightly higher phytoplankton abundance and diversity at the right bank are discussed.     

On the causes of 18O-depletion and 18O/16O homogenization during regional metamorphism; the East Humboldt Range core complex,Nevada

 Previous stable isotope studies at Lizzies Basin revealed that metasedimentary rocks are ¹⁸O-depleted relative to protolith values, particularly in the lower parts of the section (Lower Zone) where the rocks are also isotopically homogeneous on a scale of hundreds of meters (quartz δ¹⁸O=+9.0 to +9.6 per mil). In contrast, metasedimentary rocks at higher levels at Lizzies Basin (Upper Zone) are less ¹⁸O-depleted and more heterogeneous in δ¹⁸O. In order to understand more fully the isotopic evolution of this terrane, a series of detailed, meter-scale traverses across various metamorphic and igneous lithologies were completed at Lizzies Basin, and at the structurally higher Angel Lake locality. Traverses in the Lizzies Basin Lower Zone and in the lower parts of Angel Lake (Angel Lake Lower Sequence) across various silicate lithologies, including abundant granitoids, reveal similar degrees of homogeneity, although the average δ¹⁸O values are higher at Angel Lake. In contrast, traverses which include substantial thicknesses of marble and calc-silicate gneiss and very little granitoid have more heterogeneous quartz δ¹⁸O values (+11.9 to +13.4 per mil), and also have a higher average δ¹⁸O (+12.9 per mil), than observed elsewhere. The scale of ¹⁸O/¹⁶O homogeneity in quartz observed at Lizzies Basin and Angel Lake (meters to hundreds of meters) requires fluid-mediated isotope exchange, which accompanied Tertiary metamorphism. There is a correlation between the degree of ¹⁸O-depletion in metasedimentary rocks, ¹⁸O/¹⁶O homogenization between lithologies, and the proportion of granitoids (leucogranites in particular) within any part of the section, and a corresponding anticorrelation with the proportion of marble. This points to a causal relationship, whereby the leucogranites (as well as the Tertiary hornblende diorite and biotite monzogranite) acted as both a relatively low-¹⁸O reservoir and a source of fluids to enhance exchange, while the marbles hindered isotope depletion and homogenization by acting as relatively high-¹⁸O reservoirs and impermeable layers. Material balance calculations help delineate the plausible mechanisms of exchange between granitoids and metasediments. Single-pass infiltration of magmatic fluids from the granitoids is not capable of reproducing all of the observations. Fluid-mediated exchange by convective recirculation of magmatic fluids on a scale of meters is the mechanism which explains all of the observations. The generalized model for the isotopic evolution of the East Humboldt Range core complex provides an excellent opportunity to establish the main causes and controlling factors of ¹⁸O-depletion and ¹⁸O/¹⁶O homogenization during regional metamorphism. Received: 27 July 1993 / Accepted: 1 July 1994     

Strontium and oxygen isotope profiles across marble-silicate contacts,Lizzies Basin,East Humboldt Range,Nevada: constraints on metamorphic permeability contrasts and fluid flow

 Sr isotope profiles across marble-silicate rock contacts are used in conjunction with previously published oxygen isotope profiles to constrain fluid movement, porosity and permeability contrasts in migmatitic rocks from Lizzies Basin in the East Humboldt Range, Nevada. The ¹⁸O/¹⁶O systematics in the high-grade sequence have been interpreted to reflect infiltration of ∼2×10² m³/m² of a relatively low ¹⁸O hydrous fluid through the sequence, but with preservation of δ¹⁸O anomalies in thin marble bands due to a 30-fold lower porosity in the marble compared with silicate rocks (Wickham and Peters 1992). The Sr isotope profiles confirm that tracer exchange between marble and silicate rock was primarily by diffusion, and in one case, indicate that porosities differed by less than a factor of four in the ∼10 cm boundary layer which exhibits diffusive modification of ⁸⁷Sr/⁸⁶Sr ratios. This contrasts with modelling of the oxygen isotope profiles which imply porosity contrasts >10 for one marble band and >50 for a second marble band. Either strontium and oxygen isotope diffusion reflect different events (possible if fluid Sr contents varied with time) or porosity varied substantially with the silicate rocks. Oxygen isotope profiles in the deeper part of the metamorphic section in which δ¹⁸O values of silicate rocks have been homogenised and lowered, indicate similar diffusion distances (and thus porosity-time evolution) to oxygen isotopic profiles higher in the section. Comparison of strontium and oxygen isotope diffusion distances constrains fluid Sr contents to between ∼50 and ∼500 ppm deep in the section, but less than ∼10 ppm higher in the section. The difference is related to release of relatively saline, Sr-rich fluids, by the abundant leucogranites and associated skarns deep in the section (cf. Peters and Wickham 1995). Received: 9 December 1994/Accepted: 13 April 1995     

Biomass Burning in Southern Africa: Individual Particle Characterization of Atmospheric Aerosols and Savanna Fire Samples

Ambient atmospheric aerosols and savanna fireparticulate emission samples from southern Africa werecharacterised in terms of particle classes and theirnumber abundance by electron probe X-ray microanalysis(EPXMA). About ten particle classes were identifiedfor each sample. The major classes werealuminosilicates and sea salts for ambient coarse(2–10 m equivalent aerodynamic diameter (EAD))samples, and K-S and S-only particles for ambient fine(<2 m EAD) samples. The K-S particles are oneof the major products of biomass burning. The EPXMAresults were found to be consistent with the resultsfrom bulk analyses on a sample by sample basis. Forsavanna fire fine samples, quantitative EPXMA revealedthat many particles had a composition of simple saltssuch as KCl. Some particles had a deviatingcomposition in the sense that more ionic species wereinvolved in sustaining the balance between cations andanions, and they were composite or mixed salts.Because of extensive processing during the atmospherictransport, the composition of the K-S particles in theambient samples was different from K₂SO₄,and such particles were enriched with S. The finepyrogenic KCl particles and the fine sea-saltparticles were much depleted in chlorine.     

Pleistocene tectonics inferred from fluvial terraces of the northern Upper Rhine Graben, Germany

This study of fluvial terraces of the River Rhine and tributaries aims to search for indications of Pleistocene tectonic activity. The study area includes the northern Upper Rhine Graben (URG), the Mainz Basin and the adjacent Rhenish Massif with the Middle Rhine Valley. High rates of Quaternary surface processes, large amount of human modifications, relatively slow tectonic deformation and presently low intra-plate seismic activity characterize this area. Therefore, the records of relatively slow tectonic deformation are less well preserved and thus difficult to detect. This study uses the relative position of fluvial terraces to determine the more local effects of fault movements on the terraces and to evaluate their displacement rates and patterns. The research is based on a review of previous terrace studies and new terrace mapping from the eastern Mainz Basin and the bordering URG using topographic map interpretations and field observations. This newly mapped sequence of terrace surfaces can be correlated to other terraces in the vicinity on the basis of relative height levels. Terrace correlation between the western Mainz Basin and Middle Rhine Valley relies on a single chronostratigraphic unit (Mosbach sands) and additional relative height correlations. This is the first study to present a continuous correlation of terraces from the western margin of the URG to the Rhenish Massif and enables the study of the transition from the subsiding graben to the uplifted Rhenish Massif. By means of a longitudinal profile, which ranges from the URG to the Rhenish Massif, the influence of individual fault movements on the terrace levels and the large-scale regional uplift is demonstrated. It is evident from the profile that the uplift of Early to Middle Pleistocene terraces increases northwards, towards the Rhenish Massif. The uplift was diachronic, with a significant pulse occurring first in the northern URG (Lower Pleistocene) and later in the Rhenish Massif (Middle Pleistocene). The largest vertical displacements are recorded for the boundary fault separating the Mainz Basin and the Rhenish Massif (Hunsrück–Taunus Boundary Fault) and for faults bounding the northeastern Mainz Basin. The motions and displacement rates calculated for individual faults indicate deformation rates in the order of 0.01–0.08 mm/year. At this stage, the calculation of displacement rates depends mostly on a single dated stratigraphic unit. Additional dating of terrace deposits is urgently needed to better constrain the temporal development of the terrace sequence and the impact of tectonic movements.     

The miscibility gap between rhodonite and bustamite along the join MnSiO3-Ca0.60Mn0.40SiO3

The miscibility gap between rhodonite and bustamite has been experimentally determined at temperatures between 600° and 1,100° C. For temperatures below 700° C the resulting limbs have been extrapolated on T-X-diagram as at such low temperatures equilibrium could not be attained. According to microprobe analyses for the natural assemblages of Ravinella di Sotto (Ivrea zone, Italy) and Broken Hill (N.S.W., Australia) equilibrium temperatures are estimated to be at 500° to 550° C. However these assemblages are thought to have re-equilibrated during cooling and the compositions of equilibrium assemblages are also pressure dependent. According to experiments and to molar volume data the rhodonite structure is stabilized by high pressures whereas bustamite by high temperatures. Based on available experimental results and natural data an isobaric T-X _Ca diagram and two isotherm -X _Ca diagrams (for T=400° C and T=600° C) are given.     

Chromite deposits in the ophiolite complex of Northern Oman

In the ophiolite series of N. Oman numerous small and large elongated podiform chromite deposits occur within the peridotite complex at a certain level of 100–200 meters below the layered zone, which grades into the overlying gabbro complex. The chromite grains were corroded after their deposition; their composition shows a large variation in Cr/Al ratio and a small variation in Cr/Fe ratio. The chromium is thought to have been liberated from clino-pyroxenes during partial melting of lherzolitic upper mantle material. Precipitation of large quantities of chromite at the specific level below the gabbro complex is related to the plagioclase- /spinel-lherzolite transition, but the influence of a change in oxygen fugacity is also considered.