Statistical Revision of the Moment Method

The moment method is a well known technique, which uses a time series ofthe first 3 moments of a spectral line, to estimate the (discrete) modeparameters and m. The method, contrary to Doppler imaging,also yields other interesting(real-valued) parameters such as the inclination angle i, or v sin i,during its identification procedure.In this paper, we are not only interested in the estimation of thesereal-valued parameters themselves but also inreliable estimates for their uncertainty.We designed a statistical formalism for the moment method based on theso-called generalized estimating equations (GEE). This formalismaims to estimate the uncertainty of the real-valued parameters taking intoaccount that the different moments of a line profile are correlated and –more importantly – that the uncertainty of the observed moments depends onthe pulsation parameters. The latter property of the moment method makesthe least-squares technique a poor choice to estimate the uncertainty ofthe real-valued parameters. We implemented the GEE method and presentan application to a high-resolution spectroscopic dataset of the slowly pulsating B star HD181558.     

Carbon geochemistry of serpentinites in the Lost City Hydrothermal System (30°N, MAR)

The carbon geochemistry of serpentinized peridotites and gabbroic rocks recovered at the Lost City Hydrothermal Field (LCHF) and drilled at IODP Hole 1309D at the central dome of the Atlantis Massif (Mid-Atlantic Ridge, 30°N) was examined to characterize carbon sources and speciation in oceanic basement rocks affected by long-lived hydrothermal alteration. Our study presents new data on the geochemistry of organic carbon in the oceanic lithosphere and provides constraints on the fate of dissolved organic carbon in seawater during serpentinization. The basement rocks of the Atlantis Massif are characterized by total carbon (TC) contents of 59 ppm to 1.6 wt% and δ¹³C_TC values ranging from −28.7‰ to +2.3‰. In contrast, total organic carbon (TOC) concentrations and isotopic compositions are relatively constant (δ¹³C_TOC: −28.9‰ to −21.5‰) and variations in δ¹³C_TC reflect mixing of organic carbon with carbonates of marine origin. Saturated hydrocarbons extracted from serpentinites beneath the LCHF consist of n-alkanes ranging from C₁₅ to C₃₀. Longer-chain hydrocarbons (up to C₄₀) are observed in olivine-rich samples from the central dome (IODP Hole 1309D). Occurrences of isoprenoids (pristane, phytane and squalane), polycyclic compounds (hopanes and steranes) and higher relative abundances of n-C₁₆ to n-C₂₀ alkanes in the serpentinites of the southern wall suggest a marine organic input. The vent fluids are characterized by high concentrations of methane and hydrogen, with a putative abiotic origin of hydrocarbons; however, evidence for an inorganic source of n-alkanes in the basement rocks remains equivocal. We propose that high seawater fluxes in the southern part of the Atlantis Massif likely favor the transport and incorporation of marine dissolved organic carbon and overprints possible abiotic geochemical signatures. The presence of pristane, phytane and squalane biomarkers in olivine-rich samples associated with local faults at the central dome implies fracture-controlled seawater circulation deep into the gabbroic core of the massif. Thus, our study indicates that hydrocarbons account for an important proportion of the total carbon stored in the Atlantis Massif basement and suggests that serpentinites may represent an important—as yet unidentified—reservoir for dissolved organic carbon (DOC) from seawater.     

Geophysical Survey and Archaeological Data at Masseria Grasso (Benevento,Italy)

The use of geophysical methods in metrology is a significant tool within the wide research topic of landscape archaeology context. Since 2011, the Ancient Appia Landscapes Project aims to recognize dynamics, shapes and layout of the ancient settlement located along the Appia road east of Benevento, and cyclical elements and human activities that influenced the choice of landscapes. The integration of geophysical data with an archaeological infra-site analysis allowed us to investigate the area of Masseria Grasso, about 6 km from Benevento (Campania region, Italy). In this framework, an archaeogeophysical approach (Geomagnetic and Ground Penetrating Radar) was adopted for detecting anomalies potentially correlated with buried archaeological evidences. The geomagnetic results have given a wide knowledge of buried features in a large survey highlighting significant anomalies associated with the presence of buildings, roads and open spaces. These geophysical results permitted us to define the first archaeological excavations and, successively, a detailed Ground Penetrating Radar approach has been provided highlighting the rooms and paved spaces. The overlap between archaeological dataset and geophysical surveys has also allowed recognizing the path of the ancient Appia road near the city of Benevento and hypothesize the settlement organization of the investigated area, which has been identified with the ancient Nuceriola.     

Controls on Methane Occurrences in Shallow Aquifers Overlying the Haynesville Shale Gas Field,East Texas

Understanding the source of dissolved methane in drinking‐water aquifers is critical for assessing potential contributions from hydraulic fracturing in shale plays. Shallow groundwater in the Texas portion of the Haynesville Shale area (13,000 km²) was sampled (70 samples) for methane and other dissolved light alkanes. Most samples were derived from the fresh water bearing Wilcox formations and show little methane except in a localized cluster of 12 water wells (17% of total) in a approximately 30 × 30 km² area in Southern Panola County with dissolved methane concentrations less than 10 mg/L. This zone of elevated methane is spatially associated with the termination of an active fault system affecting the entire sedimentary section, including the Haynesville Shale at a depth more than 3.5 km, and with shallow lignite seams of Lower Wilcox age at a depth of 100 to 230 m. The lignite spatial extension overlaps with the cluster. Gas wetness and methane isotope compositions suggest a mixed microbial and thermogenic origin with contribution from lignite beds and from deep thermogenic reservoirs that produce condensate in most of the cluster area. The pathway for methane from the lignite and deeper reservoirs is then provided by the fault system.     

Dynamics of grains falling on a sloping granular medium: application to the evolution of a talus

Numerous field surveys have provided quantitative information on the characteristics of talus deposits. Much less has been done to quantify the basic dynamics processes of blocks involved in talus evolution. In this work, we perform a set of experiments at the reduced scale of some metres using an inclined board covered with a loose granular medium. The complexity of the processes forming a talus is simplified by studying the interaction of only two kinds of grain sizes at a time. Grains of one class size are dropped from a fixed height onto the board covered by a layer of grains of a different class size, and their final distribution is recorded. We find that when small grains fall on large grains, the granular abundance decreases rapidly as a function of the distance from the fall point, which is explained by the effect of multiple bouncing on the irregular surface. In contrast, large grains falling on a bed of smaller grains lose much more energy at impact. They may stop at once, or roll down slope, often reaching the whole board length; as a consequence, their abundance peaks in the fall zone and at the change of slope. Experiments also show that grains travel longer with increasing fall height and sloping angle. The results clarify in a physical manner one mechanism that might explain why large blocks are typically found in the distal part of a talus slope, while smaller blocks remain near the fall zone. Based on these and previous experiments, a schematic view of talus evolution is discussed. Copyright © 2014 John Wiley & Sons, Ltd.     

Evidence for a Neoproterozoic carbonate ramp on the northern edge of the Central African craton: relations with late Proterozoic intracratonic troughs

During Late Proterozoic times, the Archaean Central African craton was affected by trough faulting which led to the formation of grabens, the Sangha aulacogen being the main structure of this type in the studied area. This transverse basin connects with other basins on the northern and south-western borders of the craton. During the Cryogenian, this network of basins was filled with fluvio-deltaic and lacustrine periglacial deposits. The glacio-eustatic transgression in Neoproterozoic III (end-Proterozoic) times flooded extensive areas of shelf on the northern edge of the craton, leading to the development of carbonate sedimentation in a broad outer shelf environment associated with nearshore barriers and evaporitic lagoons. These facies are similar to those developed in the West Congolian Schisto-calcaire (shale-limestone) ramp succession. The North-Central African ramp succession (sediment slope) contains an example of tidal rhythmites in vertical accretion, which occurs beneath the barrier deposits on the subtidal outer shelf. Mathematical analysis of the bedding pattern yields a period of 29–30 days for the lunar month, a result which is in agreement with astrophysical evidence for this epoch (i.e. 650 Ma ago). Major subsidence and seismic activity on this gently sloping platform, associated with the proximity of the Sangha aulacogen, caused the triggering of carbonate turbidites and mass flow deposits. The proliferation of microbial mats under euphotic conditions on an extensive shelf led to the build-up of a carbonate platform. During early Neoproterozoic III times, the West Congolian and North-Central African ramps prograded northwards and southwards, respectively, into the Sangha aulacogen. The sea at that time was restricted to a long graben-like basin, while a remaining area of marine sedimentation persisted into the Palaeozoic. Thus the pattern of end-Proterozoic carbonate sedimentation on the borders of the Central African craton can be interpreted in terms of an overall gently sloping ramp model with progradation converging towards the Sangha aulacogen.     

Effectiveness of geophysical surveys for water wells relocation in overexploited aquifers (the example of Maggiore and Traversola Valleys,Northwestern Italy)

Aquifer overexploitation is a common problem in drinking water management. This will become more and more important given the general reduction of water resources. To overcome overexploitation, one of the most adopted solutions is the relocation of extraction wells. To establish the positions of new wells, a precise knowledge of the hydrogeological setting is required. Specific surveys are therefore necessary to obtain information over wide investigation zones. Geophysical methods, particularly electromagnetic and electrical, can be useful with this aim. In the present paper a case history on the combined use of Electric Resistivity Tomography and Time Domain Electromagnetic soundings is reported. Surveys have been performed within the Maggiore and Traversola Valleys, to investigate the uppermost part of the Quaternary deposits, hosting the near surface aquifer. The electromagnetic data have been inverted with a spatially constrained approach by assuming a quasi 1D model of the subsurface. Geophysical surveys allowed for depicting the depth and lateral continuity of the supposed aquifer level in the surveyed area up to a depth of about 200 m and proposing potential positions for well relocation.     

Sesquiterpenoids in sediments of a hypersaline lagoon: A possible algal origin

Core samples were collected in Lagoa Vermelha, a hypersaline lagoon located about 100 km east of Rio de Janeiro (Brazil). The sediment composition is predominantly carbonate in amounts up to 93%. Analysis of δ¹³C of the total organic matter in the sediments showed that marine organic matter predominates throughout the core (δ¹³C ranges from −15.84 to −22.64‰ vs. PDB). Organic carbon contents (TOC) ranged from 0.81 to 13.28%. A series of cadinane-type sesquiterpenoids can be recognized in the gas chromatography-mass spectrometry data. Essentially the same components are present in all the samples, with variations only in their relative abundances. The most abundant compounds are α- and β-cubebene, α- and β-cedrene, cadinenes (different isomers), α-curcumene and calamenene, with minor amounts of calarene, humulene, calacorene and cadalene. Since this lagoon is surrounded by dunes with only minor vegetation typical of this environment (grasses, small non-resinous shrubs and no forest) with no potential source for sesquiterpenoids, a terrestrial origin for these compounds is excluded and an algal origin is more consistent with the locale and the recognition of sesquiterpenoids (including cadinol) in microbial mats from the lagoon. Only the natural product precursor sesquiterpenoids are present in the microbial mats with no detectable diagenetic derivatives (e.g. calamenene and cadalene). This indicates that the compounds in the mats are from recent input and those found in the sediments are most likely derived from former algal biomass in this lagoon, a fact confirmed by the recognition of a series of diagenetic aromatic components in the sediments. Surface sediments contain n-alkanes with no even-to-odd predominance indicating that microbial activity is higher in shallower sediments. Moreover, mass fragmentograms (m/z 191) of biomarkers revealed the presence of 17α(H),21β(H)-hopanes, the mature isomers, together with their ββ precursors and low amounts of the intermediates with the βα configuration (moretanes). This indicates a contribution of mature organic matter to these immature sediments.